Widely-Tunable Quantum Cascade-Based Sources for the Development of Optical Gas Sensors.

Spectroscopic techniques based on Distributed FeedBack (DFB) Quantum Cascade Lasers (QCL) provide good results for gas detection in the mid-infrared region in terms of sensibility and selectivity. The main limitation is the QCL relatively low tuning range (~10 cm-1) that prevents from monitoring complex species with broad absorption spectra in the infrared region or performing multi-gas sensing. To obtain a wider tuning range, the first solution presented in this paper consists of the use of a DFB QCL array. Tuning ranges from 1335 to 1387 cm-1 and from 2190 to 2220 cm-1 have been demonstrated. A more common technique that will be presented in a second part is to implement a Fabry-Perot QCL chip in an external-cavity (EC) system so that the laser could be tuned on its whole gain curve. The use of an EC system also allows to perform Intra-Cavity Laser Absorption Spectroscopy, where the gas sample is placed within the laser resonator. Moreover, a technique only using the QCL compliance voltage technique can be used to retrieve the spectrum of the gas inside the cavity, thus no detector outside the cavity is needed. Finally, a specific scheme using an EC coherent QCL array can be developed. All these widely-tunable Quantum Cascade-based sources can be used to demonstrate the development of optical gas sensors.

Gigabit free-space multi-level signal transmission with a mid-infrared quantum cascade laser operating at room temperature.

Gigabit free-space transmissions are experimentally demonstrated with a quantum cascaded laser (QCL) emitting at mid-wavelength infrared of 4.65 µm, and a commercial infrared photovoltaic detector. The QCL operating at room temperature is directly modulated using on-off keying and, for the first time, to the best of our knowledge, four- and eight-level pulse amplitude modulations (PAM-4, PAM-8). By applying pre- and post-digital equalizations, we achieve up to 3 Gbit/s line data rate in all three modulation configurations with a bit error rate performance of below the 7% overhead hard decision forward error correction limit of 3.8×10-3. The proposed transmission link also shows a stable operational performance in the lab environment.

Low-loss Ge-rich Si0.2Ge0.8 waveguides for mid-infrared photonics.

We demonstrate low-loss Ge-rich Si0.2Ge0.8 waveguides on Si1-xGex (x from 0 to 0.79) graded substrates operating in the mid-infrared wavelength range at λ=4.6 µm. Propagation losses as low as (1.5±0.5)dB/cm and (2±0.5)dB/cm were measured for the quasi-TE and quasi-TM polarizations, respectively. A total coupling loss (input/output) of only 10 dB was found for waveguide widths larger than 7 µm due to a good fiber-waveguide mode matching. Near-field optical mode profiles measured at the output waveguide facet allowed us to inspect the optical mode and precisely measure the modal effective area of each waveguide providing a good correlation between experiments and simulations. These results put forward the potential of low-index-contrast Si1-xGex waveguides with high Ge concentration as fundamental blocks for mid-infrared photonic integrated circuits.

Comparative study of SiO2, Si3N4 and TiO2 thin films as passivation layers for quantum cascade lasers.

The aim of this article is to determine the best dielectric between SiO2, Si3N4 and TiO2 for quantum cascade laser (QCL) passivation layers depending on the operation wavelength. It relies on both Mueller ellipsometry measurement to accurately determine the optical constants (the refractive index n and the extinction coefficient k) of the three dielectrics, and optical simulations to determine the mode overlap with the dielectric and furthermore the modal losses in the passivation layer. The impact of dielectric thermal conductivities are taken into account and shown to be not critical on the laser performances.

Highly birefringent chalcogenide optical fiber for polarization-maintaining in the 3-8.5 µm mid-IR window.

A highly birefringent polarization-maintaining chalcogenide microstructured optical fiber (MOF) covering the 3-8.5 µm wavelength range has been realized for the first time. The fiber cross-section consists of 3 rings of circular air holes with 2 larger holes adjacent to the core. Birefringence properties are calculated by using the vector finite-element method and are compared to the experimental ones. The group birefringence is 1.5x10-3 and fiber losses are equal to 0.8 dB/m at 7.55 µm.

Mid-infrared wavelength multiplexer in InGaAs/InP waveguides using a Rowland circle grating.

We report the monolithic integration of a 15-channel multiplexer on indium phosphide. It covers the 7.1-to-8.5 µm wavelength range suitable for combining the outputs of several individual lasers. The fabrication is compatible with the growth of active layers, therefore enabling a fully integrate broadband laser source in the mid-infrared spectral range. Channels are accurately spaced in wavelength (97 nm) in good agreement with design.

Design, fabrication and characterization of an AWG at 4.5 µm.

In this paper, we present the design, the fabrication and the characterization of an Arrayed Waveguide Grating (AWG) based on a SiGe graded index waveguide platform, operating at 4.5 µm. These devices were specifically designed to work together with an array of Distributed Feedback Bragg Quantum Cascade Lasers (DFB-QCL) emitting at different wavelengths. The AWG enables to combine the different light sources into a single output and the design adopted allows to maximize transmission over the entire spectral range defined by the array of DFB-QCLs.

Low loss SiGe graded index waveguides for mid-IR applications.

In the last few years Mid InfraRed (MIR) photonics has received renewed interest for a variety of commercial, scientific and military applications. This paper reports the design, the fabrication and the characterization of SiGe/Si based graded index waveguides and photonics integrated devices. The thickness and the Ge concentration of the core layer were optimized to cover the full [3 - 8 µm] band. The developed SiGe/Si stack has been used to fabricate straight waveguides and basic optical functions such as Y-junction, crossings and couplers. Straight waveguides showed losses as low as 1 dB/cm at λ = 4.5 µm and 2 dB/cm at 7.4 µm. Likewise straight waveguides, basic functions exhibit nearly theoretical behavior with losses compatible with the implementation of more complex functions in integrated photonics circuits. To the best of our knowledge, the performances of those Mid-IR waveguides significantly exceed the state of the art, confirming the feasibility of using graded SiGe/Si devices in a wide range of wavelengths. These results represent a capital breakthrough to develop a photonic platform working in the Mid-IR range.

30% improvement in absorption spectroscopy detectivity achieved by the detuned loading of a quantum cascade laser.

We perform a direct absorption spectroscopy experiment of carbon monoxide at 2193 cm(-1) by exploring the detectivity improvement potential of an intensity noise (IN)-reduced distributed feedback (DFB) quantum cascade laser. This was achieved by a detuned loading approach via a short, phase-sensitive optical feedback cavity. Under optimum IN reduction conditions, we obtain an improvement in signal-to-noise ratio from 733 to 1048, which transfers into a detection limit improvement from 1.2 ppm to 840 ppb. Therefore, we achieve a 30% lower detection limit, with the IN reduced when compared to the free-running case.

Private communication with quantum cascade laser photonic chaos.

Mid-infrared free-space optical communication has a large potential for high speed communication due to its immunity to electromagnetic interference. However, data security against eavesdroppers is among the obstacles for private free-space communication. Here, we show that two uni-directionally coupled quantum cascade lasers operating in the chaotic regime and the synchronization between them allow for the extraction of the information that has been camouflaged in the chaotic emission. This building block represents a key tool to implement a high degree of privacy directly on the physical layer. We realize a proof-of-concept communication at a wavelength of 5.7 µm with a message encryption at a bit rate of 0.5 Mbit/s. Our demonstration of private free-space communication between a transmitter and receiver opens strategies for physical encryption and decryption of a digital message.