RESUMO
We have made a series of measurements, as a function of pulse duration, of ionization and fragmentation of the asymmetric molecule N2O in intense femtosecond laser radiation. The pulse length was varied from 7 fs to 500 fs with intensity ranging from 4 × 10(15) to 2.5 × 10(14) W∕cm(2). Time and position sensitive detection allows us to observe all fragments in coincidence. By representing the final dissociation geometry with Dalitz plots, we can identify the underlying breakup dynamics. We observe for the first time that there are two stepwise dissociation pathways for N2O(3+): (1) N2O(3+) â N(+) + NO(2+) â N(+) + N(+) + O(+) and (2) N2O(3+) â N2 (2+) + O(+) â N(+) + N(+) + O(+) as well as one for N2O(4+) â N(2+) + NO(2+) â N(2+) + N(+) + O(+). The N2 (2+) stepwise channel is suppressed for longer pulse length, a phenomenon which we attribute to the influence which the structure of the 3+ potential has on the dissociating wave packet propagation. Finally, by observing the total kinetic energy released for each channel as a function of pulse duration, we show the increasing importance of charge resonance enhanced ionization for channels higher than 3+.
RESUMO
Governments and municipalities need to understand their citizens' psychological needs in critical times and dangerous situations. COVID-19 brings lots of challenges to deal with. We propose NeedFull, an interactive and scalable tweet analysis platform, to help governments and municipalities to understand residents' real psychological needs during those periods. The platform mainly consists of four parts: data collection module, data storage module, data analysis module and data visualization module. The four parts interact with each other and provide users with a thorough human needs analysis based on their queries. We employed the proposed platform to investigate the reaction of people in New York State to the ongoing worldwide COVID-19 pandemic.