Energy-dependent photoion angular distributions in two-body Coulomb explosions of molecules.

We experimentally study two-body Coulomb explosions of CO2, O2, and CH3Cl molecules in intense femtosecond laser pulses. We observe an obvious variation in the ionic angular distribution of the fragments with respect to the kinetic energy releases (KERs). Using a classical model based on ab initio potential energy curves, we find that the dependence of the ionic angular distribution on the KER is relevant to the fact that the accurate potential energy deviates significantly from the value determined by applying the Coulomb interaction approximation at a relatively small internuclear distance of the molecule. We show that the KER-dependent ionic angular distribution provides an effective way to determine the critical internuclear distance at which the Coulomb interaction approximation holds or breaks down without relying on the knowledge of the accurate potential energy curves.

Picometer-Resolved Photoemission Position within the Molecule by Strong-Field Photoelectron Holography.

Laser-induced tunneling ionization is one of the fundamental light-matter interaction processes. An accurate description of the tunnel-ionized electron wave packet is central to understanding and controlling subsequent electron dynamics. Because of the anisotropic molecular structure, tunneling ionization of molecules involves considerable challenges in accurately describing the tunneling electron wave packet. Up to now, some basic properties of the tunneling electron from molecules still remain unexplored. Here, we demonstrate that the tunneling electron from a molecule is not always emitted from the geometric center of the molecule along the tunnel direction. Rather, the photoemission position depends on the molecular orientation. Using a photoelectron holographic technique, we determine the photoemission position for a nitrogen molecule relative to the molecular geometric center to be 95±21 pm when the molecular axis is oriented along the tunnel direction. Our Letter poses, and answers experimentally, a fundamental question as to where the molecular photoionization actually begins, which has significant implications for time-resolved probing of valence electron dynamics in molecules.

Intramolecular oxidative coupling: I2/TBHP/NaN3-mediated synthesis of benzofuran derivatives.

A novel intramolecular oxidative coupling reaction has been established to prepare benzofuran derivatives via direct C(sp(2))-H functionalization for the formation of C-O bond. This transformation is mediated by I2/TBHP/NaN3 under metal-free conditions and a catalytic amount of NaN3 plays a crucial role in the reaction. Furthermore, the reaction tolerates a broad substrate scope with average to excellent yields.

Treatment of reverse osmosis membrane by sodium hypochlorite and alcohols for enhanced performance using the swelling-fastening effect.

Chemicals soaking is generally acknowledged as a convenient and efficient method to improve the performance of reverse osmosis (RO) membranes. The conventional soaking of RO membranes in alkaline sodium hypochlorite (NaClO) usually promotes extensive hydrolysis and cleavage amide bonds, resulting in improved water flux but declined salt rejection. Here, alcohols were added into the NaClO solution to regulate the chlorination processes using their "swelling-fastening" effect. The alcohols could interact with polyamide chains, and thus swell the polyamide network. Due to this interaction, the NaClO has less probability of attacking the polyamide chains. Hence, the chlorine-promoted hydrolysis was partly eased, which could weaken the decrease of salt rejection. Besides, after removing alcohols as well as the dissolved small oligomers and fragments of polyamide, the network was compacted and the loosened sites were healed, which is also beneficial to increase the difficulty of salt penetration. The treatment of RO membrane by the NaClO and alcohols could produce a hydrophilic surface with increased water flux and high salt rejection. The membrane chloridized at 2000 ppm NaClO exhibited a water flux improvement of 20.28% and a salt rejection declination of 0.95%. When treated with 2000 ppm NaClO associated with 5% methanol, the water flux improved 20.13% with little declination in salt rejection.

Full experimental determination of tunneling time with attosecond-scale streaking method.

Tunneling is one of the most fundamental and ubiquitous processes in the quantum world. The question of how long a particle takes to tunnel through a potential barrier has sparked a long-standing debate since the early days of quantum mechanics. Here, we propose and demonstrate a novel scheme to accurately determine the tunneling time of an electron. In this scheme, a weak laser field is used to streak the tunneling current produced by a strong elliptically polarized laser field in an attoclock configuration, allowing us to retrieve the tunneling ionization time relative to the field maximum with a precision of a few attoseconds. This overcomes the difficulties in previous attoclock measurements wherein the Coulomb effect on the photoelectron momentum distribution has to be removed with theoretical models and it requires accurate information of the driving laser fields. We demonstrate that the tunneling time of an electron from an atom is close to zero within our experimental accuracy. Our study represents a straightforward approach toward attosecond time-resolved imaging of electron motion in atoms and molecules.