PCDD/PCDFs and PCBs in the irrigation water in Egypt: levels, patterns, and potential sources.

The contamination levels of PCDD/PCDFs in irrigation water are the most rarely studied throughout the world. The major problem in Egypt is the lack of studies and statistics about these contaminants of POPs in irrigation water. Therefore, this study is the first comprehensive report to elucidate the estimation and sources of PCDD/PCDFs and PCBs in irrigation water from Egypt and rare for worldwide may provide a reference to future studies of POPs compounds in irrigation water of Egypt. A total of 24 irrigated water samples were collected from different irrigation canals which are adjacent to industrial areas from six Egyptian governorates (Bani Swef, El-Giza, El-Sharkeya, El-Menoufeya, El-Gharbeya, and Alexandria). The study shows that irrigation water canals were contaminated with low levels of PCDDs/PCDFs, which were 0.95 pgWHO-TEQ/l, and the total of PCDD/PCDFs and dl-PCBs were 2.06 pgWHO-TEQ/l with contamination ranging between 0.88 to 2.97 pgWHO-TEQ/l while the levels of indicator PCBs were 18.52 ng/l and ranged between 0.39 to 165.6 ng/l. The most predominant dioxins congeners were HpCDD, OCDD, HpCDF, and OCDF while for dl-PCBs were PCB105 and PCB118, and for ndl-PCBs was PCB138. The areas with recent urbanization and industrialization were more contaminated with PCBs than the unindustrialized area. Lightly to moderately chlorinated congeners dominated the PCB profiles. The major sources for these contaminants were fire bricks followed by textile industries closer to the located sampling sites. The detected pattern was found to be similar to the patterns reported in the air by other studies. Although the concentrations of the studied POPs are found to be low in irrigated water, it may be considered as a potential source of soil pollution due to their accumulation process in the agricultural land and may lead to risk on human health by consuming the agricultural products irrigated by contaminated water.

Identification, Quantification, and Toxicity of PCDDs and PCDFs in Soils from Industrial Areas in the Central and Eastern Regions of Saudi Arabia.

This study was conducted to identify and quantify polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) in soil samples collected from selected industrial areas in the central and eastern regions of Saudi Arabia. All the investigated compounds of PCDDs/PCDFs were identified in the studied locations. The average concentrations of PCDDs (sum of seven congeners measured) ranged from 11.5 to 59.6 pg g(-1), with a maximum concentration of 125.7 pg g(-1) at an oil refinery station followed by 100.9 pg g(-1) at a cement factory. The average concentrations of PCDFs (sum of 10 congeners measured) accounted for 11.68-19.35 pg g(-1), with a maximum concentration of 38.67 pg g(-1) at the cement factory. It was generally observed that the soil samples collected from industrial areas have substantially high toxicity equivalence (TEQ) values of PCDDs/PCDFs compared to soils of remote areas. Principal component analysis revealed that the cement factories and oil refineries were the primary sources of PCDDs and PCDFs.

Levels of pesticide residues in breast milk and the associated risk assessment.

The aim of this study was to determine the types and levels of organochlorine pesticides (OCPs) present in the human milk collected from cities in eastern and central Saudi Arabia. This study is part of assessment of various persistent organic pollutants (POPs) in human milk in four cities of eastern and central Saudi Arabia, namely, Riyadh, Al-Kharj, Al-Jobail and Al-Dammam. Milk samples were collected from 50 donors according to the WHO/UNEP protocol for monitoring human milk for POPs. The OCPs in each of the 50 milk samples were analyzed using as triple quadrupole gas chromatography mass spectrometry-mass spectrometry detection (GC-MS/MS). Quality assurance included the analysis of blank, spiked and reference samples. Sixteen different OCPs were identified namely: aldrin, dieldrin, endrin, hexachlorobenzene, alpha, beta, gamma and delta hexachlorocycohexame, pp'-,op'-DDT, pp'-DDE, pp'-DDD, alpha and gamma chlordane, heptachlor, mirex and methoxychlor. The results of the analysis OCPs in human milk samples indicated that the tested positive samples for one or more pesticide at the limits of determination used in this study. As required by the Stockholm Convention on POPs, the levels of certain POPs in human milk will serve as an indicator of the effectiveness of the treaty in eliminating or reducing emissions of selected POPs. This study contributes to that effort by providing seline data on current levels of OPCs in human milk in Saudi Arabia.

Rapid analytical method for the determination of 220 pesticide with their isomers by GCMS-TIC.

This paper presents a cost-effective and validated multi residue modified and miniaturized method for the determination of 220 chemically different groups of pesticides and their isomers. This determination method is performed with single Quaid Gas Chromatography Mass Spectrometry -Total Ion Chromatogram GCMS-TIC. Two methods was experimented and modified with different GCMS parameters to analyses most common used pesticide and their residues in the standers solution and can be applied for real environmental samples. The results showed by single Quaid GCMS-TIC it can analyze 220 pesticides including their isomers within 49.6 min and low detection limit by using modified method 2 as described in this research. Limit of detection (LOD) was ranged from 0.78 to 14.74 ng/ml (ppb) with good separation and resolution. Limit of quantification (LOQ) was ranged between 2.34 and 44.22 ng/ml (ppb). Method 2 was more accurate, shorter, and clear separation rather than method 1. This method can be successfully applied in real environmental samples proven to be a good option for routine analysis of pesticide within the maximum residue limits (MRL) referenced to European commission especially with the most common GCMS-TIC which exists in most of labs and low income countries.

Levels of heavy metals in a multifloral Saudi honey.

The presence of chemical pollutants, especially heavy metals, affects the quality of honey. The objective of this study was to determine the levels of eight heavy metals (As, Cd, Co, Cr, Cu, Ni, Pb, and Zn) in honey samples from Al-Baha region in Saudi Arabia, using inductively coupled plasma with optical emission spectroscopy (ICP-OES). The highest concentration was found for Zn (1707.93 µg kg-1), while the lowest was found for Co (3.04 µg kg-1). Cluster analysis and principal component analysis showed that two groups are recognized indicating two different metal sources. The first group includes only Zn and the second group includes the rest of the metals. In view of the recommended and established heavy metal intakes for humans, consumption of Saudi honey from Al-Baha should not be deemed a matter of concern for human health.

Photolysis degradation of polyaromatic hydrocarbons (PAHs) on surface sandy soil.

Polycyclic aromatic hydrocarbons (PAHs) are potent environmental pollutants, and some of them have been identified as carcinogenic and mutagenic. To advance the knowledge of the environmental fate of PAHs, we systematically investigated the influence of different UV wavelengths irradiation on photolysis of PAHs on sandy soil under tow wavelengths (254 and 306 nm) UV irradiation for six PAHs. In addition, kinetic model and influence of several parameters on PAHs photolysis have been studied. The results obtained indicated that UV radiation with a wavelength of 306 nm was more efficient in the photolysis of the polycyclic aromatic hydrocarbons. Our results showed that fluoranthene (Flt) was the fastest in decomposition, has the greatest value for the coefficient of photolysis (7.4 × 10(-3) h(-1)), and has less half-life, reaching 94 h when using a wavelength of 254 nm. The results indicated that the pyrene (Pyr) was more resistant to photolysis in comparison with indeno(1,2,3-cd) pyrene (IP) and fluoranthene (Flt). The results indicate that photolysis is a successful way to remediate the six studied PAHs compounds.