RESUMO
Developing solid polymer electrolytes (SPEs) is a promising approach to realize practical dendrite-free lithium metal batteries (LMBs). Tuning the nanoscale polymer network chemsitry is of critical importance for SPE design. In this work, we took lessons from the rubber chemistry and developed a series of comb-chain crosslinker-based SPEs (ConSPEs) using a preformed polymer as the multifunctional crosslinker. The high-functionality crosslinker increased the connectivity of nanosized cross-linked domains, which led to a robust network with dramatically improved toughness and superior lithium dendrite resistance even at a current density of 2 mA cm-2. The uniform and flexile network also dramatically improved the anodic stability to over 5.3 V versus Li/Li+. Additive-free, all-solid-state LMBs with the ConSPE showed high discharge capacity and stable cycling up to 10 C rate, and could be stably cycled at 25 °C. Our results demonstrated that ConSPEs are promising for high-performance and dendrite-free LMBs.
RESUMO
Ternary complexes formed in a single pot process through the mixing of cationic (branched polyethylenimine, BPEI) and anionic (graphene oxide, GO, and poly(acrylic acid), PAA) aqueous solutions exhibit superior mechanical performance in comparison to their binary analogs. The composition of the ternary complex can be simply tuned through the composition of the anionic solution, which influences the water content and mechanical properties of the complex. Increasing the PAA content in the complex decreases the overall water content due to improved charge compensation with the BPEI, but this change also significantly improves the toughness of the complex. Ternary complexes containing ≤32 wt% PAA were too brittle to generate samples for tensile measurements, while extension in excess of 250% could be reached with 57 wt% PAA. From this work, the influence of GO and PAA on the mechanical properties of GO/PAA/BPEI complexes were elucidated with GO sheets acting to restrain the viscous flow and improve the mechanical strength at low loading (<12.6 wt%) and PAA more efficiently complexes with BPEI than GO to generate a less swollen and stronger network. This combination overcomes the brittle nature of GO-BPEI complexes and viscous creep of PAA-BPEI complexes. Ternary nanocomposite complexes appear to provide an effective route to toughen and strengthen bulk polyelectrolyte complexes.
RESUMO
Composite hydrogels containing graphene oxide (GO) offer advantageous mechanical properties, but tuning these properties generally requires the synthesis of new hydrogels or if the hydrogel is thermally responsive, utilization of a chemistry determined temperature window. Here, we demonstrate a simple route to generate a family of GO-based hydrogels from aqueous solution based assembly of GO with polycationic poly(ethylenimine), PEI, without any secondary chemical crosslinking. Tuning the ratio of GO : PEI during the assembly produces a family of hydrogels that responds to mechanical compression by irreversibly altering their equilibrium water content and mechanical properties in a controllable manner. Despite the lack of chemical crosslinks, the hydrogels are stable when stored in an excess of water or NaCl solutions (up to 1 M) and exhibit a tunable swelling ratio (mass hydrogel : mass solid) between 44 and 162 based on both composition and compression history. Consequently, the storage modulus from shear rheology can be increased by more than 3 orders of magnitude from this irreversible mechanical compression of the hydrogel. This stiffening of the hydrogels in response to mechanical stimuli enables the prior compression loading of the hydrogel to be determined. We demonstrate that this strategy is generalizable to other anionic 2D materials such as clay (cloisite). This family of mechanically adaptive hydrogels enables facile fabrication and tuning of physical properties that could be advantageous for sensing, energy dissipation, and other applications.
RESUMO
Plastic take-out food containers may release microplastics (MPs) into food and pose a potential risk to food safety and human health. Here, after being subjected to hot water treatment, MPs released from three types of plastic food containers (polypropylene, PP; polyethylene, PE; expanded polystyrene, EPS) were identified by micro-Raman spectroscopy. The results showed that the size of released MPs ranged from 0.8-38 µm and over 96% MPs were smaller than 10 µm. Various MPs concentrations were found from the three types of containers, that is, 1.90 × 104, 1.01 × 105, and 2.82 × 106 particles/L on average from PP, PE, and EPS, respectively. Moreover, based on thermal and morphology analysis, we discovered that both relaxations of the polymer chains in the rubbery state and defects caused by processing techniques might contribute to the release of MPs. Thus, such release can be reduced by increasing the thermal stability of the materials and mitigating the defects generated during production.