Research progress of metal organic frameworks and their derivatives for adsorption of anions in water: A review.

Anion pollution in water has become a problem that cannot be ignored. The anion concentration should be controlled below the national emission standard to meet the demand for clean water. Among the methods for removing excess anions in water, the adsorption method has a unique removal performance, and the core of the adsorption method is the adsorbent. In recent years, the emerging metal-organic frameworks (MOFs) have the advantages of adjustable porosity, high specific surface area, diverse functions, and easy modification. They are very competitive in the field of adsorption of liquid anions. This article focuses on the adsorption of fluoride, arsenate, chromate, radioactive anions (ReO4-, TcO4-, SeO42-/SeO32-), phosphate ion, chloride ion, and other anions by MOFs and their derivatives. The preparation methods of MOFs are introduced in turn, the application of different types of metal-based MOFs to adsorb various anions were discussed in categories with their crystal structure and functional groups. The influence on the adsorption of anions is analyzed, including the more common and special adsorption mechanisms, adsorption kinetics and thermodynamics, and regeneration performance are briefly described. Finally, the current situation of MOFs adsorption of anions is summarized, and the outlook for future development is summarized to provide my own opinions for the practical application of MOFs.

Curcumin Antagonizes Glucose Fluctuation-Induced Renal Injury by Inhibiting Aerobic Glycolysis via the miR-489/LDHA Pathway.

It has been considered that glucose fluctuation (GF) plays a role in renal injury and is related to diabetic nephropathy (DN) development. But the mechanism is still unclear. Aerobic glycolysis has become a topical issue in DN in recent years. There is an internal connection between GF, aerobic glycolysis, and DN. Curcumin (Cur) is a principal curcuminoid of turmeric and possesses specific protective properties in kidney functions. Cur also participates in the regulation of aerobic glycolysis switch. In this study, we first measured the levels of aerobic glycolysis and evaluated Cur's inhibitory ability in a cell model of HEK-293 under the condition of oscillating high glucose. The results indicated that GF exacerbated inflammation injury, oxidative stress, and apoptosis in HEK-293 cell, while Cur alleviated this cytotoxicity induced by GF. We found that GF increased aerobic glycolysis in HEK-293 cells and Cur presented a dose-dependent weakening effect to this exacerbation. Next, we built a panel of 17 miRNAs and 8 lncRNAs that were previously reported to mediate the Warburg effect. Our RT-qPCR results indicated that GF reduced the miR-489 content in the HEK-293 cell model and Cur could prevent this downregulation. Then, we planned to explore the character of miR-489 in Cur-triggered attenuation of the Warburg effect under GF condition. Our findings presented that Cur prevented GF-triggered aerobic glycolysis by upregulating miR-489 in HEK-293 cells. Next, we choose the miR-489/LDHA axis for further investigation. We confirmed that Cur prevented GF-triggered aerobic glycolysis via the miR-489/LDHA axis in HEK-293 cells. In conclusion, this study presented that Cur prevented GF-triggered renal injury by restraining aerobic glycolysis via the miR-489/LDHA axis in the HEK-293 cell model.

Oesophageal mucosal tears caused by suboptimal nasogastric tube insertion: a case study.

Oesophageal bezoars are one of the many causes of nasogastric tube obstruction; however, they are extremely rare and, therefore, not often considered to be the cause of a blockage. A bezoar is a solid mass of indigestible material that accumulates in the digestive tract. After a blockage is identified, the nasogastric tube is usually removed and another one inserted. However, this can be dangerous and can easily cause tearing of the oesophageal mucosa, bleeding, and other serious complications. In this article, the authors present a case of nasogastric tube obstruction caused by oesophageal bezoars. After the nasogastric tube was replaced, the patient experienced two tears of the oesophageal mucosa. This article highlights the importance of the introduction of a procedure for nurses to follow in cases of nasogastric tube obstruction, bearing in mind the possibility of the presence of oesophageal bezoars. If necessary, a gastroscope should be used to ensure safe insertion of the nasogastric tube and prevent oesophageal mucosal tears.

Research progresses on the application of perovskite in adsorption and photocatalytic removal of water pollutants.

The problem of global water pollution and scarcity of water resources is becoming increasingly serious. Multifunctional perovskites can well drive adsorption and photocatalytic reactions to remove water pollutants. There are many advantages of perovskites, such as abundant oxygen vacancies, easily tunable structural morphology, stable crystal state, highly active metal sites, and a wide photo response range. However, there are few reviews on the simultaneous application of perovskite to adsorption and photocatalytic removal of water pollutants. Thus, this paper discusses the preparation methods of perovskite, the factors affecting the adsorption of water environmental pollutants by perovskite, and the factors affecting perovskite photocatalytic water pollutants. The particle size, specific surface area, oxygen vacancies, electron-hole trapping agents, potentials of the valence band, and conduction band in perovskites are significant influencing factors for adsorption and photocatalysis. Strategies for improving the performance of perovskites in the fields of adsorption and photocatalysis are discussed. The adsorption behaviors and catalytic mechanisms are also investigated, including adsorption kinetics and thermodynamics, electrostatic interaction, ion exchange, chemical bonding, and photocatalytic mechanism. It summarizes the removal of water pollutants by using perovskites. It provides the design of perovskites as high-efficiency adsorbents and catalysts for developing new technologies.

Removal of fluoride from industrial wastewater by using different adsorbents: A review.

Many industries such as iron and steel metallurgy, copper and zinc smelting, the battery industry, and cement manufacturing industries discharge high concentrations of fluoride-containing wastewater into the environment. Subsequently, the discharge of high fluoride effluent serves as a threat to human life as well as the ecological ability to sustain life. This article analyses the advantages and drawbacks of some fluoride remediation technologies such as precipitation and flocculation, membrane technology, ion exchange technology, and adsorption technology. Among them, adsorption technology is considered the obvious choice and the best applicable technology. As such, several adsorbents with high fluoride adsorption capacity such as modified alumina, metal oxides, biomass, carbon-based materials, metal-organic frameworks, and other adsorption materials including their characteristics have been comprehensively summarized. Additionally, different adsorption conditions of the various adsorbents, such as pH, temperature, initial fluoride concentration, and contact time have been discussed in detail. The study found out that the composite synergy between different materials, morphological and structural control, and the strengthening of their functional groups can effectively improve the ability of the adsorbents for removing fluoride. This study has prospected the direction of various adsorbents for removing fluoride in wastewater, which would serve as guiding significance for future research in the field.