Clear Wood toward High-Performance Building Materials.

Developing advanced building materials with both excellent thermal insulating and optical properties to replace common glass (thermal conductivity of ∼1 W m-1 K-1) is highly desirable for energy-efficient applications. The recent development of transparent wood suggests a promising building material with many advantages, including high optical transmittance, tunable optical haze, and excellent thermal insulation. However, previous transparent wood materials generally have a high haze (typically greater than 40%), which is a major obstacle for their practical application in the replacement of glass. In this work, we fabricate a clear wood material with an optical transmittance as high as 90% and record-low haze of 10% using a delignification and polymer infiltration method. The significant removal of wood components results in a highly porous microstructure, much thinner wood cell walls, and large voids among the cellulose fibrils, which a polymer can easily enter, leading to the dense structure of the clear wood. The separated cellulose fibrils that result from the removal of the wood components dramatically weaken light scattering in the clear wood, which combined with the highly dense structure produces both high transmittance and extremely low haze. In addition, the clear wood exhibits an excellent thermal insulation property with a low thermal conductivity of 0.35 W m-1 K-1 (one-third of ordinary glass); thus, the application of clear wood can greatly improve the energy efficiency of buildings. The developed clear wood, combining excellent thermal insulating and optical properties, represents an attractive alternative to common glass toward energy-efficient buildings.

Thermally Conductive, Electrical Insulating, Optically Transparent Bi-Layer Nanopaper.

Cellulose nanofiber (CNF) from abundant and renewable wood is an emerging material with excellent mechanical, chemical, and optical properties. Transparent nanopaper made of CNF (CNF-nanopaper) could potentially replace plastics in electronics due to its excellent optical transparency, mechanical strength, and biodegradability. However, CNF-nanopaper normally has a low thermal conductivity and poor stability in increasing temperatures, which is not suitable for long-term stability and reliability in devices. Herein, for the first time, we report a thermally conductive, electrically insulating, and optically transparent nanopaper using a bilayer design where a thin layer of boron nitride (BN) nanosheets were coated on the CNF-nanopaper. An optical transparency (70%) and a thermal conductivity (0.76 W/m/K) were successfully achieved through a solution-based process at room temperature. Such an optically transparent, electrically insulating, and thermally conductive bilayer nanopaper can find applications in a range of electronic devices.

Self-Powered Human-Interactive Transparent Nanopaper Systems.

Self-powered human-interactive but invisible electronics have many applications in anti-theft and anti-fake systems for human society. In this work, for the first time, we demonstrate a transparent paper-based, self-powered, and human-interactive flexible system. The system is based on an electrostatic induction mechanism with no extra power system appended. The self-powered, transparent paper device can be used for a transparent paper-based art anti-theft system in museums or for a smart mapping anti-fake system in precious packaging and documents, by virtue of the advantages of adding/removing freely, having no impairment on the appearance of the protected objects, and being easily mass manufactured. This initial study bridges the transparent nanopaper with a self-powered and human-interactive electronic system, paving the way for the development of smart transparent paper electronics.