Mechanical properties of nanofilled and microhybrid composites cured by different light polymerization modes.

This study compared nanofilled and microhybrid composites polymerized by different light polymerization modes, and the effects these modes had on the mechanical properties of the composites. The following mechanical properties were measured: Vickers microhardness numbers, diametral tensile strength, flexural strength, and flexural modulus. The filler content (Wt%) present in the resins was investigated. Data were treated statistically by ANOVA and Tukey's test (P ≤ 0.05) and the interaction of the inorganic content with the mechanical properties was analyzed by Pearson's correlation (P ≤ 0.05). The nanofilled material showed a higher percentage of inorganic filler and better mechanical properties when compared to the microhybrid composite. The correlation of Wt% with the tested properties was positive for all but the flexural strength test. Different light polymerization modes were shown not to have a significant influence on the mechanical properties of the composites in this study.

Manufacture and Characterization of Polypropylene (PP) and High-Density Polyethylene (HDPE) Blocks for Potential Use as Masonry Component in Civil Construction.

The lack of suitable destinations for plastics materials can be a global environmental problem. The alternative use of materials for sustainable construction encourages the standardization of waste and promotes effective social, environmental and economic gains at the local level and ensures savings and income for communities. The aim of this paper is the development, manufacture, and characterization of PP and HDPE recycled polyolefin blocks as masonry components in civil construction. These blocks were manufactured by the rotational molding process. Besides this, the mechanical, physical, impact and flammability properties of the blocks were studied. In conclusion, HDPE showed better behavior than PP in tests realized.

Characterization and Biotechnological Potential of Intracellular Polyhydroxybutyrate by Stigeoclonium sp. B23 Using Cassava Peel as Carbon Source.

The possibility of utilizing lignocellulosic agro-industrial waste products such as cassava peel hydrolysate (CPH) as carbon sources for polyhydroxybutyrate (PHB) biosynthesis and characterization by Amazonian microalga Stigeoclonium sp. B23. was investigated. Cassava peel was hydrolyzed to reducing sugars to obtain increased glucose content with 2.56 ± 0.07 mmol/L. Prior to obtaining PHB, Stigeoclonium sp. B23 was grown in BG-11 for characterization and Z8 media for evaluation of PHB nanoparticles' cytotoxicity in zebrafish embryos. As results, microalga produced the highest amount of dry weight of PHB with 12.16 ± 1.28 (%) in modified Z8 medium, and PHB nanoparticles exerted some toxicity on zebrafish embryos at concentrations of 6.25-100 µg/mL, increased mortality (<35%) and lethality indicators as lack of somite formation (<25%), non-detachment of tail, and lack of heartbeat (both <15%). Characterization of PHB by scanning electron microscopy (SEM), X-ray diffraction (XRD), differential scanning calorimeter (DSC), and thermogravimetry (TGA) analysis revealed the polymer obtained from CPH cultivation to be morphologically, thermally, physically, and biologically acceptable and promising for its use as a biomaterial and confirmed the structure of the polymer as PHB. The findings revealed that microalgal PHB from Stigeoclonium sp. B23 was a promising and biologically feasible new option with high commercial value, potential for biomaterial applications, and also suggested the use of cassava peel as an alternative renewable resource of carbon for PHB biosynthesis and the non-use of agro-industrial waste and dumping concerns.

Biosynthesis, characterization and leishmanicidal activity of a biocomposite containing AgNPs-PVP-glucantime.

AIM: Development of functionalized nanocomposites containing AgNPs-PVP-Glucantime® to evaluate their leishmanicidal activity as a novel method for improving the pharmacological properties of the drug Glucantime® against extracellular promastigotes and intracellular amastigotes of Leishmania amazonensis in vitro to treat cutaneous leishmaniasis. MATERIALS & METHODS: The silver nanoparticles and nanocomposites prepared containing silver nanoparticles, polyvinylpyrrolidone and different amounts of Glucantime were characterized using transmission electron microscopy, x-ray diffraction, energy-dispersive x-ray spectroscopy and ζ potential analysis; in addition, the in vitro cytotoxicity was evaluated. RESULTS: The nanocomposites showed an inhibitory effect on the cellular viability of promastigote forms, with values of 47.06, 51.71 and 65.67% for nanocomposite1, nanocomposite2 and nanocomposite3, respectively, as well as a dose-dependent decrease in the infectivity index, with values of 33.33 and 23% for nanocomposite2 and nanocomposite3, respectively. CONCLUSION: The proposed nanocomposite reveals leishmanial activity and the absence of cytotoxicity in macrophages. Further investigations will be conducted in vivo.

Cleansing orthodontic brackets with air-powder polishing: effects on frictional force and degree of debris.

INTRODUCTION: Debris buildup on the bracket-wire interface can influence friction. Cleansing brackets with air-powder polishing can affect this process. OBJECTIVE: The aim of this study was to evaluate the frictional force and amount of debris remaining on orthodontic brackets subjected to prophylaxis with air-powder polishing. METHODS: Frictional force and debris buildup on the surface of 28 premolar brackets were evaluated after orthodontic treatment. In one hemiarch, each bracket was subjected to air-powder polishing (n = 14) for five seconds, while the contralateral hemiarch (n = 14) served as control. Mechanical friction tests were performed and images of the polished bracket surfaces and control surfaces were examined. Wilcoxon test was applied for comparative analysis between hemiarches at p < 0.05. RESULTS: Brackets that had been cleaned with air-powder polishing showed lower friction (median = 1.27 N) when compared to the control surfaces (median = 4.52 N) (p < 0.01). Image analysis showed that the control group exhibited greater debris buildup (median = 2.0) compared with the group that received prophylaxis with air-powder polishing (median = 0.5) (p < 0.05). CONCLUSION: Cleansing orthodontic brackets with air-powder polishing significantly reduces debris buildup on the bracket surface while decreasing friction levels observed during sliding mechanics.

Evaluation of physical-mechanical properties of self-adhesive versus conventional resin cements

Aim: The purpose of this study was to compare the microhardness, diametral tensile strength, compressive strength and the rheological properties of self-adhesive versus conventional resin cements. Methods: Specimens of a conventional (RelyX ARC) and 3 self-adhesive (RelyX U200, Maxcem Elite, Bifix SE) types of resin cements were prepared. The Knoop test was used to assess the microhardness, using a Microhardness Tester FM 700. For the diametral tensile strength test, a tensile strength was applied at a speed of 0.6 mm/minute. A universal testing machine was used for the analysis of compressive strength and a thermo-controlled oscillating rheometer was used for the Rheology test. One-way ANOVA and Tukey's test (α=0.05) were used for data analysis. Results:According to microhardness analysis, all the cements were statistically similar (p>0.05), except for Maxcem that presented lower hardness compared with the other cements in relation to the top surface (p<0.05). In the diametral tensile strength test, Relyx U200 and RelyX ARC cements were statistically similar (p>0.05), presented higher value when compared to the Maxcem and Bifix cements (p<0.05). The compressive strength of RelyX ARC and Maxcem Elite cements was statistically higher than RelyX U200 and Bifix cements (p<0.05). Regarding the rheology test, Maxcem Elite and RelyX ARC cements showed a high modulus of elasticity. Conclusions: The self-adhesive cements presented poorer mechanical properties than conventional resin cement. Chemical structure and types of monomers employed interfere directly in the mechanical properties of resin cements

Cleansing orthodontic brackets with air-powder polishing: effects on frictional force and degree of debris

ABSTRACT Introduction: Debris buildup on the bracket-wire interface can influence friction. Cleansing brackets with air-powder polishing can affect this process. Objective: The aim of this study was to evaluate the frictional force and amount of debris remaining on orthodontic brackets subjected to prophylaxis with air-powder polishing. Methods: Frictional force and debris buildup on the surface of 28 premolar brackets were evaluated after orthodontic treatment. In one hemiarch, each bracket was subjected to air-powder polishing (n = 14) for five seconds, while the contralateral hemiarch (n = 14) served as control. Mechanical friction tests were performed and images of the polished bracket surfaces and control surfaces were examined. Wilcoxon test was applied for comparative analysis between hemiarches at p < 0.05. Results: Brackets that had been cleaned with air-powder polishing showed lower friction (median = 1.27 N) when compared to the control surfaces (median = 4.52 N) (p < 0.01). Image analysis showed that the control group exhibited greater debris buildup (median = 2.0) compared with the group that received prophylaxis with air-powder polishing (median = 0.5) (p < 0.05). Conclusion: Cleansing orthodontic brackets with air-powder polishing significantly reduces debris buildup on the bracket surface while decreasing friction levels observed during sliding mechanics.

RESUMO Introdução: o acúmulo de detritos na interface braquete-arco pode influenciar no atrito, mas a limpeza dos braquetes usando jatos de bicarbonato de sódio pode interferir nesse processo. Objetivo: o objetivo desse estudo foi avaliar a força de atrito e a quantidade de detritos remanescentes em braquetes ortodônticos submetidos à profilaxia com jatos de bicarbonato de sódio. Material e Métodos: avaliou-se, ao final do tratamento ortodôntico, a força de atrito e o acúmulo de detritos na superfície de 28 braquetes de pré-molares. Em uma hemiarcada, os braquetes foram jateados com bicarbonato de sódio (n = 14) por 5 segundos, enquanto a hemiarcada contralateral serviu de controle (n = 14). Foram realizados ensaios mecânicos de atrito e análise imagiológica dos braquetes de ambas as hemiarcadas, a jateada e a controle. O teste de Wilcoxon foi utilizado para a análise comparativa entre as hemiarcadas, com p < 0,05. Resultados: os braquetes submetidos à limpeza com jatos de bicarbonato de sódio apresentaram menor atrito (mediana = 1,27N), quando comparados aos do lado controle (mediana = 4,52N) (p < 0,01). A análise imagiológica demonstrou que o grupo controle apresentou maior acúmulo de detritos (mediana = 2,0), em comparação ao grupo que recebeu profilaxia com jatos de bicarbonato (mediana = 0,5) (p < 0,05). Conclusão: a limpeza dos braquetes ortodônticos por meio do jateamento com bicarbonato de sódio reduz significativamente o acúmulo de detritos na superfície deles, bem como os níveis de atrito observados durante a mecânica de deslizamento.