1.
Dalton Trans
; 44(20): 9359-62, 2015 May 28.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25919652
RESUMO
The reduction of titanocene dichloride with dysprosium yields a new titanocene(ii) equivalent without the need for further stabilising ligands. This reagent can be employed in combination with dithioacetals for the olefination of different carbonyl groups and allows for a simplified all-in-one procedure.
2.
Chem Commun (Camb)
; 50(73): 10655-7, 2014 Sep 21.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25077602
RESUMO
The divalent heteroleptic lanthanoid fluoride complex, [Yb(C5Ph4H)(µ-F)(thf)2]2, as well as [Yb(C5Ph4H)2(thf)] and [Yb(C5Ph4H)(C6F5)(thf)2] were obtained from reactions of ytterbium metal with Hg(C6F5)2 and tetraphenylcyclopentadiene under different conditions, and C-F activation of C6F5H by Yb metal was observed.