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Chemphyschem ; 15(18): 3929-32, 2014 Dec 15.
Artigo em Inglês | MEDLINE | ID: mdl-25303164

RESUMO

ß-nuclear magnetic resonance (NMR) spectroscopy is highly sensitive compared to conventional NMR spectroscopy, and may be applied for several elements across the periodic table. ß-NMR has previously been successfully applied in the fields of nuclear and solid-state physics. In this work, ß-NMR is applied, for the first time, to record an NMR spectrum for a species in solution. (31)Mg ß-NMR spectra are measured for as few as 10(7) magnesium ions in ionic liquid (EMIM-Ac) within minutes, as a prototypical test case. Resonances are observed at 3882.9 and 3887.2 kHz in an external field of 0.3 T. The key achievement of the current work is to demonstrate that ß-NMR is applicable for the analysis of species in solution, and thus represents a novel spectroscopic technique for use in general chemistry and potentially in biochemistry.


Assuntos
Magnésio/análise , Espectroscopia de Ressonância Magnética/métodos , Líquidos Iônicos/química , Radioisótopos/análise , Soluções
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