Separating Daily 1 km PM2.5 Inorganic Chemical Composition in China since 2000 via Deep Learning Integrating Ground, Satellite, and Model Data.

Fine particulate matter (PM2.5) chemical composition has strong and diverse impacts on the planetary environment, climate, and health. These effects are still not well understood due to limited surface observations and uncertainties in chemical model simulations. We developed a four-dimensional spatiotemporal deep forest (4D-STDF) model to estimate daily PM2.5 chemical composition at a spatial resolution of 1 km in China since 2000 by integrating measurements of PM2.5 species from a high-density observation network, satellite PM2.5 retrievals, atmospheric reanalyses, and model simulations. Cross-validation results illustrate the reliability of sulfate (SO42-), nitrate (NO3-), ammonium (NH4+), and chloride (Cl-) estimates, with high coefficients of determination (CV-R2) with ground-based observations of 0.74, 0.75, 0.71, and 0.66, and average root-mean-square errors (RMSE) of 6.0, 6.6, 4.3, and 2.3 µg/m3, respectively. The three components of secondary inorganic aerosols (SIAs) account for 21% (SO42-), 20% (NO3-), and 14% (NH4+) of the total PM2.5 mass in eastern China; we observed significant reductions in the mass of inorganic components by 40-43% between 2013 and 2020, slowing down since 2018. Comparatively, the ratio of SIA to PM2.5 increased by 7% across eastern China except in Beijing and nearby areas, accelerating in recent years. SO42- has been the dominant SIA component in eastern China, although it was surpassed by NO3- in some areas, e.g., Beijing-Tianjin-Hebei region since 2016. SIA, accounting for nearly half (∼46%) of the PM2.5 mass, drove the explosive formation of winter haze episodes in the North China Plain. A sharp decline in SIA concentrations and an increase in SIA-to-PM2.5 ratios during the COVID-19 lockdown were also revealed, reflecting the enhanced atmospheric oxidation capacity and formation of secondary particles.

Factors influencing the boundary layer height and their relationship with air quality in the Sichuan Basin, China.

We investigated the factors influencing the daily maximum boundary layer height (hmax) and their relationship with air quality in the Sichuan Basin, China. We analyzed the factors influencing hmax on cloudy and sunny days in winter using five years of observational data and a reanalysis dataset and investigated the relationship between hmax and air quality. The inversion layer in the lower troposphere has a critical impact on hmax on cloudy days. By contrast, the sensible heat flux and wind shear are the main influencing factors on sunny days, although the contribution of the sensible heat flux to hmax is less than that of the wind shear. This is because the turbulence is mainly affected by mechanical mixing induced by the topographic effect of the Tibetan Plateau to the west of the Sichuan Basin. The secondary circulation over the Sichuan Basin is weaker on cloudy days than on sunny days. These results are important for understanding the dispersion of air pollutants over the Sichuan Basin.