1.
J Org Chem
; 77(19): 8705-11, 2012 Oct 05.
Artigo
em Inglês
| MEDLINE
| ID: mdl-22985461
RESUMO
A general and mild method for the construction of functionalized 2-(1H-indol-3-yl)-2-amino-carbonyl compounds was achieved, which represents the first example of direct α-arylation of α-amino carbonyl compounds with indoles using the visible light photoredox catalysis strategy.
Assuntos
Aminas/química , Indóis/química , Indóis/síntese química , Catálise , Luz , Estrutura Molecular , Oxirredução
2.
Angew Chem Int Ed Engl
; 51(39): 9909-13, 2012 Sep 24.
Artigo
em Inglês
| MEDLINE
| ID: mdl-22945894
RESUMO
Open a new door: The first example of alkene synthesis from alkyl electrophiles with Grignard reagents using the Kumada cross-coupling reaction strategy is reported. This method opens a new door for the Kumada cross-coupling reaction, allowing alkenes to be prepared from the reaction of tosylalkanes with Grignard reagents.