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1.
Meteorit Planet Sci ; 55(11): 2341-2359, 2020 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-33510569

RESUMO

The Hamburg meteorite fell on January 16, 2018, near Hamburg, Michigan, after a fireball event widely observed in the U.S. Midwest and in Ontario, Canada. Several fragments fell onto frozen surfaces of lakes and, thanks to weather radar data, were recovered days after the fall. The studied rock fragments show no or little signs of terrestrial weathering. Here, we present the initial results from an international consortium study to describe the fall, characterize the meteorite, and probe the collision history of Hamburg. About 1 kg of recovered meteorites was initially reported. Petrology, mineral chemistry, trace element and organic chemistry, and O and Cr isotopic compositions are characteristic of H4 chondrites. Cosmic ray exposure ages based on cosmogenic 3He, 21Ne, and 38Ar are ~12 Ma, and roughly agree with each other. Noble gas data as well as the cosmogenic 10Be concentration point to a small 40-60 cm diameter meteoroid. An 40Ar-39Ar age of 4532 ± 24 Ma indicates no major impact event occurring later in its evolutionary history, consistent with data of other H4 chondrites. Microanalyses of phosphates with LA-ICPMS give an average Pb-Pb age of 4549 ± 36 Ma. This is in good agreement with the average SIMS Pb-Pb phosphate age of 4535.3 ± 9.5 Ma and U-Pb Concordia age of 4535 ± 10 Ma. The weighted average age of 4541.6 ± 9.5 Ma reflects the metamorphic phosphate crystallization age after parent body formation in the early solar system.

2.
J Mass Spectrom ; 55(6): e4511, 2020 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-32219912

RESUMO

Methods are presented for rapid determination of relative efficiencies of Faraday cups in a multicollector array with movable cups and of Daly or electron multiplier detector dead time and gain values. The Faraday calibration approach is based on measuring the same isotopic ratio in two sequences with different collector configurations having one collector in common. Changes in thermal fractionation during the two measurement sequences are monitored using the same two collectors. Since the relative efficiencies are determined by measuring the same ratio in different cups corrected for time-dependent changes in fractionation, it is unnecessary to use a standard of known composition and calculations are simple, not requiring the solution of multiple equations. Determination of dead time and gain values for a Daly detector are shown based on multidynamic measurements of masses 207, 206, and 208 from Pb standard SRM982 in two sequences consisting of L1-Daly-H1 and Daly-H1-H2. This provides two equations that can be solved for Daly dead time and gain. This method uses static measurements and is therefore insensitive to signal instability. It also does not require use of a standard of known isotopic composition. The potential of using known cup efficiencies to help determine absolute isotopic abundances is discussed.

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