Compact high-power optical source for resonant infrared pulsed laser ablation and deposition of polymer materials.

We propose a novel tuneable table-top optical source as an alternative to the free electron laser currently used for resonant infrared pulsed laser deposition of polymers. It is based on two-stage pulsed optical parametric amplification using MgO doped periodically poled lithium niobate crystals. Gain in excess of 10(6) in the first stage and pump depletion of 58% in the second stage were achieved when the system was pumped by a high-power Nd:YVO(4) picosecond laser source at 1064 nm and seeded by a CW tuneable diode laser at 1530 nm. An average power of 2 W was generated at 3.5 microm corresponding to 1.3 microJ pulse energy.

Corrections to refractive index data of stoichiometric lithium tantalate in the 5-6 microm range.

We propose corrections to the coefficients in the published Sellmeier equation for stoichiometric LiTaO3 [Opt. Lett.28, 194 (2003)] that allow the extension of the wavelength range within the region of midinfrared absorption edge up to 6 microm. The required extraordinary refractive index data for this range were obtained using single-pass optical parametric fluorescence measurements with a pump wavelength of 1064.4 nm. We also observed efficient parasitic second-harmonic generation that could affect some quasi-phase-matching interactions. The corrected Sellmeier equation improves the accuracy of poling period calculations where the idler wavelength is within the region.