Characterization of the laser-induced breakdown spectroscopy near the gas-liquid two-phase interface.

The characterization of laser-induced breakdown spectroscopy (LIBS) near the gas-liquid two-phase interface was investigated with the laser acting on the sample along the horizontal direction. Simulation of the laser beam focusing process and observation of laser beam spot images show that difference in focusing positions in the air and the solution results from refraction of the laser beam entering the solution from the air and the change of propagation direction on the container lateral. The peak power and mean irradiance of the focused laser beam spot increase with the distance away from the interface, which is attributed to the fact that the loss of laser energy due to the refraction and reflection of light at the interface decreases with the focusing position moving away from the interface. This variation trend of laser irradiance allows for the growth of the spectral line intensity and lifetime with increasing the distance from the interface. The plasma electron density and temperature decrease with the delay time but increase with the distance away from the interface at the same delay time. Our findings help us to gain more insight into the characteristics and evolution mechanisms of LIBS produced near the gas-liquid two-phase interface, which provides theoretical guidance for the correction of LIBS spectra especially in water pollution monitoring.

Signal enhancement of laser-induced breakdown spectroscopy on non-flat samples by single beam splitting.

A single-beam-splitting approach was employed to enhance the signal intensity of LIBS under the extreme condition of laser beam grazing the surface of non-flat samples. Examining the time-integrated emission spectra shows that ISplit/ISingle enhancement factors of 2.5 and 3.5 were achieved at the laser energy of 33 mJ for aluminium alloy and brass, respectively. This factor first increases, reaches its maximum at 33 mJ, and drops gradually with the laser energy further increased. The mechanisms behind the enhanced optical emission and the enhancement factor evolution are discussed by using the proposed laser ablation model and laser-supported detonation (LSD) wave model, respectively. Examining the time-resolved emission spectra show that enhancement effect exists across all the plasma expansion process and the split beam mode allows for a longer plasma lifetime. A remarkable feature is that the trailing phenomenon emerging in the single beam mode vanishes due to the interaction between the plasmas generated by the grazing incident and normally incident laser beams in the split beam mode. The underlying cause is probably that the plasma plume produced by the normally incident laser beam prevents the grazing incident laser beam from further propagating and ablating the sample surface below. These findings not only give an insight into the plasma generation and evolution at grazing incidence of laser beam on sample surface but also provide a more reliable method for outdoor LIBS measurement of irregular samples.

Time-resolved characteristics of laser induced breakdown spectroscopy on non-flat samples by single beam splitting.

A single-beam-splitting approach was used to enhance the signal intensity of LIBS under the extreme conditions of laser beam grazing of the surface of non-flat samples. Time-resolved spectra show that the laser-ablated plasma presents a stronger spectral intensity and a slower plasma decay in the split beam mode because of the higher laser irradiance. The temporal evolutions of signal enhancement factors indicate that the enhancement effect first rises and then drops with delay time and the maximum enhancement factor of Al plasma comes later than that of Cu plasma under the same laser energy. The mechanisms behind it are discussed. It is also found that the electron density exhibits a faster decay with delay time in the split beam mode, mainly due to the faster plasma expansion. And a slower increase of electron density with laser energy is observed in the split beam mode because of the plasma shielding effect.

A Highly Cost-Efficient Large-Scale Uniform Laminar Plasma Jet Array Enhanced by V-I Characteristic Modulation in a Non-Self-Sustained Atmospheric Discharge.

Developing cost-efficient large-scale uniform plasma jets represents a significant challenge for high performance in material processing and plasma medicine. Here, a V-I characteristic modulation approach is proposed to reduce the discharge power and increase the plasma scale and chemical activity in non-self-sustained atmospheric direct-current discharges. The electric field in discharge space is optimized to fundamentally empower simultaneously initiating all discharge cells far below Townsend breakdown potential and stably sustaining each plasma jet at low voltage. These strategies create a crucial step to fabricating a flexible and compact low-power large-scale uniform laminar plasma jet array (LPJA) with high activity in cheap argon. The mechanisms behind the discharge enhancement are revealed by combining V-I characteristic examination and a modulation model. Compared with conventional arrays, this LPJA possesses the widest size (90 mm) and raises its uniformity from 30% to 97%. Comparing different discharge modes shows that the LPJA scale is surprisingly increased nearly by 4 times with the discharge power reduced from 7.4 to 4.8 W. The methodology provides a highly cost-efficient roadmap to break through the bottleneck of restricting low-power discharge, large-gap discharge, large-scale discharge, parallel-multi-electrode discharge, and uniform discharge together. This advance will meet the urgent need for various plasma applications.

A highly efficient magnetically confined ion source for real time on-line monitoring of trace compounds in ambient air.

We fabricate a high-efficient ion source for real time on-line monitoring of trace compounds in ambient air by introducing a weak longitudinal magnetic field to a micro-fabricated DC glow discharge. Mass spectrometric detection of various samples indicates that the signal intensity increases by an order of magnitude and the limit of detection can be lowered to 1/10 of the original level. This improvement results from the increasing ion transport efficiency through the magnetic confinement.