RESUMO
Structured surfaces, which are the basis of the lotus blossom effect, have great potential to serve/operate as functionalised surfaces, i.e., surfaces with specific and/or adjustable properties. In the present study, the aim is to use micro-structured elastomeric surfaces to specifically influence the friction and deformation behaviours on the basis of the shape and arrangement of the structures. Thiol-acrylate-based photopolymers patterned via nanoimprint lithography were investigated by using an in situ tribological measurement set-up. A clear influence of the different structures on the surface's friction behaviour could be shown, and, furthermore, this could be brought into relation with the real area of contact. This finding provides an important contribution to further development steps, namely, to give the structures switchable properties in order to enable the control of friction properties in a targeted manner.
RESUMO
Models describing how fillers affect the barrier properties of polymers remain an important research topic to improve applications such as hydrogen storage or food preservation. The Nielsen model, one of the earliest models for such predictions, is still one of the most widely used in the literature. However, it does not provide quantitative information on arrangements of fillers inside a polymer matrix, which is crucial for the definition of suitable filler distributions in barrier materials. Therefore, the channel model was developed in this work, which extends the Nielsen model by determining the relative distances between the fillers in regular filler arrangements in polymer matrices. This allows us to relate the permeation properties of filled polymer membranes to the geometric properties of the filler arrangement in simulations and experimental measurements. Simulations with geometries defined according to the channel model showed good agreement with the predictions of the Nielsen model. This demonstrated that the channel model can be a valuable tool for predicting at least mean geometric distances in studied polymer membranes. The validity range of the channel model was limited to a value range of the filler volume fraction 0.01≤Ïf≤0.5 based on theoretical considerations.
RESUMO
Stick-slip friction of elastomers arises due to adhesion, high local strains, surface features, and viscous dissipation. In situ techniques connecting the real contact area to interfacial forces can reveal the contact evolution of a rough elastomer surface leading up to gross slip, as well as provide high-resolution dynamic contact areas for improving current slip models. Samples with rough surfaces were produced by the same manufacturing processes as machined seals. In this work, a machined fluoroelastomer (FKM) hemisphere was slid against glass, and the stick-slip behavior was captured optically in situ. The influence of sliding velocity on sliding behavior was studied over a range of speeds from 1 µm/s to 100 µm/s. The real contact area was measured from image sequences thresholded using Otsu's method. The motion of the pinned region was delineated with a machine learning scheme. The first result is that, within the macroscale sticking, or pinned phase, local pinned and partial slip regions were observed and modeled as a combined contact with contributions to friction by both regions. As a second result, we identified a critical velocity below which the stick-slip motion converted from high frequency with low amplitude to low frequency with high amplitude. This study on the sliding behavior of a viscoelastic machined elastomer demonstrates a multi-technique approach which reveals precise changes in contact area before and during pinning and slip.
RESUMO
The touch-feel sensation of product surfaces arouses growing interest in various industry branches. To entangle the underlying physical and material parameters responsible for a specific touch-feel sensation, a new measurement system has been developed. This system aims to record the prime physical interaction parameters at a time, which is considered a necessary prerequisite for a successful physical description of the haptic sensation. The measurement setup enables one to measure the dynamic coefficient of friction, the macroscopic contact area of smooth and rough surfaces, the angle enclosed between the human finger and the soft-touch surfaces and the vibrations induced in the human finger during relative motion at a time. To validate the measurement stand, a test series has been conducted on two soft-touch surfaces of different roughness. While the individual results agree well with the literature, their combination revealed new insights. Finally, the investigation of the haptics of polymer coatings with the presented measuring system should facilitate the design of surfaces with tailor-made touch-feel properties.