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1.
Biomacromolecules ; 23(6): 2272-2279, 2022 06 13.
Artigo em Inglês | MEDLINE | ID: mdl-35486379

RESUMO

Smart functional fillers can significantly enhance the comprehensive properties of ionic hydrogels, such as their mechanical properties, which are key features of hydrogels in wearable sensor applications. As a plant-derived natural polymer, hemicellulose can serve as smart functional fillers. In this study, tannic acid-modified hemicellulose nanoparticles (TA@HC) and Fe3+ were used in the preparation of PAA/TA@HC/Fe3+ hydrogels. The addition of TA@HC and Fe3+ in the sodium persulfate (SPS) and acrylic acid (AA) polymerization system resulted in a fast gelation process that was completed within a short time (as short as 30 s) at room temperature. The catechol-rich TA and Fe3+ system allows for quick activation of SPS to produce free radicals, generating abundant hydroxyl groups in a short period of time, which was responsible for the fast gelation. Furthermore, due to the TA@HC effect and the dynamic catechol (TA)-Fe3+ redox system, the PAA/TA@HC/Fe3+ hydrogel exhibited excellent mechanical properties with an exceptionally high strain (as high as 5600%), adhesiveness, rapid and efficient self-healing ability, and reproducible self-adhesion onto various substrates. More importantly, asymmetric adhesive PAA/TA@HC/Fe3+ hydrogels were prepared by selective Fe3+ coating of the upper hydrogel surface to render the top surface nonadhesive so that the same hydrogel with different adhesiveness between the upper and bottom surfaces was obtained. The asymmetric adhesive hydrogel design permits the adhesive side to fit comfortably to the skin and the nonadhesive side showing anti-interference against various different pollutant materials, accurately serving as a pressure sensor.


Assuntos
Hidrogéis , Nanopartículas , Adesivos/química , Catecóis , Hidrogéis/química , Íons/química , Polissacarídeos
2.
Molecules ; 27(4)2022 Feb 21.
Artigo em Inglês | MEDLINE | ID: mdl-35209240

RESUMO

Superhydrophobic coatings have drawn much attention in recent years for their widespread potential applications. However, there are challenges to find a simple and cost-effective approach to prepare superhydrophobic materials and coatings using natural polymer. Herein, we prepared a kraft lignin-based superhydrophobic powder via modifying kraft lignin through 1H, 1H, 2H, 2H-perfluorodecyl-triethoxysilane (PFDTES) substitution reaction, and constructed superhydrophobic coatings by direct spraying the suspended PFDTES-Lignin powder on different substrates, including glass, wood, metal and paper. The prepared lignin-based coatings have excellent repellency to water, with a water contact angle of 164.7°, as well as good friction resistance, acid resistance, alkali resistance, salt resistance properties and quite good self-cleaning performance. After 30 cycles of sand friction or being stayed in 2 mol/L HCl, 0.25 mol/L NaOH and 2 mol/L NaCl solution for 30 min, the coatings still retain super hydrophobic capability, with contact angles higher than 150°. The superhydrophobic performance of PFDTES-Lignin coatings is mainly attributed to the constructed high surface roughness and the low surface energy afforded by modified lignin. This lignin-based polymer coating is low-cost, scalable, and has huge potential application in different fields, providing a simple way for the value-added utilization of kraft lignin.

3.
Angew Chem Int Ed Engl ; 60(39): 21310-21318, 2021 Sep 20.
Artigo em Inglês | MEDLINE | ID: mdl-34254416

RESUMO

Noticeable pseudo-capacitance behavior out of charge storage mechanism (CSM) has attracted intensive studies because it can provide both high energy density and large output power. Although cyclic voltammetry is recognized as the feasible electrochemical technique to determine it quantitatively in the previous works, the results are inferior due to uncertainty in the definitions and application conditions. Herein, three successive treatments, including de-polarization, de-residual and de-background, as well as a non-linear fitting algorithm are employed for the first time to calibrate the different CSM contribution of three typical cathode materials, LiFePO4 , LiMn2 O4 and Na4 Fe3 (PO4 )2 P2 O7 , and achieve well-separated physical capacitance, pseudo-capacitance and diffusive contributions to the total capacity. This work can eliminate misunderstanding concepts and correct ambiguous results of the pseudo-capacitance contribution and recognize the essence of CSM in electrode materials.

4.
Sensors (Basel) ; 19(23)2019 Nov 23.
Artigo em Inglês | MEDLINE | ID: mdl-31771131

RESUMO

Currently, with the satisfaction of people's material life, sports, like yoga and tai chi, have become essential activities in people's daily life. For most yoga amateurs, they could only learn yoga by self-study, like mechanically imitating from yoga video. They could not know whether they performed standardly without feedback and guidance. In this paper, we proposed a full-body posture modeling and quantitative evaluation method to recognize and evaluate yoga postures to provide guidance to the learner. Back propagation artificial neural network (BP-ANN) was adopted as the first classifier to divide yoga postures into different categories, and fuzzy C-means (FCM) was utilized as the second classifier to classify the postures in a category. The posture data on each body part was regarded as a multidimensional Gaussian variable to build a Bayesian network. The conditional probability of the Gaussian variable corresponding to each body part relative to the Gaussian variable corresponding to the connected body part was used as criterion to quantitatively evaluate the standard degree of body parts. The angular differences between nonstandard parts and the standard model could be calculated to provide guidance with an easily-accepted language, such as "lift up your left arm", "straighten your right forearm". To evaluate our method, a wearable device with 11 inertial measurement units (IMUs) fixed onto the body was designed to measure yoga posture data with quaternion format, and the posture database with a total of 211,643 data frames and 1831 posture instances was collected from 11 subjects. Both the posture recognition test and evaluation test were conducted. In the recognition test, 30% data was randomly picked from the database to train BP-ANN and FCM classifiers, and the recognition accuracy of the remaining 70% data was 95.39%, which is highly competitive with previous posture recognition approaches. In the evaluation test, 30% data were picked randomly from subject three, subject four, and subject six, to train the Bayesian network. The probabilities of nonstandard parts were almost all smaller than 0.3, while the probabilities of standard parts were almost all greater than 0.5, and thus the nonstandard parts of body posture could be effectively separated and picked for guidance. We also tested separately the trainers' yoga posture performance in the condition of without and with guidance provided by our proposed method. The results showed that with guidance, the joint angle errors significantly decreased.


Assuntos
Monitorização Ambulatorial/instrumentação , Postura/fisiologia , Adulto , Algoritmos , Braço/fisiologia , Teorema de Bayes , Fenômenos Biomecânicos/fisiologia , Estudos de Avaliação como Assunto , Retroalimentação , Feminino , Humanos , Masculino , Movimento/fisiologia , Redes Neurais de Computação , Dispositivos Eletrônicos Vestíveis , Yoga , Adulto Jovem
5.
IEEE Trans Biomed Eng ; 71(6): 2001-2011, 2024 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-38285582

RESUMO

OBJECTIVE: This article aimed to investigate the biomechanical mechanisms underlying the energetic advantages of the suspended backpacks during load carriage. METHODS: In this study, we examined eight adults walking with a 15 kg load at 5 km/h with a designed suspended backpack, in which the load could be switched to locked and suspended with four combinations of stiffness. Mechanical work and metabolic cost were measured during load carriage. RESULTS: The results showed that the suspended backpacks led to an average reduction of 23.35% in positive work, 24.77% in negative work, and a 12.51% decrease in metabolic cost across all suspended load conditions. Notably, the decreased mechanical work predominantly occurred during single support (averaging 84.19% and 71.16% for positive and negative work, respectively), rather than during double support. CONCLUSION: Walking with the suspended backpack induced a phase shift between body movement and load movement, altering the human-load interaction. This adjustment caused the body and load to move against each other, resulting in flatter trajectories of the human-load system center of mass (COM) velocities and corresponding profiles in ground reaction forces (GRFs), along with reduced vertical excursions of the trunk. Consequently, this interplay led to flatter trajectories in mechanical work rate and reduced mechanical work, ultimately contributing to the observed reduction in energetic expenditure. SIGNIFICANCE: Understanding these mechanisms is essential for the development of more effective load-carrying devices and strategies in various applications, particularly for enhancing walking abilities during load carriage.


Assuntos
Caminhada , Suporte de Carga , Humanos , Caminhada/fisiologia , Fenômenos Biomecânicos/fisiologia , Masculino , Adulto , Suporte de Carga/fisiologia , Feminino , Metabolismo Energético/fisiologia , Adulto Jovem , Marcha/fisiologia
6.
Artigo em Inglês | MEDLINE | ID: mdl-39137070

RESUMO

Individuals with high-level spinal cord injuries often face significant challenges in performing essential daily tasks due to their motor impairments. Consequently, the development of reliable, hands-free human-computer interfaces (HCI) for assistive devices is vital for enhancing their quality of life. However, existing methods, including eye-tracking and facial electromyogram (FEMG) control, have demonstrated limitations in stability and efficiency. To address these shortcomings, this paper presents an innovative hybrid control system that seamlessly integrates gaze and FEMG signals. When deployed as a hybrid HCI, this system has been successfully used to assist individuals with high-level spinal cord injuries in performing activities of daily living (ADLs), including tasks like eating, pouring water, and pick-and-place. Importantly, our experimental results confirm that our hybrid control method expedites the performance in pick-place tasks, achieving an average completion time of 34.3 s, which denotes a 28.8% and 21.8% improvement over pure gaze-based control and pure FEMG-based control, respectively. With practice, participants experienced up to a 44% efficiency improvement using the hybrid control method. This state-of-the-art system offers a highly precise and reliable intention interface, suitable for daily use by individuals with high-level spinal cord injuries, ultimately enhancing their quality of life and independence.

7.
ACS Appl Mater Interfaces ; 16(28): 37111-37121, 2024 Jul 17.
Artigo em Inglês | MEDLINE | ID: mdl-38968403

RESUMO

A fundamental challenge in artificial superhydrophobic papers is their poor resistance to mechanical abrasion, which limits their practical application in different fields. Herein, a robust and multifunctional superhydrophobic paper is successfully fabricated via a facile spraying method by combining silver nanowires and fluorinated titania nanoparticles through a common paper sizing agent (alkyl ketene dimer) onto paper. It is shown that the surface of the paper-based material presents a three-dimensional network structure due to the cross-linking of silver nanowires with a high aspect ratio. Further hydrophilic and hydrophobic performance test results show that it exhibits exceptional water repellency, with a desirable static contact angle of 165° and roll-off angle of 6.2°. The superhydrophobic paper showcases excellent mechanical durability and maintains its superhydrophobicity even after enduring 130 linear sandpaper abrasion cycles or high-velocity water jetting impact benefited from interfacial van der Waals and hydrogen bonding. Simultaneously, the robust superhydrophobic surface can effectively prevent the penetration of acid or alkali solutions, as well as UV light, resulting in excellent chemical stability. Additionally, the superhydrophobic paper offers supplementary features such as self-cleaning, electrical conductivity, and antibacterial capability. Further development of this strategy paves a way toward next-generation superhydrophobic paper composed of nanostructures and characterized by multiple (or additional) functionalities.

8.
Bioresour Technol ; 395: 130400, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-38286169

RESUMO

The rational use of bamboo to make dissolving pulp can offer up new opportunities for cellulose production, alleviating wood scarcity. Bamboo contains a high content of non-fiber cells, which presents technical challenges in dissolving pulp production by the conventional process. In this study, a process concept of separating hemicelluloses is presented by fiber fractionation and purification for cleaner production of bamboo dissolving pulp: bamboo kraft pulp was fractionated into long-fiber and short-fiber fractions. The cellulose-rich long-fiber fraction was converted to dissolving pulp by further purification treatment with acid hydrolysis and cold caustic extraction. The hemicellulose-rich short-fiber fraction was used for papermaking. The laboratory results were confirmed by those from mill trials. The combined pulp yield (dissolving pulp + paper-grade pulp) reached 49 %, which was significantly higher than that of the conventional pre-hydrolysis kraft pulping process. Furthermore, the quality of dissolving pulp was higher due to inherently higher cellulose content of long-fiber fraction.


Assuntos
Celulose , Fracionamento Químico , Madeira , Hidrólise
9.
Artigo em Inglês | MEDLINE | ID: mdl-37883284

RESUMO

Decoding the user's natural grasp intent enhances the application of wearable robots, improving the daily lives of individuals with disabilities. Electroencephalogram (EEG) and eye movements are two natural representations when users generate grasp intent in their minds, with current studies decoding human intent by fusing EEG and eye movement signals. However, the neural correlation between these two signals remains unclear. Thus, this paper aims to explore the consistency between EEG and eye movement in natural grasping intention estimation. Specifically, six grasp intent pairs are decoded by combining feature vectors and utilizing the optimal classifier. Extensive experimental results indicate that the coupling between the EEG and eye movements intent patterns remains intact when the user generates a natural grasp intent, and concurrently, the EEG pattern is consistent with the eye movements pattern across the task pairs. Moreover, the findings reveal a solid connection between EEG and eye movements even when taking into account cortical EEG (originating from the visual cortex or motor cortex) and the presence of a suboptimal classifier. Overall, this work uncovers the coupling correlation between EEG and eye movements and provides a reference for intention estimation.


Assuntos
Movimentos Oculares , Intenção , Humanos , Movimento , Eletroencefalografia , Força da Mão
10.
Artigo em Inglês | MEDLINE | ID: mdl-37490379

RESUMO

The 6-min walk distance (6MWD) and the Fugl-Meyer assessment lower-limb subscale (FMA-LE) of the stroke patients provide the critical evaluation standards for the effect of training and guidance of the training programs. However, gait assessment for stroke patients typically relies on manual observation and table scoring, which raises concerns about wasted manpower and subjective observation results. To address this issue, this paper proposes an intelligent rehabilitation assessment method (IRAM) for rehabilitation assessment of the stroke patients based on sensor data of the lower limb exoskeleton robot. Firstly, the feature parameters of the patient were collected, including age, height, and duration, etc. The sensor data of the exoskeleton robot were also collected, including joint angle, joint velocity, and joint torque, etc. Secondly, a gait feature model was constructed to deduce the walking gait parameters of the patient according to the sensor data of the exoskeleton, including the support phase to swing phase ratio, step length and leg lift height of the patient, etc. Then, the 6MWD and FMA-LE values were collected by traditional methods, feature parameters, gait parameters and human-machine interaction parameters (joint torque) of the patient were adopted to train the rehabilitation assessment model. Finally, the assessment model was trained by a machine-learning based algorithm. The new stroke patients' the 6MWD and FMA-LE values can be predicted by the trained model. The experimental results present that the prediction accuracy for the 6MWD and FMA-LE values reach to 85.19% and 92.66%, respectively.


Assuntos
Exoesqueleto Energizado , Robótica , Reabilitação do Acidente Vascular Cerebral , Acidente Vascular Cerebral , Humanos , Reabilitação do Acidente Vascular Cerebral/métodos , Marcha , Extremidade Inferior
11.
Int J Biol Macromol ; 238: 124031, 2023 May 31.
Artigo em Inglês | MEDLINE | ID: mdl-36933599

RESUMO

Actuators are widely used in bionic devices and soft robots, among which invisible actuators have some unique applications, including performing secret missions. In this paper, highly visible transparent cellulose-based UV-absorbing films were prepared by dissolving cellulose raw materials using N-methylmorpholine-N-oxide (NMMO) and using ZnO nanoparticles as UV absorbers. Furthermore, transparent actuator was fabricated by growing highly transparent and hydrophobic polytetrafluoroethylene (PTFE) film on regenerated cellulose (RC)-ZnO composite film. In addition to its sensitive response to Infrared (IR) light, the as-prepared actuator also shows a highly sensitive response to UV light, which is attributed to the strong absorption of UV light by ZnO NPs. Thanks to the drastic differences in adsorption capacity between the RC-ZnO and PTFE materials for water molecules, the asymmetrically- assembled actuator demonstrates extremely high sensitivity and excellent actuation performance, with a force density of 60.5, a maximum bending curvature of 3.0 cm-1, and a response time of below 8 s. Bionic bug, smart door and the arm of excavator made from the actuator all exhibit sensitive responses to UV and IR lights.


Assuntos
Nanopartículas , Óxido de Zinco , Raios Ultravioleta , Celulose/química , Água/química , Nanopartículas/química
12.
Artigo em Inglês | MEDLINE | ID: mdl-37971912

RESUMO

Prediction of foot placement presents great potential in better assisting the walking of people with lower-limb disability in daily terrains. Previous researches mainly focus on foot placement prediction in level ground walking, however these methods cannot be applied to daily complex terrains including ramps, stairs, and level ground with obstacles. To predict foot placement in complex terrains, this paper presents a probability fusion approach for foot placement prediction in complex terrains which consists of two parts: model training and foot placement prediction. In the first part, a deep learning model is trained on augmented data to predict the probability distribution of preliminary foot placement. In the second part, environmental information and human walking constraints are used to calculate the feasible area, and finally the feasible area is fused with the probability distribution of preliminary foot placement to predict the foot placement in complex terrains. The proposed method can predict the foot placement of next step in complex terrains when heel-off is detected. Experiments (including structured terrains experiments and complex terrains experiments) show that the root mean square error (RMSE) of prediction is 8.19 ± 1.20 cm, which is less than 8% of the average stride length, and the landing feasible area accuracy (LFAA) of prediction is 95.11 ± 3.09%. Comparing with existing foot placement prediction studies, the method proposed in this paper achieves faster and more accurate prediction in complex terrains.


Assuntos
, Caminhada , Humanos , Extremidade Inferior , Probabilidade , Calcanhar , Fenômenos Biomecânicos , Marcha
13.
Artigo em Inglês | MEDLINE | ID: mdl-36191095

RESUMO

Two-dimensional lung ultrasound (LUS) has widely emerged as a rapid and noninvasive imaging tool for the detection and diagnosis of coronavirus disease 2019 (COVID-19). However, image differences will be magnified due to changes in ultrasound (US) imaging experience, such as US probe attitude control and force control, which will directly affect the diagnosis results. In addition, the risk of virus transmission between sonographer and patients is increased due to frequent physical contact. In this study, a fully automatic dual-probe US scanning robot for the acquisition of LUS images is proposed and developed. Furthermore, the trajectory was optimized based on the velocity look-ahead strategy, the stability of contact force of the system and the scanning efficiency were improved by 24.13% and 29.46%, respectively. Also, the control ability of the contact force of robotic automatic scanning was 34.14 times higher than that of traditional manual scanning, which significantly improves the smoothness of scanning. Importantly, there was no significant difference in image quality obtained by robotic automatic scanning and manual scanning. Furthermore, the scanning time for a single person is less than 4 min, which greatly improves the efficiency of screening triage of group COVID-19 diagnosis and suspected patients and reduces the risk of virus exposure and spread.


Assuntos
COVID-19 , Robótica , Humanos , Teste para COVID-19 , Robótica/métodos , Triagem , COVID-19/diagnóstico por imagem , Ultrassonografia/métodos , Pulmão/diagnóstico por imagem
14.
Artigo em Inglês | MEDLINE | ID: mdl-36223362

RESUMO

Gait asymmetry is an important clinical characteristic of the hemiplegic gait most stroke survivors suffered, leading to restricted functional mobility and long-term negative impact on their quality of life. In recent years, robot assistance has been proven able to improve stroke patients' functional walking, but few studies have been conducted to specifically correct gait asymmetry of stroke patients during the whole gait cycle. In this work, an adaptive oscillator-based assistive torque control was developed and implemented on a unilateral hip exoskeleton driven by a novel nonlinear series elastic actuator (nSEA), aiming at correcting gait asymmetry at hip joints during the whole gait cycle. The adaptive oscillator-based gait asymmetry detection method extracted continuous gait phase and gait asymmetry seamlessly, and then the proposed assistive control attempted to correct gait asymmetry by delivering precise assistive torques synchronized with the continuous gait phase of the patients' gait. An initial experimental study was conducted to evaluate the proposed assistive control on seven healthy subjects with artificial impairment. The participants walked on a treadmill with assistance from the hip exoskeleton, while artificial impairment was added to mimic the hemiplegic gait with both spacial and temporal asymmetry (such as reduced hip flexion in the impaired side and reduced hip extension in the healthy side). Experimental results suggested the effectiveness of the proposed assistive control in restoring gait symmetry to levels comparable to a normal gait of the participants ( ).


Assuntos
Exoesqueleto Energizado , Transtornos Neurológicos da Marcha , Acidente Vascular Cerebral , Humanos , Torque , Qualidade de Vida , Marcha , Caminhada , Fenômenos Biomecânicos
15.
Front Neurorobot ; 16: 914706, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-35711281

RESUMO

Fuzzy inference systems have been widely applied in robotic control. Previous studies proposed various methods to tune the fuzzy rules and the parameters of the membership functions (MFs). Training the systems with only supervised learning requires a large amount of input-output data, and the performance of the trained system is confined by that of the target system. Training the systems with only reinforcement learning (RL) does not require prior knowledge but is time-consuming, and the initialization of the system remains a problem. In this paper, a supervised-reinforced successive training framework is proposed for a multi-continuous-output fuzzy inference system (MCOFIS). The parameters of the fuzzy inference system are first tuned by a limited number of input-output data from an existing controller with supervised training and then are utilized to initialize the system in the reinforcement training stage. The proposed framework is applied in a robotic odor source searching task and the evaluation results demonstrate that the performance of the fuzzy inference system trained by the successive framework is superior to the systems trained by only supervised learning or RL. The system trained by the proposed framework can achieve around a 10% higher success rate compared to the systems trained by only supervised learning or RL.

16.
Artigo em Inglês | MEDLINE | ID: mdl-35584064

RESUMO

Powered lower-limb prostheses with vision sensors are expected to restore amputees' mobility in various environments with supervised learning-based environmental recognition. Due to the sim-to-real gap, such as real-world unstructured terrains and the perspective and performance limitations of vision sensor, simulated data cannot meet the requirement for supervised learning. To mitigate this gap, this paper presents an unsupervised sim-to-real adaptation method to accurately classify five common real-world (level ground, stair ascent, stair descent, ramp ascent and ramp descent) and assist amputee's terrain-adaptive locomotion. In this study, augmented simulated environments are generated from a virtual camera perspective to better simulate the real world. Then, unsupervised domain adaptation is incorporated to train the proposed adaptation network consisting of a feature extractor and two classifiers is trained on simulated data and unlabeled real-world data to minimize domain shift between source domain (simulation) and target domain (real world). To interpret the classification mechanism visually, essential features of different terrains extracted by the network are visualized. The classification results in walking experiments indicate that the average accuracy on eight subjects reaches (98.06% ± 0.71 %) and (95.91% ± 1.09 %) in indoor and outdoor environments respectively, which is close to the result of supervised learning using both type of labeled data (98.37% and 97.05%). The promising results demonstrate that the proposed method is expected to realize accurate real-world environmental classification and successful sim-to-real transfer.


Assuntos
Amputados , Membros Artificiais , Algoritmos , Humanos , Locomoção , Caminhada
17.
Int J Biol Macromol ; 201: 104-110, 2022 Mar 15.
Artigo em Inglês | MEDLINE | ID: mdl-34998868

RESUMO

Flexible hydrogels with integration of excellent mechanical and electrical properties are well suited for applications as wearable electronic sensors, and others. Self-adhesion is an important feature of wearable sensors. However, the usual isotropic- adhesion hydrogels have the drawback of poor anti-interference, which negatively affects their applications. In this study, we developed asymmetric-adhesion and tough lignin reinforced hydrogels in a facile two-step process: 1) PAA hydrogels, with lignin as the binder and conductive filler, were first prepared; 2) the asymmetric-adhesion property was imparted to lignin reinforced hydrogel by simple soaking of the top portion of the hydrogel in CaCl2 solution. The as-obtained asymmetric-adhesion lignin reinforced hydrogel was assembled into a wearable sensor, which shows excellent anti-interference and accurate and stable collections of sensing signals, with its gauge factor (GF) of 2.51 (in the strain range of 0-51.5%). In addition, the tough hydrogel is capable of generating electricity upon moist air sweeping through it, showing excellent energy conversion capabilities, with open-circuit voltage of as high as 306.6 mV. These results provided new prospects for the application of polyelectrolyte hydrogel materials in the fields of wet-to-electric conversion and wearable electronic sensors.


Assuntos
Hidrogéis , Dispositivos Eletrônicos Vestíveis , Condutividade Elétrica , Eletricidade , Lignina
18.
Int J Biol Macromol ; 200: 226-233, 2022 Mar 01.
Artigo em Inglês | MEDLINE | ID: mdl-34999036

RESUMO

Hydrogels have found applications in many different fields. However, poor mechanical properties, such as low elasticity and lack of rapid recovery under large deformation, can severely limit their applications. In this study, we developed lignin reinforced hydrogels made of calcium ion containing ternary polymers (lignosulfonate (LS), alginate (Alg), and polyacrylic acid (PAA)). The resultant hydrogel has excellent elasticity, rapid self-recovery, and multi-functionalities. The covalent PAA network acts as the elastic scaffold of hydrogel, while calcium bridging networks of LS, Alg, and PAA, as well as the strong hydrogen bonding network in the system, function as sacrifice bonds to dissipate energy and transfer stress. The PAA/LS/Alg/Ca hydrogels exhibit rapid and durable elastic recovery ability under large deformation with the highest compressive stress of 835 kPa (95% strain), highest tensile fracture stress of 357 kPa, and highest tensile strain of 1144%. In addition, these tough hydrogels show UV resistance, self-healing, antifreeze, and excellent electro-conductivity. When assembled into a strain sensor, stable and reliable electrical responses with 375 ms response time are demonstrated. The PAA/LS/Alg/Ca hydrogel strain sensors can monitor human movements with responsive and accurate physiological signals. These results support the conclusion that the PAA/LS/Alg/Ca hydrogel strain sensors have great application potential in flexible wearable electronics and smart devices.


Assuntos
Hidrogéis
19.
Artigo em Inglês | MEDLINE | ID: mdl-35349445

RESUMO

Leg stiffness is considered a prevalent parameter used in data analysis of leg locomotion during different gaits, such as walking, running, and hopping. Quantification of the change in support leg stiffness during stair ascent and descent will enhance our understanding of complex stair climbing gait dynamics. The purpose of this study is to investigate a methodology to estimate leg stiffness during stair climbing and subdivide the stair climbing gait cycle. Leg stiffness was determined as the ratio of changes in ground reaction force in the direction of the support leg Fl (leg force) to the respective changes in length Ll during the entire stance phase. Eight subjects ascended and descended an instrumented staircase at different cadences. In this study, the changes of leg force and length (force-length curve) are described as the leg stiffness curve, the slope of which represents the normalized stiffness during stair climbing. The stair ascent and descent gait cycles were subdivided based on the negative and positive work fluctuations of the center-of-mass (CoM) work rate curve and the characteristics of leg stiffness. We found that the leg stiffness curve consists of several segments in which the force-length relationship was similarly linear and the stiffness value was relatively constant; the phase divided by the leg stiffness curve corresponds to the phase divided by the CoM work rate curve. The results of this study may guide biomimetic control strategies for a wearable lower-extremity robot for the entire stance phase during stair climbing.


Assuntos
Subida de Escada , Fenômenos Biomecânicos , Marcha , Humanos , Perna (Membro) , Locomoção , Caminhada
20.
Int J Biol Macromol ; 212: 275-282, 2022 Jul 01.
Artigo em Inglês | MEDLINE | ID: mdl-35594941

RESUMO

Soft and elastic polymer hydrogel materials are booming in the fields of wearable biomimetic skin, sensors, robotics, and bioelectrodes. Currently, many researchers are exploring new chemistries for the preparation of hydrogels to improve their performance. In the present study, we design and develop a strategy to prepare lignin reinforced hydrogels based on disulfide bond crosslinking mechanisms, and resultant hydrogels exhibit excellent stretchability, with tensile strain of up to 1085.4%, and high adhesion (with the highest T-peel strength of up to 432.2 N/m to pigskin). The underlying mechanism is based on the disulfide bonds that act as crosslinkers in the as-prepared hydrogel, and they can be easily cleaved and re-formed under mild conditions. Thanks to the presence of lignin, the as-obtained hydrogels also have excellent UV shielding effect. When assembled into a strain sensor, they can output stable and sensitive sensing signals, with gauge factor (GF) of 2.72 (strain: 0-72.8%). Furthermore, a simple and effective strategy to construct asymmetric adhesive hydrogels was adopted, which is based on directional soaking of the top portion of the hydrogel in a high-concentrated calcium chloride solution. The asymmetric hydrogel strain sensor transmits accurate and stable signals without the interference of various contaminants.


Assuntos
Hidrogéis , Lignina , Adesivos/química , Dissulfetos , Condutividade Elétrica , Hidrogéis/química
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