Integrating Mobile and Fixed-Site Black Carbon Measurements to Bridge Spatiotemporal Gaps in Urban Air Quality.

Urban air pollution can vary sharply in space and time. However, few monitoring strategies can concurrently resolve spatial and temporal variation at fine scales. Here, we present a new measurement-driven spatiotemporal modeling approach that transcends the individual limitations of two complementary sampling paradigms: mobile monitoring and fixed-site sensor networks. We develop, validate, and apply this model to predict black carbon (BC) using data from an intensive, 100-day field study in West Oakland, CA. Our spatiotemporal model exploits coherent spatial patterns derived from a multipollutant mobile monitoring campaign to fill spatial gaps in time-complete BC data from a low-cost sensor network. Our model performs well in reconstructing patterns at fine spatial and temporal resolution (30 m, 15 min), demonstrating strong out-of-sample correlations for both mobile (Pearson's R ∼ 0.77) and fixed-site measurements (R ∼ 0.95) while revealing features that are not effectively captured by a single monitoring approach in isolation. The model reveals sharp concentration gradients near major emission sources while capturing their temporal variability, offering valuable insights into pollution sources and dynamics.

High-resolution urban air pollution mapping.

Variation in urban air pollution arises because of complex spatial, temporal, and chemical processes, which profoundly affect population exposure, human health, and environmental justice. This Review highlights insights from two popular in situ measurement methods-mobile monitoring and dense sensor networks-that have distinct but complementary strengths in characterizing the dynamics and impacts of the multidimensional urban air quality system. Mobile monitoring can measure many pollutants at fine spatial scales, thereby informing about processes and control strategies. Sensor networks excel at providing temporal resolution at many locations. Increasingly sophisticated studies leveraging both methods can vividly identify spatial and temporal patterns that affect exposures and disparities and offer mechanistic insight toward effective interventions. This Review summarizes the strengths and limitations of these methods and discusses their implications for understanding fine-scale processes and impacts.

Meteorology governs the variation of Delhi's high particulate-bound chloride levels.

A significant number of past studies have reported Delhi to witness some of the highest levels of particulate-bound chloride compared to anywhere else in the world. The present study employs long-term, highly time-resolved chloride measurements at the IIT Delhi campus from February 2020 to April 2021. The present work sheds light on the dependence of high chloride levels in Delhi on the winds from the northwest direction. The study makes use of linear regression models and stepped linear models to quantify the role of meteorological variables in driving the seasonal variation of chloride in Delhi. The results indicate that ∼85-88% of the variation in chloride concentration observed in Delhi can be attributed to meteorological parameters, mainly temperature (T), relative humidity (RH), and percentage of wind incoming from the northwest (%NW). The results also suggest that the primary chloride emissions remain relatively consistent year-round, and are regionally transported from Delhi's northwest. The results of this study provide valuable insights in understanding the nature of the sources and the variability associated with the chloride levels in Delhi and thus provide a basis for future emission control strategies.

Variation in chemical composition and sources of PM2.5 during the COVID-19 lockdown in Delhi.

The Government of India (GOI) announced a nationwide lockdown starting 25th March 2020 to contain the spread of COVID-19, leading to an unprecedented decline in anthropogenic activities and, in turn, improvements in ambient air quality. This is the first study to focus on highly time-resolved chemical speciation and source apportionment of PM2.5 to assess the impact of the lockdown and subsequent relaxations on the sources of ambient PM2.5 in Delhi, India. The elemental, organic, and black carbon fractions of PM2.5 were measured at the IIT Delhi campus from February 2020 to May 2020. We report source apportionment results using positive matrix factorization (PMF) of organic and elemental fractions of PM2.5 during the different phases of the lockdown. The resolved sources such as vehicular emissions, domestic coal combustion, and semi-volatile oxygenated organic aerosol (SVOOA) were found to decrease by 96%, 95%, and 86%, respectively, during lockdown phase-1 as compared to pre-lockdown. An unforeseen rise in O3 concentrations with declining NOx levels was observed, similar to other parts of the globe, leading to the low-volatility oxygenated organic aerosols (LVOOA) increasing to almost double the pre-lockdown concentrations during the last phase of the lockdown. The effect of the lockdown was found to be less pronounced on other resolved sources like secondary chloride, power plants, dust-related, hydrocarbon-like organic aerosols (HOA), and biomass burning related emissions, which were also swayed by the changing meteorological conditions during the four lockdown phases. The results presented in this study provide a basis for future emission control strategies, quantifying the extent to which constraining certain anthropogenic activities can ameliorate the ambient air. These results have direct relevance to not only Delhi but the entire Indo-Gangetic plain (IGP), citing similar geographical and meteorological conditions common to the region along with overlapping regional emission sources. SUMMARY OF MAIN FINDINGS: We identify sources like vehicular emissions, domestic coal combustion, and semi-volatile oxygenated organic aerosol (SVOOA) to be severely impacted by the lockdown, whereas ozone levels and, in turn, low-volatility oxygenated organic aerosols (LVOOA) rise by more than 95% compared to the pre-lockdown concentrations during the last phase of the lockdown. However, other sources resolved in this study, like secondary chloride, power plants, dust-related, hydrocarbon-like organic aerosols (HOA), and biomass burning related emissions, were mainly driven by the changes in the meteorological conditions rather than the lockdown.