RESUMO
Ammonia and methanol are essential to modern societies, but their production has been heavily reliant on natural gas, which contributes to supply disruptions and significant CO2 emissions. While low-carbon or green production routes have been extensively researched, their adoption has been hindered by higher costs, making them unsustainable. However, a recent energy crisis in Europe has created a unique opportunity to shift towards greener production technologies. Here we show that, green ammonia, produced through wind-powered water electrolysis, had the potential to outperform its fossil counterpart for six months as of December 2021, while methanol produced through CO2 capture and wind-based water electrolysis became an economically appealing alternative. With a coordinated effort from academia, industry, and policymakers, Europe can lead the grand transition towards more sustainable practices in the chemical industry.
RESUMO
Reducing the amount of municipal solid waste (MSW) fed to incineration while enhancing source separation and biological treatments is being considered a mean to protect the environment and human health and promote recycling. However, such a strategy can compromises the landfill reduction targets while the associated environmental benefits remain so far unexplored and, in any case, any potential benefit should be evaluated for specific situations. In this study we applied material flow analysis (MFA) and life cycle assessment (LCA) to quantitatively evaluate the potential impact of phasing-out incineration in Madrid, Spain. The current MSW management system was assessed against future scenarios that describe the elimination of incineration as well as the increase of source separation, recycling, composting, and anaerobic digestion. The results revealed that incineration phase-out jeopardizes landfill reduction. However, phasing-out incineration can reduce the impact on acidification, terrestrial and marine eutrophication, photochemical ozone formation, human toxicity cancer effects, and ecotoxicity. The climate impact ranges from irrelevant to largely beneficial depending on how the biogenic carbon is considered. The transition towards a renewable electricity mix and the increase in source separation of biodegradable waste seriously compromise the climate benefits of incineration over landfilling. Overall, actions are required in order to align incineration phase-out with the landfill reduction objective, namely upgrading material recovery facilities to reduce rejects and seeking alternative pathways for the rejects that will always exist.