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Biochem Biophys Res Commun ; 590: 139-144, 2022 01 29.
Artigo em Inglês | MEDLINE | ID: mdl-34974302

RESUMO

In Brazil, the major vector of arboviruses is Aedes aegypti, which can transmit several alpha and flaviviruses. In this work, a pacifastin protease inhibitor library was constructed and used to select mutants for Ae. aegypti larvae digestive enzymes. The library contained a total of 3.25 × 105 cfu with random mutations in the reactive site (P2-P2'). The most successfully selected mutant, TiPI6, a versatile inhibitor, was able to inhibit all three Ae. aegypti larvae proteolytic activities, trypsin-like, chymotrypsin-like and elastase-like activities, with IC50 values of 0.212 nM, 0.107 nM and 0.109 nM, respectively. In conclusion, the TiPI mutated phage display library was shown to be a useful tool for the selection of an inhibitor of proteolytic activities combined in a mix. TiPI6 is capable of controlling all three digestive enzyme activities present in the larval midgut extract. To our knowledge, this is the first time that one inhibitor containing a Gln at the P1 position showed inhibitory activity against trypsin, chymotrypsin, and elastase-like activities. TiPI6 can be a candidate for further larvicidal studies.


Assuntos
Aedes/enzimologia , Inibidores Enzimáticos/farmacologia , Biblioteca de Peptídeos , Proteínas/farmacologia , Sequência de Aminoácidos , Animais , Proteínas de Insetos/química , Proteínas de Insetos/isolamento & purificação , Proteínas de Insetos/metabolismo , Larva/efeitos dos fármacos , Proteínas Mutantes/química , Proteínas Mutantes/isolamento & purificação , Mutação/genética , Inibidores da Tripsina
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