Utilizing Edge-Oxidized Graphene Oxide to Enhance Cement Mortar's Properties Containing Crumb Rubber: Toward Achieving Sustainable Materials.

Scrap tires have become one of the most serious environmental issues worldwide in recent years. Exploiting this scrap has caught the attention of researchers in their efforts to conserve the environment. From a structural engineering materials perspective, a partial fine aggregate in cement mortar can be replaced by crumb rubber produced from scrap tires. This research mainly emphasizes the role of adding 0.1% edge-oxidized graphene oxide EOGO (by the weight of cement) in enhancing the properties of cement mortars containing 5%, 10%, and 15% of crumb rubber (by sand replacement). Cube and prism specimens were employed to investigate compressive and flexural strengths at 7- and 28-day curing ages. A porosity test was also conducted after 28 days of curing. In addition, a scanning electron microscopy (SEM) test was performed to investigate the effect of incorporating EOGO on the interfacial transition zone (ITZ). Results showed an enhancement of the mechanical properties of cement mortar, including compressive and flexural strengths, with the inclusion of EOGO in the mixes. The findings demonstrated that adding EOGO can improve the mechanical properties of mixes containing crumb rubber particles. Specifically, the mortar mix with 0.1% EOGO and 5% crumb rubber exhibited better performance compared with the virgin mix without rubber particles. Therefore, crumb rubber is viable for use as a sand replacement when EOGO is included.

Investigation of Alkali-Activated Slag-Based Composite Incorporating Dehydrated Cement Powder and Red Mud.

Recycled construction cementitious materials (RCCM) and red mud (RM) could be considered a type of discarded material with potential cementitious properties. Generally, landfilling and stacking are utilized to dispose of this type of solid waste, which can be detrimental to the environment and sustainability of the construction sector. Accordingly, a productive process for making eco-efficient alkali-activated slag-based samples with the inclusion of RCCM and red mud is studied in this paper. Dehydrated cement powder (DCP) is attained through the high-temperature treatment of RCCM, and red mud can be obtained from the alumina industry. Subsequently, DCP and RM are utilized as a partial substitute for granulated blast furnace slag (GBFS) in alkali-activated mixtures. Two different batches were designed; the first batch had only DCP at a dosage of 15%, 30%, 45%, and 60% as a partial substitute for GBFS, and the second batch had both DCP and RM at 15%, 30%, 45%, and 60% as a partial substitute for GBFS. Different strength and durability characteristics were assessed. The findings show that when both dehydrated cement powder and red mud are utilized in high quantities, the strength and durability of the specimens were enhanced, with compressive strength improving by 42.2% at 28 days. Such improvement was obtained when 7.5% each of DCP and RM were added. The results revealed that DCP and RM have a negative effect on workability, whilst they had a positive impact on the drying shrinkage as well as the mechanical strength. X-ray diffraction and micro-structural analysis showed that when the amount of DCP and RM is increased, a smaller number of reactive products forms, and the microstructure was denser than in the case of the samples made with DCP alone. It was also confirmed that when DCP and RM are used at optimized dosages, they can be a potential sustainable binder substitute; thus, valorizing wastes and inhibiting their negative environmental footprint.

Mechanical and Sorptivity Characteristics of Edge-Oxidized Graphene Oxide (EOGO)-Cement Composites: Dry- and Wet-Mix Design Methods.

This paper aims to investigate the effects of edge-oxidized graphene oxide nanoflakes (EOGO) on the mechanical properties and sorptivity of cement composites. The EOGO used in this study was produced by a mechanochemical process that assists the production of EOGO in large quantities at significantly reduced costs, enabling its practical use for infrastructure construction. The scope of this work includes the use of EOGO as an additive in cement composites, including cement paste and mortar. This study explores two mixing methods: The dry-mix method and the wet-mix method. The dry-mix method uses EOGO as dry powder in cement composites whereas the wet-mix method uses a water-dispersed solution (using a sonication process). Varied percentages of EOGO, ranging from 0.01% to 1.0%, were used for both methods. To evaluate the concrete durability, the effect of EOGO addition on sorptivity of the cement composites was investigated by performing total porosity and water sorptivity tests. It was found that 0.05% of EOGO is the optimum proportion to exert the highest strength in compressive and flexural strength tests. In addition, the dry-mix method is comparable to the wet-mix method (with dispersion of EOGO), thus more practical for field engineering applications.