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Waste wood, which has a large amount of cellulose fibers, should be transformed into useful materials for addressing environmental and resource problems. Thus, this study analyzed the application of waste wood as supercapacitor electrode material. First, cellulose fibers were extracted from waste wood and mixed with different contents of graphene nanoplatelets (GnPs) in water. Using a facile filtration method, cellulose papers with GnPs were prepared and converted into carbon papers through carbonization and then to porous activated carbon papers containing GnPs (ACP-GnP) through chemical activation processes. For the morphology of ACP-GnP, activated carbon fibers with abundant pores were formed. The increase in the amount of GnPs attached to the fiber surfaces decreased the number of pores. The Brunauer-Emmett-Teller surface areas and specific capacitance of the ACP-GnP electrodes decreased with an increase in the GnP content. However, the galvanostatic charge-discharge curves of ACPs with higher GnP contents gradually changed into triangular and linear shapes, which are associated with the capacitive performance. For example, ACP with 15 wt% GnP had a low mass transfer resistance and high charge delivery of ions, resulting in the specific capacitance value of 267 Fg-1 owing to micropore and mesopore formation during the activation of carbon paper.
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The development of multicomponent materials is the most efficient and successful way for creating advanced multifunctional catalysts. Herein, the bimetal FeCo nanoarrays enclosed N-CNTs have a high surface on carbon cloth support, which promotes efficient electron transport and prevents nanoparticle aggregation. Taking advantage of the high-level use of active material and fast charge transfer, the developed electrocatalyst exhibits excellent multifunctional electrocatalyst such as oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER). The N-CNTs@MOF FeCo nanoarrays @CC exhibit higher activity than reference catalysts including MOF FeCo nanoarrays@CC, FeCo nanoarrays@CC, and CC. Interestingly, the synthesized multifunctional catalyst, which serves as the air electrode in zinc-air batteries with liquid electrolytes as well as solid-state gel electrolytes possesses outstanding charging-discharge performance and long service life. This study provides enormous potential for the real implementation of portable, even wearable, and efficient rechargeable batteries in the future.
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The structural design of transition metal-based electrode materials with gigantic energy storage capabilities is a crucial task. In this work, we report an assembly of thin layered double hydroxide (LDH) nanosheets arrayed throughout the luminal and abluminal parts of polypyrrole tunnels fastened onto both sides of a carbon cloth as a battery-type energy storage system. Electron microscopy images reveal that the resulting electrode (NiCo-LDH@H-PPy@CC, where H-PPy@CC represents carbon cloth-supported hollow polypyrrole fibers) is constructed by combining luminal and abluminal NiCo-LDH nanosheets onto a long polypyrrole tunnel on a carbon cloth. The primary sample shows an excellent specific capacity of 149.16 mAh g-1 at 1.0 mA cm-2, a remarkable rate capability of 80.45%, and comprehensive cyclic stability (93.4%). The improved performance is mainly attributed to the strategic organization of the electrode materials with superior Brunauer-Emmett-Teller (BET) surface area and conductivity. Moreover, an asymmetric supercapacitor device assembled with NiCo-LDH@H-PPy@CC and vanadium phosphate-incorporated carbon nanofiber (VPO@CNFs900) electrodes contributes a specific energy density of 32.42 Wh kg-1 at 3 mA cm-2 with a specific power density of 359.16 W kg-1. When the current density is increased by 6-fold, the specific power density reaches 1999.89 W kg-1 at a specific energy density of 20.06 Wh kg-1. This is a simple, cost-effective, and convenient synthetic strategy for the synthesis of porous nanosheet arrays assimilated into hollow fiber architectures, which can illuminate the ideal approach for the fabrication of novel materials with an immense potential for energy storage.
RESUMO
The hurdle of fabricating asymmetric supercapacitor (ASC) devices using a faradic cathode and a double layer anode is challenging due to the required large amount of active mass of anodic material compared to that of the cathodic material during mass balancing due to the large difference in capacitance values of the two electrodes. Here, the problem is addressed by engineering a negative electrode that furnishes an ultrahigh capacitance. An in situ developed metal-organic framework (MOF)-based thermal treatment is adopted to grow highly porous N-doped carbon nanotubes (CNTs) containing submerged Co nanoparticles over nano-fibrillated electrospun hollow carbon nanofibers (HCNFs). The optimized CNT@HCNF-1.5 furnishes an ultrahigh capacitance approaching 712 F g-1 with excellent rate capability. The capacitance reported from this work is the highest for any carbonaceous material reported to date. The CNT@HCNF-1.5 is further used to fabricate symmetric supercapacitors (SSCs), as well as ASC devices. Remarkably, both the SSC and ASC devices furnish incredible performances in all aspects of SCs, such as a high energy density, long cycle life, and high rate capability, displaying decent practical applicability. The energy density of the SSC device reaches as high as 20.13 W h kg-1 , whereas that of ASC approaches 87.5 W h kg-1 .
RESUMO
The fabrication of an economic and efficient multifunctional advanced nanomaterial with a rational composition and configuration by a facile methodology is a crucial challenge. Herein, we are the first to report the growth of Co nanoparticle-integrated nitrogen-doped carbon nanotubes (N-CNTs) on porous carbon nanofibers by simply heating in the situ-developed metal-organic framework (MOF)-based electrospun nanofibrous membrane with no need for an external supply of any additional precursors and reducing gases. The long and entangled N-CNTs originating from highly porous and graphitic carbon nanofibers offer good flexibility, large surface area, high porosity, high conductivity, the homogeneous incorporation of heteroatoms and metallic constituents, and an abundant exposure of active nanocatalytic sites. The as-developed nanoassembly demonstrates attractive characteristics for electrocatalytic hydrogen and oxygen evolution reactions and electrochemical energy storage. This strategy of integrating the essence of an MOF with electrospinning offers a new, direct, and cost-effective approach for making N-doped CNT-based multifunctional membranes.
RESUMO
White-light-emitting materials have received significant attention because of their potential application in lighting, displays, and sensors. However, it is a challenge to obtain white light from one phosphor, because the basic requirement of the white light emission spectrum is that it should be wide enough to cover the entire visible light region. In this study, we have designed and demonstrated a white-light-emitting PMMA-CBS-127/PVP-coumarin 6/PAN-rhodamine B (PSCR) fibrous membrane, which was prepared through a triphasic electrospinning method. Three luminescent organic dyes, CBS-127 (4.77 wt%, blue), coumarin 6 (0.1 wt%, green), and rhodamine B (0.42 wt%, red), were elaborately selected and doped into PMMA, PVP, and PAN, respectively. The resulting flexible PSCR membranes show white light emission (cover the entire visible-light region from 382 to 700 nm) with Commission Internationale de L'Eclairage (CIE) coordinates of (0.31, 0.32), which is very close to ideal white light with CIE coordinates (0.33, 0.33). In addition, the PSCR membranes maintained high-quality white light emission after about 10 weeks of storage. The PSCR membranes can be used as the phosphor converting layer in white light-emitting diodes (WLEDs) through a remote membrane packaging method. A bright white emission is achieved at an applied voltage of 9 V. Therefore, the results indicate that PSCR membranes are potentially attractive candidates for application in WLEDs and displays.
RESUMO
Transition metal phosphate (TMPi)-based composites as anode electrode materials in supercapacitor applications are less reported. Herein, we report a phytic acid (PA)-assisted in situ-formed amorphous cobalt phosphate/carbon (CoPi/C) composite grown on a flexible woven carbon cloth (CC) via a simple one-step carbonization approach. The tunable synthesis of amorphous and crystalline composites is shown by simply controlling the concentration of the cobalt salts. The strategy for high mass loading to 12 mg cm-2 is also shown in this report. Importantly, the resulting amorphous electrode materials exhibit electric double-layer capacitance (EDLC) behavior that works over a wide potential range from -1.4 to +0.5 V in an aqueous solution of potassium hydroxide (2 M KOH) and from -1.5 to +1.5 V in sodium sulfate (1 M Na2SO4). The amorphous electrode as an anode is capable of delivering an areal capacitance up to 2.15 F cm-2 at a current density of 4 mA cm-2 (gravimetric capacitance up to 606.1 F g-1 at 1 Ag-1) and has a retention of 94.2% at 10 000 cycles. The flexible solid-state symmetric device fabricated shows an energy density of approximately 620.0 µW h cm-2 at a power density of 4.7 mW cm-2 (31.1 W h kg-1 at 476.0 W kg-1). This study offers a novel route for the generation of metal phosphate-based anode materials with high capacitance for symmetrical supercapacitor device with high energy density.
RESUMO
Herein, we outline the fabrication of highly porous three-dimensional carbon-fiber network anchored with uniform metallic cobalt (Co) via electrospinning and subsequent post-modification approaches. First, cobalt acetate solution saturated electrospun polyacrylonitrile (PAN) nanofibrous mat was subjected to sodium borohydride (NaBH4) solution which results in the fabrication of three dimensional (3D) hierarchical multilayer network. Restructuring of the 2D mat into multilayered sponges with metal particles entrapment is attributed to the in-situ generated hydrogen gas into the interconnected pores of the fibrous network simultaneous with reduction of cobalt salt into metallic cobalt by NaBH4. The resulting mesh was stabilized and carbonization at inert atmosphere to obtain metallic cobalt (Co) embedded 3D carbon nanofibrous networks (Co@3D-CNFs). Physicochemical characterization and electrochemical analysis were performed. Results show carbon network was found to be expanded with bubbling like structures often embedded metallic Co nanoparticles. X-ray diffraction (XRD) pattern confirms the existence of the metallic cobalt particles on the carbon fiber networks. Furthermore, we establish a resulting composite (Co@3D-CNFs) identify the enhanced electrochemical performance having specific capacitance 762 Fâ¯g-1 compared to 173 and 180 Fâ¯g-1 for corresponding @3D-CNFs and 2D carbon nanofiber network with cobalt doped (Co@2D-CNFs) counterparts, respectively. The assembled Co2@3D-CNFs//NGH ASC device exhibits a high energy density 24.6â¯Wâ¯hâ¯Kg-1 at 797â¯Wâ¯kg-1 power density with an operating voltage of 1.6â¯V (vs Ag/AgCl). The device further shows good capacitance retention (90.1%) after 5000 cycles. This research shows the simple and cost-effective strategy to make metallic particles embedded 3D porous carbonaceous electrode materials which can have great potential for energy storage application.
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Carbon foams were prepared by carbonization of carboxymethyl cellulose (CMC)/waste artificial marble powder (WAMP) composites obtained via electron beam irradiation (EBI); these composites were prepared by mixing eco-friendly CMC with WAMP as the fillers for improved their poor mechanical strength. Gel fractions of the CMC/WAMP composites obtained at various EBI doses were investigated, and it was found that the CMC/WAMP composites obtained at an EBI dose of 80 kGy showed the highest gel fraction (95%); hence, the composite prepared at this dose was selected for preparing the carbon foam. The thermogravimetric analysis of the CMC/WAMP composites obtained at 80 kGy; showed that the addition of WAMP increased the thermal stability and carbon residues of the CMC/WAMP composites at 900 °C. SEM images showed that the cell walls of the CMC/WAMP carbon foams were thicker more than those of the CMC carbon foam. In addition, energy dispersive X-ray spectroscopy showed that the CMC/WAMP carbon foams contained small amounts of aluminum, derived from WAMP. The results confirmed that the increased WAMP content and hence increased aluminum content improved the thermal conductivity of the composites and their corresponding carbon foams. Moreover, the addition of WAMP increased the compressive strength of CMC/WAMP composites and hence the strength of their corresponding carbon foams. In conclusion, this synthesis method is encouraging, as it produces carbon foams of pore structure with good mechanical properties and thermal conductivity.
RESUMO
The heat generated from electronic devices such as light emitting diodes (LEDs), batteries, and highly integrated transistors is one of the major causes obstructing the improvement of their performance and reliability. Herein, we report a comprehensive method to dissipate the generated heat to a vast area by using the new type of graphene-carbon-metal composite film as a heat sink. The unique porous graphene-carbon-metal composite film that consists of an electrospun carbon nanofiber with arc-graphene (Arc-G) fillers and an electrochemically deposited copper (Cu) layer showed not only high electrical and thermal conductivity but also high mechanical stability. Accordingly, superior thermal management of LED devices to that of conventional Cu plates and excellent resistance stability during the repeated 10â¯000 bending cycles has been achieved. The heat dissipation of LEDs has been enhanced by the high heat conduction in the composite film, heat convection in the air flow, and thermal radiation at low temperature in the porous carbon structure. This result reveals that the graphene-carbon-metal composite film is one of the most promising materials for a heat sink of electronic devices in modern electronics.