RESUMO
Food-processing wastewater (FPWW), as opposed to solid residues, occurs extensively throughout the world, and has considerable potential for resource recovery (RR), however, at present, it is severely underutilized. This paper serves as a suggested 'plan forward' to optimize integrated RR from FPWW. In order to optimize this potential and 'close the loop', there needs to be further development in in-depth analytical methods of the FPWW; axenic/mixed cultures or microbial communities capable of growing on FPWW and hence producing single-cell protein for animal feed and food additives; cost-effective methods for separating high-value-added solutes such as vitamins K2, B12, and B2; isoflavones and flavanones; integrated energy- and water-recovery flowsheets; and optimization methods to integrate RR and energy harvesting with minimal impact on the environment. Each of these areas is examined and future research directions are laid out.
Assuntos
Águas Residuárias , AnimaisRESUMO
Organic fraction municipal solid waste (OFMSW) has a high potential for energy and value-added product recovery due to its carbon- and nutrient-rich composition; however, traditional value chains have treated OFMSW as an undesired by-product. This study focuses on value chain optimisation to assist the transition to resource recovery value chains. To achieve this, this work combined two stage stochastic mathematical optimisation with geographical spatial analysis and time series waste generation analysis. Existing infrastructure in England, including anaerobic digestion plants and road transportation networks, were included in the model. To account for uncertainty in waste generation, multiple scenarios and their associated probabilities were developed based on environmental variables. The optimisation problem was solved to further advance the understanding of economically optimal waste-to-resource value chains under waste generation variability. The pertinent decision variables included sizing, technology selection, waste flows and location of thermochemical treatment sites. The model highlights the potential reduction in system profitability as a result of different operating constraints, such as minimum plant operating capacity factors and landfill taxation. The latter was shown to have the largest impact on profitability as overconservative systems designs were implemented to hedge against the waste variability. Such computer-aided models offer opportunities to overcome the challenges posed by waste generation variability and waste to resource value chain transformation.
RESUMO
Invited for this month's cover picture is the group of Dr Miao Guo from Department of Chemical Engineering at the Imperial College London (UK). The cover picture shows modelling research on the co-polymerisation of waste-sourced limonene oxide with CO2 to produce poly(limonene carbonate), which offers a sustainable pathway to achieve carbon capture and utilisation. A computational approach to process design was integrated with sustainability evaluation to model this synthetic pathway and identify the environmental-damaging and performance-limiting steps for further improvement. Our research highlights the potential of closed-loop manufacturing systems with waste recovery, which is instrumental in building a sustainable circular economy. Read the full text of their Full Paper at 10.1002/open.201900015.
RESUMO
Poly(limonene carbonate) (PLC) has been highlighted as an attractive substitute to petroleum derived plastics, due to its utilisation of CO2 and bio-based limonene as feedstocks, offering an effective carbon capture and utilisation pathway. Our study investigates the techno-economic viability and environmental sustainability of a novel process to produce PLC from citrus waste derived limonene, coupled with an anaerobic digestion process to enable energy cogeneration and waste recovery maximisation. Computational process design was integrated with a life cycle assessment to identify the sustainability improvement opportunities. PLC production was found to be economically viable, assuming sufficient citrus waste is supplied to the process, and environmentally preferable to polystyrene (PS) in various impact categories including climate change. However, it exhibited greater environmental burdens than PS across other impact categories, although the environmental performance could be improved with a waste recovery system, at the cost of a process design shift towards energy generation. Finally, our study quantified the potential contribution of PLC to mitigating the escape of atmospheric CO2 concentration from the planetary boundary. We emphasise the importance of a holistic approach to process design and highlight the potential impacts of biopolymers, which is instrumental in solving environmental problems facing the plastic industry and building a sustainable circular economy.