Synthesis of biochar from iron-free and iron-containing microalgal biomass for the removal of pharmaceuticals from water.

The contamination of natural water bodies with pharmaceutical compounds has raised significant concerns about ecological and public health safety. In this study, biochars were synthesized from iron-free microalgal biomass (harvested by centrifugation) and iron-containing microalgal biomass (harvested by coagulation) and tested for the adsorption of ciprofloxacin (CIP) and diclofenac (DIC) from water in batch and fixed-bed column continuous studies. The physicochemical properties of synthesized biochars were analyzed using Brunauer, Emmett and Teller (BET) surface area analyzer, elemental analyzer, Fourier Transformed Infrared spectroscopy (FTIR), X-ray Diffractometer (XRD), and Scanning electron microscope with energy dispersive spectroscopy (SEM-EDS). The maximum monolayer adsorption capacities of iron-containing biochar (FBC750W) and iron-free biochar (MBC750W) based on the Langmuir model were obtained as 75.97 mg/g and 39.08 mg/g for CIP, and 40.99 mg/g and 6.77 mg/g for DIC, respectively. Comparatively, maximum monolayer adsorption capacities of commercial activated carbon (C-AC) were found to be 50.97 mg/g and 46.39 mg/g for CIP and DIC, respectively. In fixed-bed column continuous adsorption studies, the effects of flow rate (1 and 2 mL/min) and the adsorbent amount (50 and 100 mg) on adsorption performance were evaluated. Column kinetic models, such as Bohart-Adams model and Fractal-like Bohart-Adams model were examined. The adsorption mechanisms were proposed as pore filling, π-π interaction, and electrostatic interaction. Overall, the results of this study revealed that microalgal biomass, harvested with FeCl3, can be used for the direct synthesis of iron-containing biochar for the removal of pharmaceuticals from water.

Synthesis and Characterization of a Magnetic Carbon Nanofiber Derived from Bacterial Cellulose for the Removal of Diclofenac from Water.

Engineering and synthesis of novel materials are vital for removing emerging pollutants, such as pharmaceuticals from contaminated water. In this study, a magnetic carbon nanofiber (MCF) fabricated from bacterial cellulose was tested for the adsorption of diclofenac from water. The physical and chemical properties of the synthesized adsorbent were examined by field emission scanning electron microscopy (FESEM), field emission transmission electron microscopy (FETEM), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) analysis, energy-dispersive X-ray spectroscopy (EDS), a vibrating sample magnetometer (VSM), Raman spectroscopy, and Fourier transform infrared (FTIR) spectroscopy. The characterization results showed that the MCF is a carbon nanofiber with a three-dimensional interconnect network, forming a porous material (mesopores and macropores) with a specific surface area of 222.3 m2/g. The removal of diclofenac (10 mg/L) by the MCF (0.75 g/L) was efficient (93.2%) and fast (in 20 min). According to the Langmuir isotherm model fitting, the maximum adsorption capacity of the MCF was 43.56 mg/g. Moreover, continuous adsorption of diclofenac onto MCF was investigated in a fixed-bed column, and the maximum adsorption capacity was found to be 67 mg/g. The finding of this research revealed that the MCF could be a promising adsorbent used to remove diclofenac from water, while it can be easily recovered by magnetic separation.

Bmim[OAc]-Cu2O/g-C3N4 as a multi-function catalyst for sonophotocatalytic degradation of methylene blue.

In this study, ionic liquid, 1-butyl-3-methylimidazolium acetate (Bmim[OAc]) modified cuprous oxide immobilized over graphitic carbon nitride (Bmim[OAc]-Cu2O/g-C3N4) as an efficient heterogeneous catalyst was successfully prepared by depositing Bmim[OAc]-Cu2O over the surface of g-C3N4. The deposition of cuprous oxide over the surface of g-C3N4 leads to the formation of a heterojunction that promotes the charge separation. Cu2O enhances the degradation capability owing to its dual function where it acts as a photocatalyst and Fenton like catalyst. Bmim[OAc] plays a vital role in trapping the photogenerated electrons, which in turn reduce the chances of electron-hole pairs recombination. Sonophotocatalytic degradation of methylene blue (MB) was investigated using the prepared Bmim[OAc]-Cu2O/g-C3N4 at room temperature and pH = 7 in presence of ultraviolet (UV, 6 W, λ = 254 nm) and ultrasonic (US, 20 kHz) as a dual irradiation system and H2O2 as an oxidant. Only 30 min of dual irradiation was enough for Bmim[OAc]-Cu2O/g-C3N4 (0.1 gL-1) to achieve a complete degradation using 10 mM H2O2 at 25 °C and pH = 7. The value of band gap of tested catalyst plays a vital role in boosting the degradation capability of the sonophotocatalytic system through the generated reactive radicals especially the hydroxyl radicals and superoxide radicals, which play a major role in the system. The kinetics of the reaction was investigated and the activation energy was calculated from the slope of the Arrhenius plot and found to be 19.77 kJ/mol.