Energy-Transfer-Induced Multiexcitation and Enhanced Emission of Hyperbranched Polysiloxane.

Fluorescent hyperbranched polysiloxane (HBPSi) has attracted increasing attention due to its good biocompatibility. However, its emission mechanism remains an open question. Unfortunately, the excitation spectra of HBPSi are rarely systematically investigated and show a narrow excitation band, which hinders the emission mechanism study. Herein, we synthesized a series of novel HBPSi containing l-glutamic acid (HBPSi-GA). Surprisingly, these polymers have four excitation peaks and two emission peaks, which are caused by the energy transfer from free functional groups to heterogeneous electron delocalizations in different clusters. Meanwhile, the fluorescence and biocompatibility of HBPSi-GA are significantly improved with increasing l-glutamic acid. Furthermore, HBPSi-GA exhibits dual stimuli-responsive fluorescence to temperature and Fe3+ as well as potential application in cell imaging. This research possesses important guidance to develop multiexcitation unconventional fluorescent polymers.

Towards conductive hydrogels in e-skins: a review on rational design and recent developments.

Over the past decades, electronic skins (e-skins) have attracted significant attention owing to their feasibility of applications in health monitoring, motion detection, and entertainment. As a class of soft materials, conductive hydrogels feature biocompatibility, stretchability, adhesiveness, and self-healing properties, making them one of the most important candidates for high-performance e-skins. However, profound challenges remain for achieving the combination of superior mechanical strength and conductivity of conductive hydrogels simultaneously without sacrificing their multifunctionalities. Herein, a framework for rational designs to fabricate conductive hydrogels are proposed, including the fundamental strategies of copolymerization, doping, and self-assembly. In addition, we provide a comprehensive analysis of their merits and demerits when the conductive hydrogels are fabricated in different ways. Furthermore, the recent progress and future perspective for conductive hydrogels in terms of electronic skins are highlighted.