MOF-derived xPd-NPs@ZnO porous nanocomposites for ultrasensitive ppb-level gas detection with photoexcitation: Design, diverse-scenario characterization, and mechanism.

Metal-organic frameworks (MOFs) have been regarded as a potential candidate with great application prospects in the field of gas sensing. Although plenty of previous efforts have been made to improve the sensitivity of MOF-based nanocomposites, it is still a great challenge to realize ultrafast and high selectivity to typical flammable gases in a wide range. Herein, porous xPd-NPs@ZnO were prepared by optimized heat treatment, which maintained the controllable morphology and high specific surface area of 471.08 m2g-1. The coupling effects of photoexcitation and thermal excitation on the gas-sensing properties of nanocomposites were systematically studied. An ultrafast high response of 88.37 % towards 200 ppm H2 was realized within 1.2 s by 5.0Pd-NPs@ZnO under UV photoexcitation. All xPd-NPs@ZnO exhibited favorable linearity over an extremely wide range (0.2-4000 ppm H2) of experimental tests, indicating the great potential in quantitative detection. The photoexcited carriers enabled the nanocomposites a considerable response at lower operating temperatures, which made diverse applications of the sensors. The mechanisms of high sensing performances and the photoexcitation enhancement were systematically explained by DFT calculations. This work provides a solid experimental foundation and theoretical basis for the design of controllable porous materials and novel photoexcited gas detection.

Experimental study on a comparison of typical premixed combustible gas-air flame propagation in a horizontal rectangular closed duct.

Research surrounding premixed flame propagation in ducts has a history of more than one hundred years. Most previous studies focus on the tulip flame formation and flame acceleration in pure gas fuel-air flame. However, the premixed natural gas-air flame may show different behaviors and pressure dynamics due to its unique composition. Natural gas, methane and acetylene are chosen here to conduct a comparison study on different flame behaviors and pressure dynamics, and to explore the influence of different compositions on premixed flame dynamics. The characteristics of flame front and pressure dynamics are recorded using high-speed schlieren photography and a pressure transducer, respectively. The results indicate that the compositions of the gas mixture greatly influence flame behaviors and pressure. Acetylene has the fastest flame tip speed and the highest pressure, while natural gas has a faster flame tip speed and higher pressure than methane. The Bychkov theory for predicting the flame skirt motion is verified, and the results indicate that the experimental data coincide well with theory in the case of equivalence ratios close to 1.00. Moreover, the Bychkov theory is able to predict flame skirt motion for acetylene, even outside of the best suitable expansion ratio range of 6