Advances in Functionalized Biocomposites of Living Cells Combined with Metal-Organic Frameworks.

Motivated by the remarkable innate characteristics of cells in living organisms, we have found that hybrid materials that combine bioorganisms with nanomaterials have significantly propelled advancements in industrial applications. However, the practical deployment of unmodified living entities is inherently limited due to their sensitivity to environmental fluctuations. To surmount these challenges, an efficacious strategy for the biomimetic mineralization of living organisms with nanomaterials has emerged, demonstrating extraordinary potential in biotechnology. Among them, innovative composites have been engineered by enveloping bioorganisms with a metal-organic framework (MOF) coating. This review systematically summarizes the latest developments in living cells/MOF-based composites, detailing the methodologies employed in structure fabrication and their diverse applications, such as bioentity preservation, sensing, catalysis, photoluminescence, and drug delivery. Moreover, the synergistic benefits arising from the individual compounds are elucidated. This review aspires to illuminate new prospects for fabricating living cells/MOF composites and concludes with a perspective on the prevailing challenges and impending opportunities for future research in this field.

High-Activity 2D/2D Core-Shell Structure to NiMoO4-Based Electrodes for Electrochemical Energy Storage.

The limited reactive active sites on the surface of NiMoO4 electrodes are the main bottleneck, restricting the rate performance of the corresponding supercapacitors (SCs). However, it is still a difficult problem to improve the utilization of redox reaction sites by adjusting the interface of the nickel molybdate (NiMoO4) electrode. This study reports a two-dimensional (2D)/2D core-shell electrode on a carbon cloth (CC) with NiMoO4 nanosheets grown on NiFeZn-LDH nanosheets (NFZ@NMO/CC). The interface of the 2D/2D core-shell structure promotes the redox reaction by improving OH- adsorption and diffusion capacity (diffusion coefficient = 1.47 × 10-7 cm2 s-1) and increasing the electrochemical active surface area (ECSA = 737.5 mF cm-2), which are much larger than the pure NiMoO4 electrode (2.5 × 10-9 cm2 s-1 and 177.5 mF cm-2). The NFZ@NMO/CC electrode exhibits an excellent capacitance of 2864.4 F g-1 at 1 A g-1 and an outstanding rate performance (92%), which is 3.18 times and 1.9 times those of the NiMoO4 nanosheets (33%) and the NiFeZn-LDH nanosheets (57.14%), respectively. Additionally, an asymmetric SC was assembled with NFZ@NMO/CC as the anode and Zn metal-organic framework (MOF)-derived carbon nanosheet (CNS)/CC as the cathode, which exhibited superior energy and power densities (70 Wh kg-1 and 709 W kg-1) with good cycling capability.

Oxygen-Doped Red Carbon Nitride: Enhanced Charge Separation and Light Absorption for Robust CO2 Photoreduction.

Utilizing artificial photosynthesis for the conversion of CO2 into value-added fuels has been recognized as a promising strategy for the ever-increasing energy crisis and the greenhouse effect. Herein, the element doping engineering of red spherical g-C3N4 having oxygen bonded with compositional carbon (C-O-C) for CO2 photoreduction has been explored to address this challenge. The C-O bond was formed by hydrothermal treatment with dicyandiamide and 1,3,5-trichlorotriazine. The experimental and DFT results displayed the optimum oxygen substitution sites and demonstrated that the oxygen doping greatly improved the light utilization efficiency, CO2 affinity, and charge carrier transfer, which enhanced photoreduction efficiency of CO2. The evolution rates of CO (47.2 µmol g-1) and CH4 (9.1 µmol g-1) using O-CN were much higher than that of bulk-CN without a cocatalyst. The main reason was the contribution of the O 2p orbital to the conduction band (CB) and valence band of O-CN, which effectively reduced the electron mass, facilitating electron/hole separation and enhancing its fluidity. Furthermore, the Fermi level also shifted to the bottom of the CB, leading to higher electron density, which further improved the CO2 reduction ability. Our study marks an important step for developing high-performance photocatalysts for reduction of CO2.

Vacancy-Rich CoSx@LDH@Co-NC Catalytic Membrane for Antibiotic Degradation with Mechanistic Insights.

Improving the wettability of carbon-based catalysts and overcoming the rate-limiting step of the Mn+1/Mn+ cycle are effective strategies for activating peroxymonosulfate (PMS). In this study, the coupling of Co-NC, layered double hydroxide (LDH), and CoSx heterostructure (CoSx@LDH@Co-NC) was constructed to completely degrade ofloxacin (OFX) within 10 min via PMS activation. The reaction rate of 1.07 min-1 is about 1-2 orders of magnitude higher than other catalysts. The interfacial effect of confined Co-NC and layered double hydroxide (LDH) not only enhanced the wettability of catalysts but also increased the vacancy concentration; it facilitated easier contact with the interface reactive oxygen species (ROS). Simultaneously, reduced sulfur species (CoSx) accelerated the Co3+/Co2+ cycle, acquiring long-term catalytic activity. The catalytic mechanism revealed that the synergistic effect of hydroxyl groups and reduced sulfur species promoted the formation of 1O2, with a longer lifespan and a longer migration distance, and resisted the influence of nontarget background substances. Moreover, considering the convenience of practical application, the CoSx@LDH@Co-NC-based catalytic membrane was prepared, which had zero discharge of OFX and no decay in continuous operation for 5.0 h. The activity of the catalytic membrane was also verified in actual wastewater. Consequently, this work not only provides a novel strategy for designing excellent catalysts but also is applicable to practical organic wastewater treatment.

Pd Nanosheet-Decorated 2D/2D g-C3N4/WO3·H2O S-Scheme Photocatalyst for High Selective Photoreduction of CO2 to CO.

The development of the global economy in recent years, environmental problems, greenhouse effect, and so forth have been of concern for countries all over the world. The key for solving the greenhouse effect is the reduction of CO2. With the development of photocatalytic reduction of CO2, hybrid photocatalytic nanostructures composed of noble metals and plasmonic semiconductors are being widely studied. In this work, S-scheme photocatalysts with a g-C3N4/WO3·H2O/Pd heterostructure was constructed by introducing ultrathin Pd nanosheets into the optimized 2D/2D g-C3N4/WO3·H2O binary system. The S-scheme charge transfer generated by the matched band gap of g-C3N4 and WO3·H2O can effectually improve the electron transfer rate and the redox ability of photogenerated carriers. The introduction of Pd nanosheets can inject a large number of hot electrons into the semiconductor on the basis of the S-scheme heterojunction to participate in the reaction. The S-scheme electron transfer method is used to improve the utilization rate of thermionic electrons and achieve the effect of widening the near-infrared-light absorption area of the composite material. Moreover, the reaction was carried out in water without the addition of any sacrificial agent, which can better reflect the green environmental protection of the experiment. This investigation will promote the broad-spectrum application of new and environment-friendly thermoelectron-assisted S-scheme photocatalysts, and on this basis, the possible reaction mechanism is discussed.

Interior and Surface Synergistic Modifications Modulate the SnNb2O6/Ni-Doped ZnIn2S4 S-Scheme Heterojunction for Efficient Photocatalytic H2 Evolution.

Interior and surface synergistic modifications can endow the photocatalytic reaction with tuned photogenerated carrier flow at the atomic level. Herein, a new class of 2D/2D SnNb2O6/Ni-doped ZnIn2S4 (SNO/Ni-ZIS) S-scheme heterojunctions is synthesized by a simple hydrothermal strategy, which was used to evaluate the synergy between interior and surface modifications. Theoretical calculations show that the S-scheme heterojunction boosts the desorption of H atoms for rapid H2 evolution. As a result, 25% SNO/Ni0.4-ZIS exhibits significantly improved PHE activity under visible light, roughly 4.49 and 2.00 times stronger than that of single ZIS and Ni0.4-ZIS, respectively. In addition, 25% SNO/Ni0.4-ZIS also shows superior structural stability. This work provides advanced insight for developing high-performance S-scheme systems from photocatalyst design to mechanistic insight.

Tailored Linker Defects in UiO-67 with High Ligand-to-Metal Charge Transfer toward Efficient Photoreduction of CO2.

Defect engineering can be used as a potential tool to activate metal-organic frameworks by regulating the pore structure, electronic properties, and catalytic activity. Herein, linker defects were effectively controlled by adjusting the amount of formic acid, and UiO-67 with different CO2 reduction capabilities was obtained. Among them, UiO-67-200 had the highest ability to selectively reduce CO2 to CO (12.29 µmol g-1 h-1). On the one hand, the results based on time-resolved photoluminescence decay curves and photochemical experiments revealed that UiO-67-200 had the highest charge separation efficiency. On the other hand, the linker defects affected the band structure of UiO-67 by changing the lowest unoccupied molecular orbital (LUMO) based on the density functional theory and UV-vis spectra. Hence, the proper linker defects enhanced the ligand-to-metal charge transfer process by promoting the transfer of electrons between the highest occupied molecular orbital and LUMO. Additionally, in situ Fourier transform infrared spectra and 13CO2 labeling experiments also indicated that COOH* was an important intermediate for CO formation and that CO originated from the photoreduction of CO2.

Construction of a ZnIn2S4/Au/CdS Tandem Heterojunction for Highly Efficient CO2 Photoreduction.

Photocatalytic CO2 reduction technology is of great importance to alleviate energy crisis and environmental pollution; however, it remains a serious challenge due to the fast recombination of carriers. In this study, we report a three-dimensional structure of a ZnIn2S4/Au/CdS composite photocatalyst for the CO2 reduction reaction, where Au nanoparticles (NPs) are evenly anchored on the surface of ZnIn2S4 by photodeposition and Au NPs are wrapped around by CdS. In ZnIn2S4/Au/CdS composite photocatalysts, Au NPs act as a bridge to construct a "semiconductor-metal-semiconductor" tandem electron transfer mechanism (ZnIn2S4 → Au → CdS) heterojunction, which greatly promotes the transfer of photogenerated electrons. It is worth noting that Au NPs, as a local surface plasmon resonance (LSPR) effect excited source to generate excited-state electrons, further improve the photoreduction CO2 activity. Under UV-vis light irradiation, the CO yield of ZnIn2S4/Au/CdS can reach 63.07 µmol·g-1·h-1, which is higher than that of 6.37 µmol·g-1·h-1 for pure ZnIn2S4, 0.93 µmol·g-1·h-1 for CdS, 8.9 µmol·g-1·h-1 for ZnIn2S4/CdS, 31.04 µmol·g-1·h-1 for ZnIn2S4/Au, and 5.37 µmol·g-1·h-1 for CdS/Au. In addition, the ternary ZnIn2S4/Au/CdS composite photocatalyst has good cyclic stability. This study broadens the idea of designing photocatalysts with good carrier separation efficiency.

Boosting H2 Production over C60 -Mediated NH2 -MIL-125(Ti)/Zn0.5 Cd0.5 S S-Scheme Heterojunction via Enhanced Interfacial Carrier Separation.

Improving greatly the separation efficiency of interfacial charge carrier is a major challenge in photocatalysis. Herein, a new class of C60 -mediated NH2 -MIL-125(Ti)/Zn0.5 Cd0.5 S S-scheme heterojunction with enhanced interfacial charge carrier separation is designed and synthesized. The constructed S-scheme heterojunction thermodynamically favors photocatalytic H2 evolution because of the large driving force resulting from its strong redox abilities. As a consequence, the optimum proportion of C60 -mediated NH2 -MIL-125(Ti)/Zn0.5 Cd0.5 S S-scheme heterojunction displays comparable H2 evolution activity with a rate of 7825.20 µmol h-1 g-1 under visible light irradiation, which is about 93.05 times, 6.38 times and 2.65 times higher than that of 2% C60 /NH2 -MIL-125(Ti), Zn0.5 Cd0.5 S and 45% NH2 -MIL-125(Ti)/Zn0.5 Cd0.5 S, and outperforms the majority of the previously reported MOFs-based photocatalysts. Spectroscopic characterizations and theory calculations indicate that the S-scheme heterojunction can powerfully promote the separation of photogenerated carriers. This work offers a new insight for future design and development of highly active MOFs-based photocatalysts.

Constructed Z-Scheme g-C3N4/Ag3VO4/rGO Photocatalysts with Multi-interfacial Electron-Transfer Paths for High Photoreduction of CO2.

Z-scheme g-C3N4/Ag3VO4/reduced graphene oxide (rGO) photocatalysts with multi-interfacial electron-transfer paths enhancing CO2 photoreduction under UV-vis light irradiation were successfully prepared by a hydrothermal process. Transmission electron microscope images displayed that the prepared photocatalysts have a unique 2D-0D-2D ternary sandwich structure. Photoelectrochemical characterizations including TPR, electrochemical impedance spectroscopy, photoluminescence, and linear sweep voltammetry explained that the multi-interfacial structure effectively improved the separation and transmission capabilities of photogenerated carriers. Electron spin resonance spectroscopy and band position analysis proved that the electron-transfer mode of g-C3N4/Ag3VO4 meets the Z-scheme mechanism. The introduction of rGO provided more electron-transfer paths for the photocatalysts and enhanced the stability of Ag-based semiconductors. In addition, the π-π conjugation effect between g-C3N4 and rGO further improved the generation and separation efficiency of photogenerated electron-hole pairs. Then, the multiple channels (Ag3VO4 → CN, Ag3VO4 → rGO → CN, and rGO → CN) due to the 2D-0D-2D structure greatly improving the photocatalytic CO2 reduction ability have been discussed in detail.

Biomass derived the V-doped carbon/Bi2O3 composite for efficient photocatalysts.

This work focused on the utilization of biological extract for the preparation of lignin-based carbon composites materials and used in the field of photocatalysis. A straightforward one-step carbonization way has been developed to prepare vanadium-doped lignin-based carbon/Bi2O3 composites photocatalyst by using sodium lignosulfonate as the carbon source and catalyst. The application of lignin as the carbon source to form photocatalyst support tends to control the uniform distribution. At the same time, sodium lignosulfonate as the catalyst could break down the BiVO4 during carbonization process. A series of characterizations demonstrated the BiVO4 was transformed into Bi2O3 and vanadium-doped lignin-based carbon. The possible synthesis process was proposed. Moreover, the novel V-doped carbon/Bi2O3 composites photocatalyst displayed higher photocatalytic activity than bare BiVO4. A possible photocatalytic mechanism was also discussed. This work provided new insight into the lignin-based carbon materials.

Construction of Heterogenous S-C-S MoS2/SnS2/r-GO Heterojunction for Efficient CO2 Photoreduction.

Photocatalytic reduction of CO2 by semiconductors is of great significance in generating value-added fuels. Here, we construct a novel S-C-S heterojunction constituted of MoS2/SnS2/r-GO by a simple solvothermal method. The prepared MoS2/SnS2/r-GO showed significant photoexcitation of photosensitive oxygen (ROS) by electron spin resonance spectroscopy, demonstrating that superoxide radicals (•O2-), pores, and hydroxyl radicals (•OH) are the main active species. The constructed S-C-S heterojunction has a multilevel electron transport mechanism and synergistic effect, which provides the possibility of producing more organic fuel. The photocatalytic materials were characterized by XRD, XPS, SEM, TEM, PL, etc. As a result, the atomic layer MoS2/SnS2/r-GO heterojunction exhibited a CO formation rate of 68.53 µmol g-1 h-1 and a CH4 formation rate of 50.55 µmol g-1 h-1, respectively. This work opens up new prospects for the formation of heterojunctions of chalcogenide transition-metal sulfides.

Construction of vesicle CdSe nano-semiconductors photocatalysts with improved photocatalytic activity: Enhanced photo induced carriers separation efficiency and mechanism insight.

Visible-light-driven photocatalysis as a green technology has attracted a lot of attention due to its potential applications in environmental remediation. Vesicle CdSe nano-semiconductor photocatalyst are successfully prepared by a gas template method and characterized by a variety of methods. The vesicle CdSe nano-semiconductors display enhanced photocatalytic performance for the degradation of tetracycline hydrochloride, the photodegradation rate of 78.824% was achieved by vesicle CdSe, which exhibited an increase of 31.779% compared to granular CdSe. Such an exceptional photocatalytic capability can be attributed to the unique structure of the vesicle CdSe nano-semiconductor with enhanced light absorption ability and excellent carrier transport capability. Meanwhile, the large surface area of the vesicle CdSe nano-semiconductor can increase the contact probability between catalyst and target and provide more surface-active centers. The photocatalytic mechanisms are analyzed by active species quenching. It indicates that h+ and O2- are the main active species which play a major role in catalyzing environmental toxic pollutants. Simultaneously, the vesicle CdSe nano-semiconductor had high efficiency and stability.

Novel TiO2/C3N4 Photocatalysts for Photocatalytic Reduction of CO2 and for Photocatalytic Decomposition of N2O.

TiO2/g-C3N4 photocatalysts with the ratio of TiO2 to g-C3N4 ranging from 0.3/1 to 2/1 were prepared by simple mechanical mixing of pure g-C3N4 and commercial TiO2 Evonik P25. All the nanocomposites were characterized by X-ray powder diffraction, UV-vis diffuse reflectance spectroscopy, photoluminescence, X-ray photoelectron spectroscopy, Raman spectroscopy, infrared spectroscopy, transmission electron microscopy, photoelectrochemical measurements, and nitrogen physisorption. The prepared mixtures along with pure TiO2 and g-C3N4 were tested for the photocatalytic reduction of carbon dioxide and photocatalytic decomposition of nitrous oxide. The pure g-C3N4 exhibited the lowest photocatalytic activity in both cases, pointing to a very high recombination rate of charge carriers. On the other hand, the most active photocatalyst toward all the products was (0.3/1)TiO2/g-C3N4. The highest activity is achieved by combination of a number of factors: (i) specific surface area, (ii) adsorption edge energy, (iii) crystallite size, and (iv) efficient separation of the charge carriers, where the efficient charge separation is the most decisive parameter.

Fabrication and evaluation of artemisinin-imprinted composite membranes by developing a surface functional monomer-directing prepolymerization system.

Inspired by a surface functional monomer-directing prepolymerization system, a straightforward and effective synthesis method was first developed to prepare highly regenerate and perm-selective molecularly imprinted composite membranes of artemisinin (Ars) molecules. Attributing to the formation of the prepolymerization system, Ars molecules are attracted and bound to the membrane surface, hence promoting the growth of homogeneous and high-density molecular recognition sites on the surface of membrane materials. Afterward, a two-step-temperature imprinting procedure was carried out to prepare the novel surface functional monomer capping molecularly imprinted membranes (FMIMs). The as-prepared FMIMs not only exhibited highly adsorption capacity (11.91 mg g(-1)) but also showed an outstanding specific selectivity (imprinting factor α is 4.50) and excellent perm-selectivity ability (separation factor ß is 10.60) toward Ars molecules, which is promising for Ars separation and purification.

The hierarchical dense structure induced high stability to NiCoB-based electrode for electrochemical energy storage.

The construction of stable hierarchical surfaces through structural engineering is the key to improve reactive active sites and cycle stability to achieve high cycle performance of supercapacitors (SCs). In this work, the NiCo-LDH nanoflower as a structure guide agent was used to support NiCoB nanosheets to form a dense and stable hierarchical structure, thereby exposing more active sites and improving cycle stability. Due to the hierarchical stable surface structure, the NiCoB-0.3@NiCo-LDH-30 electrode has an excellent specific capacitance of 2710F g-1 at 1 A/g due to the excellent electrochemical active surface area (1259 mF cm-2), improving the OH- diffusion coefficient (2.4 × 10-9 cm2 s-1) and decreasing ionic diffusion barrier. After 5000 cycles, NiCoB-0.3@NiCo-LDH-30 electrode still has 92.6 % initial specific capacitance. In order to balance the energy density decrease caused by the capacitance imbalance between positive and negative electrodes, the cubed carbon (Co-C) derived from cobalt metal organic frameworks (Co-MOFs) as cathode with a good specific capacitance of 220F g-1 at 1 A/g is prepared. The assembled NiCoB-0.3@NiCo-LDH-30//Co-C hybrid SCs (HSCs), which are assembled with NiCoB-0.3@NiCo-LDH-30 electrode as anode and Co-C electrode as cathode, displays an energy density of 75 Wh kg-1 at a power density of 741 W kg-1.

Coupling plasmon and catalytic-active hotspots of Au@Pt core-satellite nanoparticles for in-situ spectroscopic observation of plasmon-promoted decarboxylation.

Plasmon-induced hot carriers are a promising "active" energy source, attracting increasing attention for their potential applications in photocatalysis and photodetection. Here, we hybridize plasmonic Au spherical nanoparticles (SNPs) with catalytically active Pt nanocrystals to form Au@Pt core-satellite nanoparticles (CSNPs), which act as both an efficient catalyst for plasmon-promoted decarboxylation reaction and a robust surface-enhanced Raman scattering (SERS) substrate for plasmon-enhanced molecular spectroscopic detection. By regulating the coverage of Pt nanocrystals on the Au SNPs, we modulated the "hotspot" structures of the Au@Pt CSNPs to optimize the SERS detecting capability and catalytic decarboxylation performance. The coupling functionalities enable us with unique opportunities to in-situ SERS monitor universal reactions catalyzed by active catalysts (e.g. Pt, Pd) in the chemical industry in real-time. The decarboxylation rate of 4-mercaptophenylacetic acid was dynamically controlled by the surface catalytic decarboxylation step, following first-order overall reaction kinetics. Moreover, the reaction rate exhibited a strong correlation with the local field enhancement |E/E0|4 of the hotspot structure. This work provides spectroscopic insights into the molecule-plasmon interface under the plasmon-promoted catalytic reactions, guiding the rational design of the plasmonic interface of nanocatalysts to achieve desired functionalities.

A Recent Advancement in Food Quality Assessment: Using MOF-Based Sensors: Challenges and Future Aspects.

Monitoring food safety is crucial and significantly impacts the ecosystem and human health. To adequately address food safety problems, a collaborative effort needed from government, industry, and consumers. Modern sensing technologies with outstanding performance are needed to meet the growing demands for quick and accurate food safety monitoring. Recently, emerging sensors for regulating food safety have been extensively explored. Along with the development in sensing technology, the metal-organic frameworks (MOF)-based sensors gained more attention due to their excellent sensing, catalytic, and adsorption properties. This review summarizes the current advancements and applications of MOFs-based sensors, including colorimetric, electrochemical, luminescent, surface-enhanced Raman scattering, and electrochemiluminescent sensors. and also focused on the applications of MOF-based sensors for the monitoring of toxins such as heavy metals, pesticide residues, mycotoxins, pathogens, and illegal food additives from food samples. Future trends, as well as current developments in MOF-based materials.

Elucidating protonation pathways in CO2 photoreduction using the kinetic isotope effect.

The surge in anthropogenic CO2 emissions from fossil fuel dependence demands innovative solutions, such as artificial photosynthesis, to convert CO2 into value-added products. Unraveling the CO2 photoreduction mechanism at the molecular level is vital for developing high-performance photocatalysts. Here we show kinetic isotope effect evidence for the contested protonation pathway for CO2 photoreduction on TiO2 nanoparticles, which challenges the long-held assumption of electron-initiated activation. Employing isotopically labeled H2O/D2O and in-situ diffuse reflectance infrared Fourier transform spectroscopy, we observe H+/D+-protonated intermediates on TiO2 nanoparticles and capture their inverse decay kinetic isotope effect. Our findings significantly broaden our understanding of the CO2 uptake mechanism in semiconductor photocatalysts.

Construction of Au-modified CN-based donor-acceptor system coupled with dual photothermal effects for efficient photoreduction of carbon dioxide.

Conversion of CO2 into high value-added fuels through the photothermal effect is an effective approach for utilizing solar energy. In this study, we prepared the CN-based photocatalyst Py-CTN-Au with both donor-acceptor (D-A) system and dual photothermal effects using a simple two-step method involving calcination and photo-deposition. Real-time monitoring with a thermal imaging camera revealed that Py-CTN-Au0.5 achieved a maximum stable temperature of 180 °C, which was approximately 1.2 times higher than that of Py-CTN (155 °C) and 1.9 times higher than that of g-CN (95 °C) under the same reaction conditions. Under the optimized reaction conditions, Py-CTN-Au0.5 exhibited a CO release rate of 30.59 umol g-1 after 4 h of reaction, which was 7.3 times higher than that of pure g-CN (4.18 umol g-1). The D-A system not only facilitated the separation and transformation of charge carriers but also induced a photothermal effect to accelerate the photoreduction of CO2. Additionally, the cocatalyst Au nanoparticles (Au NPs) further enhanced the charge carrier dynamics and photothermal effect by increasing the built-in electric field intensity and localized surface plasmon resonance (LSPR) effect, respectively. The dual photothermal effects resulting from the non-radiative photon conversion of the D-A structure and the Au NPs LSPR effect, along with the enhanced charge carrier dynamics, catalyzed the efficient photoreduction of CO2. DFT simulations were used to confirm the effect of D-A system and Au NPs. In-situ FTIR results demonstrated that the synergistic photothermal effect promoted the formation of the key intermediate species COOH*, which is beneficial for the photocatalytic reduction of CO2. This study provides valuable insights into the multiple photothermal synergistic effects in photocatalytic reactions.