RESUMO
The crystal structure of a newly synthesized compound, [PbL(Ac)]2 , (where L=2 (amino(pyrazin-2-yl) methylene) hydrazinecarbothioamide, Ac=acetate anion) exhibits a close contact between pairs of Pb atoms, suggesting a ditetrel bond, in addition to two Pbâ â â O tetrel bonds, and two C-Hâ â â O H-bonds. The presence of this ditetrel bond as an attractive component is confirmed by various quantum chemical methods. This novelty of this particular bond is its existence even in the absence of a σ-hole on the Pb atom, which is typically considered a prerequisite for a bond of this type. From a wider perspective, a survey of the Cambridge Structural Database suggests this bond may be more common than was hitherto thought, with 44 examples of Pbâ â â Pb contacts amongst a total number of 219 examples of Tâ â â T interactions in general (T=Si, Ge, Sn, Pb).
Assuntos
Chumbo , Ânions , Modelos MolecularesRESUMO
We received a complaint from the Université Catholique de Louvain [...].
RESUMO
Four dioxidovanadium(V) complexes with Schiff-base ligands based on 2-hydroxybenzhydrazide with four different substituted salicylaldehydes (5-chlorosalicylaldehyde, 3,5-dichlorosalicylaldehyde, 5-nitrosalicylaldehyde, 3-bromo-5-chlorosalicylaldehyde) were synthesized and described, by using V2O5 and triethylamine. The single crystal X-ray structure measurements as well as elemental analyses and IR spectra confirmed the formulas of the ionic complexes with a protonated triethylamine acting as counterion, HTEA[VO2(L)] (HL = Schiff-base ligand). The kinetic stability of the complexes at pH = 2 and 7 was discussed with respect to the neutral vanadium(V) complexes previously studied as potential insulin-mimetic agents. A correlation between the substituents in an aromatic ring of the Schiff-base ligands with crystal packing, and also with the stability of the compounds, was presented.
Assuntos
Complexos de Coordenação , Vanádio , Ligantes , Vanádio/química , Insulina , Bases de Schiff/química , Íons , Complexos de Coordenação/químicaRESUMO
The blockade of kainate receptors, in particular with non-competitive antagonists, has-due to their anticonvulsant and neuroprotective properties-therapeutic potential in many central nervous system (CNS) diseases. Deciphering the structural properties of kainate receptor ligands is crucial to designing medicinal compounds that better fit the receptor binding pockets. In light of that fact, here, we report experimental and computational structural studies of four indole derivatives that are non-competitive antagonists of GluK1/GluK2 receptors. We used X-ray studies and Hirshfeld surface analysis to determine the structure of the compounds in the solid state and quantum chemical calculations to compute HOMO and LUMO orbitals and the electrostatic potential. Moreover, non-covalent interaction maps were also calculated. It is worth emphasizing that compounds 3 and 4 are achiral molecules crystallising in non-centrosymmetric space groups, which is a relatively rare phenomenon.
Assuntos
Indóis , Receptores de Ácido Caínico , Indóis/farmacologia , Ligantes , Ligação Proteica , Receptores de Ácido Caínico/química , Receptores de Ácido Caínico/metabolismoRESUMO
This study represents synthesis, characterization, screening of antibiofilm efficacy, and cytotoxicity of iridium bis-terpyridine complexes. The complexes were characterized by NMR, MS, FTIR, UV/Visible, and fluorescence spectroscopies. The efficacy of biofilm inhibition and eradication of iridium complexes was evaluated using a crystal violet assay test and verified by fluorescence microscopy. Cytotoxicity and apoptosis analysis of iridium complexes were determined in this study. The results of our study revealed that three iridium complexes had the potential to inhibit biofilm formation and moderate the ability to destroy pre-formed biofilm of S. aureus ATCC 29,213. 250 µM concentration of synthesized complexes showed the highest antibiofilm activity (75% for Ir1, 90% for Ir2, and 71% for Ir3). The significant inhibition obtained at 6.25 µM concentration of Ir2 and Ir3 revealed the potential of our samples. Also, Ir1 and Ir2 complexes had a good capacity to destroy pre-formed biofilm. The results clearly showed that iridium complexes have cytotoxic activity towards colon cancer (Caco-2) and liver cancer (HepG2) cell lines without affecting non-cancerous cells (HEK293) at applied doses. Moreover, tested compounds induced apoptosis in these cancer cells. All of these results showed that iridium complexes had possessed the ability to inhibit or destroy pre-formed biofilm and could be developed as an effective agent against bacterial biofilms. Moreover, these pure substances may have valuable anti-cancer activity and it should be confirmed with further studies for therapeutic effects.
Assuntos
Antibacterianos/farmacologia , Antineoplásicos/farmacologia , Biofilmes/efeitos dos fármacos , Complexos de Coordenação/farmacologia , Staphylococcus aureus/efeitos dos fármacos , Antibacterianos/síntese química , Antibacterianos/química , Antineoplásicos/síntese química , Antineoplásicos/química , Linhagem Celular , Proliferação de Células/efeitos dos fármacos , Sobrevivência Celular/efeitos dos fármacos , Complexos de Coordenação/síntese química , Complexos de Coordenação/química , Relação Dose-Resposta a Droga , Ensaios de Seleção de Medicamentos Antitumorais , Humanos , Irídio/química , Irídio/farmacologia , Testes de Sensibilidade Microbiana , Estrutura Molecular , Piridinas/química , Piridinas/farmacologia , Relação Estrutura-AtividadeRESUMO
In this work, we report solvent-induced complexation properties of a new N2S2 tetradentate bis-thiosemicarbazone ligand (H2LI), prepared by the condensation of 4-phenylthiosemicarbazide with bis-aldehyde, namely 2,2'-(ethane-1,2-diylbis(oxy)dibenzaldehyde, towards nickel(II). Using ethanol as a reaction medium allowed the isolation of a discrete mononuclear homoleptic complex [NiLI] (1), for which its crystal structure contains three independent molecules, namely 1-I, 1-II, and 1-III, in the asymmetric unit. The doubly deprotonated ligand LI in the structure of 1 is coordinated in a cis-manner through the azomethine nitrogen atoms and the thiocarbonyl sulfur atoms. The coordination geometry around metal centers in all the three crystallographically independent molecules of 1 is best described as the seesaw structure. Interestingly, using methanol as a reaction medium in the same synthesis allowed for the isolation of a discrete mononuclear homoleptic complex [Ni(LII)2] (2), where LII is a monodeprotonated ligand 2-(2-(2-(2-(dimethoxymethyl)phenoxy)ethoxy)benzylidene)-N-phenylhydrazine-1-carbothioamide (HLII). The ligand LII was formed in situ from the reaction of LI with methanol upon coordination to the metal center under synthetic conditions. In the structure of 2, two ligands LII are coordinated in a trans-manner through the azomethine nitrogen atom and the thiocarbonyl sulfur atom, also yielding a seesaw coordination geometry around the metal center. The charge and energy decomposition scheme ETS-NOCV allows for the conclusion that both structures are stabilized by a bunch of London dispersion-driven intermolecular interactions, including predominantly N-HâââS and N-HâââO hydrogen bonds in 1 and 2, respectively; they are further augmented by less typical C-HâââX (where X = S, N, O, π), CHâââHC, πâââπ stacking and the most striking, attractive long-range intermolecular C-HâââNi preagostic interactions. The latter are found to be determined by both stabilizing Coulomb forces and an exchange-correlation contribution as revealed by the IQA energy decomposition scheme. Interestingly, the analogous long-range C-HâââS interactions are characterized by a repulsive Coulomb contribution and the prevailing attractive exchange-correlation constituent. The electron density of the delocalized bonds (EDDB) method shows that the nickel(II) atom shares only ~0.8|e| due to the σ-conjugation with the adjacent in-plane atoms, demonstrating a very weak σ-metalloaromatic character.
Assuntos
Níquel/química , Tiossemicarbazonas/química , Aldeídos/química , Compostos Azo/química , Complexos de Coordenação/química , Cristalografia por Raios X/métodos , Ligação de Hidrogênio , Ligantes , Modelos Moleculares , Estrutura Molecular , Solventes/química , Tiossemicarbazonas/metabolismoRESUMO
Extensive experimental and theoretical investigations are reported on the nature of resonance-assisted hydrogen bonding phenomenon (RAHB) and its influence on photophysical properties of the newly designed dyes differing in donor-acceptor properties, namely ethyl N-salicylideneglycinate (1), ethyl N-(5-methoxysalicylidene)glycinate (2), ethyl N-(5-bromosalicylidene)glycinate (3) and ethyl N-(5-nitrosalicylidene)glycinate (4). All compounds are thermochromic in the solid state and they contain a typical intramolecular O-Hâ â â N hydrogen bond formed between the hydroxyl hydrogen atom and the imine nitrogen atom, yielding the enol form in the solid state. It is unveiled, that the magnitude of RAHB effect fine tunes the strength of the O-Hâ â â N bonding and accordingly the relative populations of the enol, cis-keto and trans-keto forms leading to variation of the photophysical properties of 1-4. It is determined, that the electron-withdrawing NO2 in 4 amplifies the most RAHB effect causing the breaking of the O-Hâ â â N hydrogen bond and accordingly formation of the dominant cis-keto isomer in both the solid state and EtOH. To this end, the UV/Vis spectra of 1-3 in EtOH revealed the exclusive presence of the enol form, while the prevalent contribution of the cis-keto form was found for 4. Furthermore, only compoundâ 4 is emissive in the solid state in ambient condition due to dual emission arising from the cis-keto* and trans-keto* forms, while 2 was found to be highly emissive in EtOH. It is revealed qualitatively and quantitatively, based on the ETS-NOCV charge and energy decomposition scheme and the EDDB population-based method, that RAHB is strongly a non-local phenomenon based on electrons pumping or sucking through both the π- and σ-channels, which accordingly exerts chemical bonding changes at both the phenyl ring and predominantly a distant O-Hâ â â N area.
RESUMO
The reaction of 4'-(2-thienyl)-2,2':6',2,2''-terpyridine (S-terpy) with the heterometallic complexes [Au2Ag2R4(OEt2)2]n (R = C6F5, C6Cl5) leads to the compounds [{Au(C6X5)2}Ag(S-terpy)]n (X = F (1), Cl (2)). The X-ray diffraction analysis of the complexes shows an alternating disposition of the metals -Au-Ag-Au-Ag- in 1D infinite polymeric chains. Despite the fact of having the same metallic sequence, the spatial arrangement observed for both complexes is very different, since for [{Au(C6F5)2}Ag(S-terpy)]n (1) the metals adopt a zigzag disposition, whereas an helicoidal distribution of the interacting metals is observed for the complex [{Au(C6Cl5)2}Ag(S-terpy)]n (2). These different arrangements are related to the perhalophenyl ligands present in the complexes, which appear with different spatial dispositions, being staggered in the case of C6F5 (1) and almost eclipsed in the case of C6Cl5 (2). In order to explain the reasons for these different structural arrangements, we performed a DFT-D3 computational analysis and a subsequent study of the qualitative characterization of the noncovalent interactions (NCIs) in real space.
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A new supramolecular Pb(II) complex [PbL(NO2)]n was synthesized from Pb(NO3)2, N'-(1-(pyridin-2-yl)ethylidene)isonicotinohydrazide (HL) and NaNO2. [PbL(NO2)]n is constructed from discrete [PbL(NO2)] units with an almost ideal N2O3 square pyramidal coordination environment around Pb(II). The ligand L- is coordinated through the 2-pyridyl N-atom, one aza N-atom, and the carbonyl O-atom. The nitrite ligand binds in a κ2-O,O coordination mode through both O-atoms. The Pb(II) center exhibits a hemidirected coordination geometry with a pronounced coordination gap, which allows a close approach of two additional N-atoms arising from the N=C(O) N-atom of an adjacent molecule and from the 4-pyridyl N-atom from the another adjacent molecule, yielding a N4O3 coordination, constructed from two Pb-N and three Pb-O covalent bonds, and two Pbâ¯N tetrel bonds. Dimeric units in the structure of [PbL(NO2)]n are formed by the Pbâ¯N=C(O) tetrel bonds and intermolecular electrostatically enforced π+â¯π- stacking interactions between the 2- and 4-pyridyl rings and further stabilized by C-Hâ¯π intermolecular interactions, formed by one of the methyl H-atoms and the 4-pyridyl ring. These dimers are embedded in a 2D network representing a simplified uninodal 3-connected fes (Shubnikov plane net) topology defined by the point symbol (4â82). The Hirshfeld surface analysis of [PbL(NO2)] revealed that the intermolecular Hâ¯X (X = H, C, N, O) contacts occupy an overwhelming majority of the molecular surface of the [PbL(NO2)] coordination unit. Furthermore, the structure is characterized by intermolecular Câ¯C and Câ¯N interactions, corresponding to the intermolecular πâ¯π stacking interactions. Notably, intermolecular Pbâ¯N and, most interestingly, Pbâ¯H interactions are remarkable contributors to the molecular surface of [PbL(NO2)]. While the former contacts are due to the Pbâ¯N tetrel bonds, the latter contacts are mainly due to the interaction with the methyl H-atoms in the πâ¯π stacked [PbL(NO2)] molecules. Molecular electrostatic potential (MEP) surface calculations showed marked electrostatic contributions to both the Pbâ¯N tetrel bonds and the dimer forming π+â¯π- stacking interactions. Quantum theory of atoms in molecules (QTAIM) analyses underlined the tetrel bonding character of the Pbâ¯N interactions. The manifold non-covalent interactions found in this supramolecular assembly are the result of the proper combination of the polyfunctional multidentate pyridine-hydrazide ligand and the small nitrito auxiliary ligand.
Assuntos
Isoniazida/química , Chumbo/química , Cristalografia por Raios X , Teoria da Densidade Funcional , Dimerização , Modelos Moleculares , Conformação Molecular , Teoria Quântica , Eletricidade EstáticaRESUMO
We report the design as well as structural and spectroscopic characterizations of two new coordination compounds obtained from Cd(NO3)2·4H2O and polydentate ligands, benzilbis(pyridin-2-yl)methylidenehydrazone (LI) and benzilbis(acetylpyridin-2-yl)methylidenehydrazone (LII), in a mixture with two equivalents of NH4NCS in MeOH, namely [Cd(SCN)(NCS)(LI)(MeOH)] (1) and [Cd(NCS)2(LII)(MeOH)] (2). Both LI and LII are bound via two pyridyl-imine units yielding a tetradentate coordination mode giving rise to the 12 π electron chelate ring. It has been determined for the first time (qualitatively and quantitatively), using the EDDB electron population-based method, the HOMA index, and the ETS-NOCV charge and energy decomposition scheme, that the chelate ring containing CdII can be classified as a quasi-aromatic Möbius motif. Notably, using the methyl-containing ligand LII controls the exclusive presence of the NCS- connected with the CdII atom (structure 2), while applying LI allows us to simultaneously coordinate NCS- and SCN- ligands (structure 1). Both systems are stabilized mostly by hydrogen bonding, C-H···π interactions, aromatic π···π stacking, and dihydrogen C-H···H-C bonds. The optical properties have been investigated by diffused reflectance spectroscopy as well as molecular and periodic DFT/TD-DFT calculations. The DFT-based ETS-NOCV analysis as well as periodic calculations led us to conclude that the monomers which constitute the obtained chelates are extremely strongly bonded to each other, and the calculated interaction energies are found to be in the regime of strong covalent connections. Intramolecular van der Waals dispersion forces, due to the large size of LI and LII, appeared to significantly stabilize these systems as well as amplify the aromaticity phenomenon.
RESUMO
We report design and structural characterization of six new coordination polymers fabricated from PbCl2 and a series of closely related bis-pyridyl ligands LI and HLII-HLVI, namely, [Pb2(LI)Cl4]n, [Pb(HLII)Cl2]n·nMeOH, [Pb(HLIII)Cl2]n·0.5 nMeOH, [Pb2(LIV)Cl3]n, [Pb(HLV)Cl2]n, and [Pb3(LVI)2Cl4]n·nMeOH. The topology of the obtained networks is dictated by the geometry of the organic ligand. The structure of [Pb2(LI)Cl4]n is constructed from the [PbCl2]n two-dimensional (2D) sheets, linked through organic linkers into a three-dimensional framework, which exhibits a unique binodal 4,7-connected three-periodic topology named by us as sda1. Topological analysis of the 2D metal-organic sheet in [Pb(HLII)Cl2]n·nMeOH discloses a binodal 3,4-connected layer topology, regardless of the presence of tetrel bonds. A one-dimensional (1D) coordination polymer [Pb(HLIII)Cl2]n·0.5 nMeOH is considered as a uninodal 2-connected chain. The overall structure of [Pb2(LIV)Cl3]n is constructed from dimeric tetranuclear [Pb4(µ3-LIV-κ6N:N':Nâ³:µ3-O)2(µ4-Cl)(µ2-Cl)2]3+ cationic blocks linked in a zigzag manner through bridging µ2-Cl- ligands, yielding a 1D polymeric chain. Topological analysis of this chain reveals a unique pentanodal 3,4,4,5,6-connected chain topology named by us as sda2. The structure of [Pb(HLV)Cl2]n exhibits a 1D zigzaglike polymeric chain. Two chains are further linked into a 1D gridlike ribbon through the dimeric [Pb2(µ2-Cl)2Cl2] blocks as bridging nodes. With the bulkiest ligand HLVI, a 2D layered coordination polymer [Pb3(LVI)2Cl4]n·nMeOH is formed, which network, considering all tetrel bonds, reveals a unique heptanodal 3,3,3,3,4,5,5-connected layer topology named by us as sda3. Compounds [Pb2(LI)Cl4]n, [Pb2(LIV)Cl3]n, and [Pb(HLV)Cl2]n were found to be emissive in the solid state at ambient temperature. While blue emission of [Pb2(LI)Cl4]n is due to the ligand-centered transitions, bluish-green and white luminescence of [Pb2(LIV)Cl3]n and [Pb(HLV)Cl2]n, respectively, was assigned to ligand-to-metal charge transfer mixed with metal-centered excited states. Molecular as well as periodic calculations were additionally applied to characterize the obtained polymers.
RESUMO
Three solid materials, [Pb(HL)(SCN)2 ]â CH3 OH (1), [Pb(HL)(SCN)2 ] (2), and [Pb(L)(SCN)]n (3), were obtained from Pb(SCN)2 and an unsymmetrical bis-pyridyl hydrazone ligand that can act both as a bridging and as a chelating ligand. In all three the lead center is hemidirectionally coordinated and is thus sterically optimal for participation in tetrel bonding. In the crystal structures of all three compounds, the lead atoms participate in short contacts with thiocyanate sulfur or nitrogen atoms. These contacts are shorter than the sums of the van der Waals radii (3.04-3.47â Å for Pbâ â â S and 3.54â Å for Pbâ â â N) and interconnect the covalently bonded units (monomers, dimers, and 2D polymers) into supramolecular assemblies (chains and 3D structures). DFT calculations showed these contacts to be tetrel bonds of considerable energy (6.5-10.5â kcal mol(-1) for Pbâ â â S and 16.5â kcal mol(-1) for Pbâ â â N). A survey of structures in the CSD showed that similar contacts often appear in crystals of Pb(II) complexes with regular geometries, which leads to the conclusion that tetrel bonding plays a significant role in the supramolecular chemistry of Pb(II) .
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A new amphiphilic azo-functionalized polyhedral oligomeric silsesquioxane (POSS) derivative was synthesized by functionalizing octa(3-aminopropyl)silsesquioxane (OAS-POSS) with 4-((4-(dodecyloxy)phenyl)diazenyl)benzoic acid, affording a hydrophilic amino POSS head and hydrophobic dodecyl tail with a diphenyl-azo connector. Prepared amphiphilic azo-functionalized POSS (azo-POSS) exhibited high ability for encapsulation and transferring cationic dyes into the organic phase by vigorously mixing with aqueous solutions of each dye. The photo-controlled encapsulating properties of the synthesized phase transfer reagent was studied using cationic dyes, such as methylene blue (MB), crystal violet (CV) and thymol blue in acidic conditions. Results showed more than 95 % encapsulation of MB. However, no considerable encapsulation was shown in the case of anionic dyes such as eriochrome black T (EBT) and thymol blue in alkaline solutions. By trans/cis isomerization of the azo moiety of the phase transfer reagent by UV irradiation (365â nm), the amount of dye encapsulation was decreased, which could be attributed to the formation of cis isomer that led to the folding of the dodecyl alkyl tail on the POSS moiety, and therefore prevent to lay the 3-aminopropyl moieties of POSS head to the water/DCM interface to adsorb and encapsulate MB molecules.
RESUMO
In this work, we report on the synthesis of a novel zinc(II) coordination compound [ZnL2] (1), which was readily obtained from the reaction of Zn(OAc)·2H2O and N'-(pyridin-2-ylmethylene)nicotinohydrazide (HL) in methanol. Recrystallization of 1 from dimethylformamide under ambient conditions allowed to produce yellow block-like crystals of 1·H2O. Complex 1·H2O was characterized by FT-IR and 1H NMR spectroscopy, while its optical properties were studied by UV-vis and spectrofluorimetry in methanol. The crystal structure of the title complex was revealed by single crystal X-ray diffraction and further explored in detail by the Hirshfeld surface analysis. Theoretical investigations based on the DFT calculations have also been applied to show the electronic properties of complex 1. The antitumor activities of the parent ligand HL and complex 1 were studied using Dalton's lymphoma malignant cancer model. Both compounds were found to induce concentration-dependent cytotoxicity and apoptotic cell death, leading to a decrease in cell viability, body weight, and tumor volume in mice with the superior activity of complex 1 over HL. Mice treated with complex 1 demonstrated an increase in life span with a survival period of 23 days. Finally, using a molecular docking approach, we have probed complex 1 to inhibit the recombinant mouse tumor-necrosis factor alpha (mTNF).
Assuntos
Antineoplásicos , Complexos de Coordenação , Zinco , Zinco/química , Complexos de Coordenação/farmacologia , Complexos de Coordenação/síntese química , Complexos de Coordenação/química , Animais , Camundongos , Antineoplásicos/farmacologia , Antineoplásicos/síntese química , Antineoplásicos/química , Humanos , Cristalografia por Raios X , Linhagem Celular Tumoral , Apoptose/efeitos dos fármacos , Sobrevivência Celular/efeitos dos fármacosRESUMO
The synthesis of novel metal-organic coordination polymers (MOCP) with the chemical formula [Mn2L (SCN)2(OH)2]3·CH3OH [L = 1,5-bis(pyridine-4-ylmethylene) carbonohydrazide] {1} was accomplished using two different techniques: solvothermal and sonochemical ultrasonic-assisted. An investigation was carried out to examine the impact of various factors such as reaction time, sonication power, temperature, and reactant concentration on the morphology and size of the crystals. Interestingly, it was found that sonication power and temperature did not affect the crystals' morphology and size. To further analyze the prepared microcrystals of MOCPs, SEM was utilized to examine their surface morphology, and XRD, elemental evaluation composition. The identification of the functional groups present in the prepared Mn-MOCPs was accomplished through the utilization of FT-IR spectroscopy. Subsequently, the calcination of 1 in an air atmosphere at 650 °C led to the formation of Mn3O4 nanoparticles. The geometric and electronic structure of the MOCPs was evaluated using density functional theory (DFT). The utilization of molecular docking methodologies demonstrated that the best cavity of the human androgen receptor possessed an interaction energy of -116.3 kJ mol-1. This energy encompassed a combination of both bonding and non-bonding interactions. The Results showed that steric interaction and electrostatic potential are the main interactions in AR polymer and Mn(II). These interactions in the defined cavity indicated that this polymer could be an effective anti-prostate candidate, because AR is involved in the growth of prostate cancer cells, and these interactions indicated the inhibition of prostate cancer cell growth.
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The polymeric linear chain [AuTl(C6Cl5)2]n reacts with three terpyridine-type ligands substituted with thiophene groups containing N-donor centres in different relative positions (L1, L2 and L3), leading to the Au(I)/Tl(I) complexes [AuTl(C6Cl5)2(L1)]n (1), [{AuTl(C6Cl5)2}2(L2)]n (2) and [AuTl(C6Cl5)2(L3)]n (3). X-Ray diffraction studies reveal that L1 acts as a chelate, while L2 and L3 act as bridging ligands, resulting in different coordination indexes for the thallium(I) centre. These structural differences strongly influence their optical properties, and while compounds 2 and 3 emit near the limit of the visible range, complex 1 emits in the infrared region. DFT calculations have also been carried out in order to determine the origin of the electronic transitions responsible for their optical properties.
RESUMO
Cellulose nanofibers decorated with SiO2 nanoparticles (SiO2-CNF) were prepared by the extraction of cellulose nanofibers from Yucca leaves, followed by modification with SiO2 nanoparticles, and used as efficient materials for the removal of both anionic and cationic dyes from the aqueous solution. Prepared nanostructures were characterized using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction powder (XRD), Thermogravimetric analysis (TGA), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), and transmission electron microscopy (TEM) analysis. The adsorption capacity of the nanostructures was investigated for the removal of both cationic (Methylene Blue, MB, and Crystal Violet, CV) and anionic (Eriochrome Black-T, EB) dyes. The kinetics of adsorption were investigated using some well-known models, including intraparticular diffusion (IPD), pseudo-first-order (PFO), pseudo-second-order (PSO), and Elovich. The adsorption isotherms were also explored using the Langmuir, Freundlich, Temkin, and Redlich-Peterson models. The obtained results revealed that the adsorption processes follow PSO kinetic and Langmuir isotherm models. Thermodynamic parameters of the adsorption were measured at different temperatures, indicating the feasibility and spontaneity of the adsorption. The pH and salt effects on adsorption were also explored. Finally, according to the reusability tests, the prepared adsorbents showed high recoverability without considerable loss in adsorption efficiency after five repeated runs.
Assuntos
Nanofibras , Nanopartículas , Poluentes Químicos da Água , Corantes/química , Dióxido de Silício , Cinética , Celulose , Espectroscopia de Infravermelho com Transformada de Fourier , Termodinâmica , Cátions , Adsorção , Poluentes Químicos da Água/química , Concentração de Íons de HidrogênioRESUMO
Shape-memory polymers and alloys are adaptable materials capable of reversing from a deformed, metastable phase to an energetically favored original phase in response to external stimuli. In the context of metal-organic frameworks, the term shape-memory is defined as the property of a switchable framework to stabilize the reopened pore phase after the first switching transition. Herein we describe a novel flexible terpyridine MOF which, upon desolvation, transforms into a nonporous structure that reopens into a shape-memory phase when exposed to CO2 at 195 K. Based on comprehensive in situ experimental studies (SC-XRD and PXRD) and DFT energetic considerations combined with literature reports, we recommend dividing shape-memory MOFs into two categories, viz responsive and nonresponsive, depending on the transformability of the gas-free reopened pore phase into the collapsed phase. Furthermore, considering the methodological gap in discovering and understanding shape-memory porous materials, we emphasize the importance of multicycle physisorption experiments for dynamic open framework materials, including metal-organic and covalent organic frameworks.
RESUMO
The relevance of hydrogen-bonding, π-π stacking and aurophilic interactions in the solid-state of two new heterobimetallic (AuI -MnII ) complexes is analyzed in this manuscript. They are discrete complexes of formulae [Mn(bipy)2 (H2 O){Au(CN)2 }][Au(CN)2 ] and [Mn(dmbipy)2 {Au(CN)2 }] â H2 O, (bipy=2,2'-bipyridine and dmbipy=5,5'-dimethyl-2,2'-bipyridine), which are based on dicyanidoaurate(I) groups and 2,2'-bipyridyl-like co-ligands. They have been synthesized in good yields and X-ray characterized. In both compounds, aurophilic, OHâ â â N hydrogen bonding and π-π interactions governed the supramolecular assemblies in the solid state. These contacts with special emphasis on the aurophilic interactions have been studied using density functional theory calculations and characterized using the quantum theory of atoms-in-molecules and the noncovalent interaction plot. The aurophilic contacts have been also rationalized from an orbital point of view using the natural bond orbital methodology, evidencing stabilization energies up to 5.7â kcal/mol. Moreover, the interaction energies have been decomposed using the Kitaura-Morokuma energy decomposition analysis, confirming the importance of electrostatic and orbital effects.
RESUMO
In the title coordination polymer, [Hg4Cl4(C26H20N6)](n), one Hg(II) ion is coordinated by four N atoms from the benzylbis((pyridin-2-yl)methyl-idenehydrazone) ligand and two Clâ» ions in a very distorted cis-HgCl2N4 octa-hedral geometry. The other Hg(II) ion is coordinated in a distorted tetra-hedral geometry by four Clâ» ions. Bridging chloride ions link the Hg(II) ions into a chain propagating in [010]: the Hg-Cl bridging bonds are significantly longer than the terminal bonds. The dihedral angle between the central benzene rings of the ligand is 83.3â (2)°. The packing is consolidated by weak C-Hâ¯Cl hydrogen bonds and C-Hâ¯π inter-actions.