Key issues to consider when using alum sludge as substrate in constructed wetland.

Globally, alum sludge is an easily, locally and largely available by-product from water treatment plants where aluminium sulphate is used as the coagulant for raw water purification. Owing to the high content of Al ions (29.7±13.3% dry weight) in alum sludge and the strong affinity of Al ions to adsorb various pollutants especially phosphorus (P), alum sludge (in the form of dewatered cakes) has been investigated in recent years as a low-cost alternative substrate in constructed wetland (CW) systems to enhance the treatment efficiency especially for high strength P-containing wastewater. Long-term trials in different scales have demonstrated that the alum sludge-based CW is a promising technique with a two-pronged feature of using 'waste' for wastewater treatment. Alum sludge cakes in CW can serve as a medium for wetland plant growth, as a carrier for biofilm development and as a porous material for wastewater infiltration. After the intensive studies of the alum sludge-based CW system, this paper aims to address the key issues and concerns pertaining to this kind of CW system. These include: (1) Is alum sludge suitable for reuse in CWs? (2) Is Al released from the sludge a concern? (3) What is the lifespan of the alum sludge in CWs? (4) How can P be recovered from the used alum sludge? (5) Does clogging happen in alum sludge-based CW systems and what is the solution?

Achieving an extraordinary high organic and hydraulic loadings with good performance via an alternative operation strategy in a multi-stage constructed wetland system.

In this study, a high organic loading rate of 58-146 g BOD5/m2 day with a hydraulic loading rate (HLR) of 1.63 m3/m2 day and retention time (RT) of 16 h was achieved to maximize the treatment capacity of a four-stage alum sludge-based constructed wetland (CW) system. An alternative operation strategy, i.e., the first stage anaerobic up-flow and the remaining stage tidal flow with effluent recirculation, was investigated to achieve the goal with good treatment performance of 82% COD, 91% BOD5, 92% SS, 94% NH4-N, and 82% TN removal. Two kinetic models, i.e., first-order model and Monod plus continuous stirred-tank reactor (CSTR) flow model, were employed for predicting the removal dynamics. The results showed that the tidal flow strategy enhances oxygen transport and diffusion, thus improving reduction of organics and NH4-N. Effluent recirculation could further increase elimination of organics by extending the interaction time and also benefit the denitrification process. In addition, denitrification could be further enhanced by anaerobic up-flow in the first stage.