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1.
Environ Res ; 245: 118026, 2024 Mar 15.
Artigo em Inglês | MEDLINE | ID: mdl-38151144

RESUMO

In the context of the circular economy, the development of innovative and low-carbon concrete that incorporates different kinds of waste materials is gaining attention among the research community, regulatory agencies, and policymakers. These materials can be incorporated into concrete mixtures as aggregates or as fillers for improvement of product properties. This study aims to identify reliable designs for biochar-augmented cementitious products and general applications through technical, environmental, and economic assessments. The outcomes demonstrate that 5 wt% biochar addition could enhance the compressive strength of the final products. Using biochar, together with other recycled materials, can enormously reduce the environmental impacts, especially for global warming, enabling biochar-augmented cementitious products and general application as carbon-negative resources. The highest GWP reduction reached -720 kg CO2/tonne, equal to a 200% saving. A high quantity of biochar could be included in several specific applications (up to 60 wt%). The economic assessment highlights that the proposed designs are cost-effective and carbon tax can be significantly reduced. Carbon credits can also be earned for some carbon-negative designs. These findings can serve to mitigate GHG emissions and provide decision-makers with a reliable and holistic framework towards the goal of carbon neutrality.


Assuntos
Carbono , Carvão Vegetal , Análise Custo-Benefício , Aquecimento Global
2.
Environ Sci Technol ; 56(10): 6596-6607, 2022 05 17.
Artigo em Inglês | MEDLINE | ID: mdl-35476456

RESUMO

Biological models describing anaerobic digestion (AD) of sewage sludge have been widely applied to test various control and operation strategies. Anaerobic digestion model 1 (ADM1) provides a generic platform that includes the main processes of AD, excluding homoacetogenesis and the microbial structure. Homoacetogenic bacteria have been identified as important competitors for hydrogen consumption and acetate production. Although recent advances in meta-omics techniques have improved our characterization of AD microbial communities, conventional models treat functional groups as homogeneous and overlook the physiology and behavior of microbial individuality, limiting insights into mechanisms governing process performance. A novel microbial individuality model (MIM) that integrates kinetics, energetics, and agent-based modeling to describe a microbiome's behavior as heterogenic populations, including homoacetogenesis, was developed. The MIM was validated with two datasets from previous studies through daily biogas production, methane content, compound concentrations, and microbial relative abundance changes. The MIM identified the emergence of Methanosaeta at low concentrations of acetate. Moreover, this simulation supports experimental studies confirming that the overlooked homoacetogenesis is an important hydrogen sink in AD. Validated MIMs are expected to provide insights into syntrophic and competitive interactions among microbiomes in AD systems while testing different operational parameters in a virtual environment. The MIM offers a methodological framework to other biological treatment systems and their microbial community dynamics.


Assuntos
Microbiota , Esgotos , Acetatos , Anaerobiose , Reatores Biológicos/microbiologia , Hidrogênio , Metano , Esgotos/química
3.
Environ Sci Technol ; 54(8): 4746-4757, 2020 04 21.
Artigo em Inglês | MEDLINE | ID: mdl-32186192

RESUMO

Several life-cycle assessments (LCAs) have evaluated the environmental impacts (EIs) of different wastewater treatment (WWT) configurations, attempting resource recovery and energy efficiency. However, a plant-wide LCA considering up-concentration primary treatment and low carbon-to-nitrogen (C/N) ratio sewage at the secondary biological treatment (SBT) has not yet been conducted. This study identifies the environmental trade-offs and hotspots for the chemically enhanced primary treatment (CEPT) and low C/N ratio SBT emerging processes compared to conventional WWT. The life-cycle inventories were calculated using a stoichiometric life-cycle inventory framework that couples stoichiometry and kinetics to obtain site-specific water, air, and soil emissions. The midpoint results of LCA show that CEPT with anaerobic digestion (AD) for sludge treatment achieves energy self-sufficiency, but increases marine eutrophication (MEu) by 1 order of magnitude compared to conventional WWT. A mainstream anaerobic fluidized-bed bioreactor and a partial nitritation-anammox fluidized-bed membrane bioreactor which can reduce all environmental impacts by 17-47%, including MEu, are proposed as the SBT of the low-carbon CEPT settled sewage. Integrating the standardized S-LCI framework resulted in a site-specific LCA that aids decision-makers on choosing between higher reductions in most EIs at the expense of high MEu or less but consistent reductions in all EI categories.


Assuntos
Nitrogênio , Esgotos , Reatores Biológicos , Carbono , Eliminação de Resíduos Líquidos , Águas Residuárias
4.
Environ Sci Technol ; 53(9): 5111-5123, 2019 05 07.
Artigo em Inglês | MEDLINE | ID: mdl-30946574

RESUMO

In recent years, many life-cycle assessments (LCAs) have been applied to the field of sewage treatment (ST). However, most LCAs lack systematic data collection (DC) and processing methods for inventories of conventional ST (CST), much less for recently developed technologies. In addition, the use of site-generic databases results in LCAs that lack the representativeness and understanding of the regional environmental impacts and trade-offs between different impact categories, especially nutrient enrichment and toxicity-related categories. These shortcomings make comparative evaluation and implementation more challenging. In order to assist in the decision-making process, a novel stoichiometric life-cycle inventory (S-LCI) for ST was developed. In the S-LCI, biochemical pathways derived from elemental analyses combined with process-engineering calculations enable steady-state comparison of the water, air, and soil emissions of any sewage and sludge sample treated through the ST configurations analyzed herein. The DC required for the estimation of the foreground data for a CST is summarized in a 41-item checklist. Moreover, the S-LCI was validated for CST by comparing the S-LCI with actual ST plant operations performed in Hong Kong. A novel energy-derived ST inventory is developed and compared here with the CST. The resulting inventories are ready to be integrated into the SimaPro software for life cycle impact assessment as illustrated by the case study. Using the S-LCI not only helps to standardize the DC and processing, but it also enhances the level of specificity by using sample characterization and site-specific data. The EcoInvent database, which contains a single sample characterization per Swiss and global average ST plant class could be expanded by using the S-LCI.


Assuntos
Meio Ambiente , Esgotos , Hong Kong , Sensibilidade e Especificidade
5.
Energy Sustain Dev ; 68: 182-191, 2022 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-36267957

RESUMO

The COVID-19 pandemic has introduced opportunities for more research in resilience as globally cities experienced lock-down, causing change to conventional energy consumption pattern especially in the residential sector. This study aims to quantify the increased energy demand during work-from-home arrangement, using high-rise public residential buildings in Hong Kong, where its government announced work-from-home arrangement four times in 2020. Building energy modellings were conducted to compare the total energy demand of residential units during normal and work-from-home arrangements, followed by validation against peer models and empirical data. A 9% residential energy demand increase was demonstrated, hence additional energy supply became desirable for the sake of resilience. This study assesses the possibility to leverage photovoltaic rooftop to supplement the increased energy demand. The photovoltaics' potential contribution was estimated by solar energy simulation and evaluated in terms of the capability to utilize its generation output to supplement the additional energy demand. During the four work-from-home periods, it was shown that a photovoltaic system could have supplemented 6.8% - 11% of the increased energy demand, mainly subject to the air-conditioning operation and solar generation. These findings are valuable to safeguard energy resilience in upcoming grid planning and operation.

6.
Sci Rep ; 12(1): 9706, 2022 06 11.
Artigo em Inglês | MEDLINE | ID: mdl-35690631

RESUMO

Recurrent updates in non-pharmaceutical interventions (NPIs) aim to control successive waves of the coronavirus disease 2019 (COVID-19) but are often met with low adherence by the public. This study evaluated the effectiveness of gathering restrictions and quarantine policies based on a modified Susceptible-Exposed-Infectious-Hospitalized-Recovered (SEIHR) model by incorporating cross-boundary travellers with or without quarantine to study the transmission dynamics of COVID-19 with data spanning a nine-month period during 2020 in Hong Kong. The asymptotic stability of equilibria reveals that the model exhibits the phenomenon of backward bifurcation, which in this study is a co-existence between a stable disease-free equilibrium (DFE) and an endemic equilibrium (EE). Even if the basic reproduction number ([Formula: see text]) is less than unity, this disease cannot be eliminated. The effect of each parameter on the overall dynamics was assessed using Partial Rank Correlation Coefficients (PRCCs). Transmission rates (i.e., [Formula: see text] and [Formula: see text]), effective contact ratio [Formula: see text] between symptomatic individuals and quarantined people, and transfer rate [Formula: see text] related to infection during quarantine were identified to be the most sensitive parameters. The effective contact ratios between the infectors and susceptible individuals in late July were found to be over twice as high as that in March of 2020, reflecting pandemic fatigue and the potential existence of infection during quarantine.


Assuntos
COVID-19 , Pandemias , Número Básico de Reprodução , COVID-19/epidemiologia , Suscetibilidade a Doenças , Fadiga/epidemiologia , Humanos , Pandemias/prevenção & controle , Quarentena
7.
Sci Total Environ ; 751: 141610, 2021 Jan 10.
Artigo em Inglês | MEDLINE | ID: mdl-32877794

RESUMO

Energy service companies (ESCOs) have emerged to carry out energy efficiency retrofit projects, playing an essential role in mitigating carbon dioxide (CO2) emissions in China. However, it remains unclear how exactly ESCOs contribute to CO2 mitigation during urbanization and industrialization. We conducted regression analyses on data collected in 29 provinces in China as the first case study to investigate the moderating effect of ESCOs in relationships between urbanization, industrialization, and CO2 emissions. The results indicate that urbanization had a significantly negative influence on CO2 emissions. In contrast, industrialization displayed a statistically significant positive impact on CO2 emissions. ESCOs have a significant moderating effect on the relationship between industrialization, urbanization, and CO2 emissions. The analysis also revealed that ESCOs have a better performance in areas with lower industrialization and greater urbanization. ESCOs may invest more in regions with limited ESCO activities and huge CO2 emission reduction demand, while energy-saving technology innovation should be advocated in regions with sufficient ESCO activities.

8.
Chemosphere ; 274: 129750, 2021 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-33549880

RESUMO

To tackle the crisis associated with the rising commercial food waste generation, it is imperative to comprehend how corporates' recycling behaviour is influenced by different industry structures and economies. This study aims to fill in the information gap that various factors might be affecting corporates' recycling behaviour in two different economies due to environmental inequality by comparing upper-middle-income region (Malaysia) and high-income region (Hong Kong), respectively. A questionnaire survey regarding food waste management according to the Theory of Planned Behaviour was conducted with representatives coming from diverse industries of the hotel, food and beverage, and property management. The questionnaire responses were evaluated based on quantitative structural equation modelling and correlation analysis. The analysis results showed that the model fit the data well, explaining 78% of the variance in recycling behaviour. The findings demonstrated that the most substantial factor on individual's recycling intention by Malaysian commercial food waste generators was perceived behavioural control, and logistics and management incentives. Subjective norms demonstrated significant and adverse effects on the behaviour of food waste recycling. The variable of administrative incentives and corporate support presented strong positive correlations with moral attitudes as well as logistics and management incentives. Hotel industries from both Hong Kong and Malaysia have a higher acceptance level on human resources regarding food waste recycling. In comparison, food and beverage industries from both regions have a lower acceptance level. These findings could enrich our knowledge of the concerns in establishing regional policy strategies to encourage economic behavioural changes for sustainable development.


Assuntos
Eliminação de Resíduos , Gerenciamento de Resíduos , Alimentos , Hong Kong , Humanos , Malásia , Reciclagem
9.
J Hazard Mater ; 366: 573-581, 2019 03 15.
Artigo em Inglês | MEDLINE | ID: mdl-30572297

RESUMO

Multi-agent simulation (MAS) regulated by microbe-oriented thermodynamics and kinetics equations were performed for exploiting the interspecies dynamics and evolution in anaerobic respiration and bioelectrochemical systems. A newly-defined kinetically thermodynamic parameter is recognized microbes as agents in various conditions, including electron donors and acceptors, temperature, pH, etc. For verification of the MAS, the treatment of synthetic wastewater containing glucose and acetate was evaluated in four 25°C laboratory-scale reactors with different electron acceptors and cathode materials that had potential for methanogenesis, hydrogenesis, sulfidogenesis and exoelectrogenesis. Within 1000 h operation, the reactors performance and microbial structures using 16S rRNA sequencing matched with the MAS, suggesting acetoclastic exoelectrogenesis predominance (Geobacter). After 2400 h, MAS observed the co-existence of acetoclastic methanogenesis and acetoclastic and propionate exoelectrogenesis, as was reported previously. Such microbial evolution from the short-term to long-term operation likely resulted from the glucose-driven propionate. The MAS developed is applicable in a wide range of complex engineering and natural ecosystems.


Assuntos
Técnicas Eletroquímicas/métodos , Hidrogênio/química , Metano/metabolismo , Sulfetos/metabolismo , Termodinâmica , Cinética , RNA Ribossômico 16S/genética , Especificidade da Espécie
10.
Waste Manag ; 83: 161-170, 2019 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-30514463

RESUMO

Changing individual's recycling attitude and behaviour is of utmost importance in achieving sustainable construction and demolition (C&D) waste management, yet it has often been underachieved. To understand the motivations for recycling, this study identifies and prioritizes the key factors that affect C&D waste recycling behaviour of various stakeholders in Hong Kong (i.e., representatives from construction-waste-related organizations, environmental consultants and contractors, and government engineers) in a quantitative manner using statistical tools. Different from traditional C&D waste behavioural determinants studies, this paper utilizes an integrated analytical method through semi-structured interviews and survey questionnaire on the basis of Theory of Planned Behaviour (TPB). Qualitative thematic analysis and quantitative frequency analysis were performed to analyse responses from semi-structured interviews and questionnaires, followed by correlation analysis to quantify the relationships between factors. Results indicated that four key factors: (i) regulatory compliance, (ii) economic incentives, (iii) accreditation scheme, and (iv) logistics and management incentives directly influenced recycling behaviour of individuals. Regulatory compliance was the most determining factor for consultants, contractors, experts, and government officials, whereas economic incentives were of great concern to the public. Under the factor of economic incentives, strong positive relationships were identified between disposal costs and collection and sorting costs, thus increasing waste disposal charging fee may promote recycling behaviour. In comparison, accreditation scheme deserved better recognition to facilitate a closed-loop material flow in the construction industry. These findings help to devise more effective and stakeholder-oriented policy tools to raise awareness and encourage behavioural change towards C&D waste recycling, and assist policy makers to establish regulations and practices for sustainable resource management.


Assuntos
Indústria da Construção , Gerenciamento de Resíduos , Materiais de Construção , Hong Kong , Humanos , Reciclagem
11.
Accid Anal Prev ; 94: 8-17, 2016 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-27240124

RESUMO

The construction industry in Hong Kong increased its safety investment by 300% in the past two decades; however, its accident rate has plateaued to around 50% for one decade. Against this backdrop, researchers have found inconclusive results on the causal relationship between safety investment and safety performance. Using agent-based modeling, this study takes an unconventional bottom-up approach to study safety performance on a construction site as an outcome of a complex system defined by interactions among a worksite, individual construction workers, and different safety investments. Instead of focusing on finding the absolute relationship between safety investment and safety performance, this study contributes to providing a practical framework to investigate how different safety investments interacting with different parameters such as human and environmental factors could affect safety performance. As a result, we could identify cost-effective safety investments under different construction scenarios for delivering optimal safety performance.


Assuntos
Indústria da Construção , Saúde Ocupacional , Análise de Sistemas , Hong Kong , Humanos , Investimentos em Saúde , Organização e Administração , Segurança , Local de Trabalho
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