RESUMO
To assure a smooth and cost-efficient flow of crude oil emulsion from wells to a production facility, the oil industry relies heavily on the prediction of viscosity in pipe. The physical expression of this viscosity depends on a subjective estimate of a maximum packing volume fraction (compacity), ranging between 58 and 74 vol%. This inaccurate practice can lead to catastrophic loss of pump efficiency. Two new concepts were defined to describe the emulsion: its compacity; and the occupancy of water droplets at the oil-water interface. This development leads to a better understanding of the formation and disappearance of a suspension, and can assist in building a reliable phenomenological model of the sedimentation and coalescence of an emulsion. Theoretical and experimental approaches were conducted to investigate the packing of water droplets in emulsions. A 3D packing model was developed to explain the observations made during emulsification experiments. It was found that below a water volume fraction of 34 vol%, water droplets settle, under the effect of gravity, in a loose-packed zone; and then sediment in a dense-packed zone (DPZ). The DPZ exists between a water volume fraction of 34 vol% and 60 vol%. The maximum compacity is the upper limit of this zone; and has a value of 60.46%. Knowing this objective value, other parameters affecting the viscosity can be better studied.
Assuntos
Petróleo , Emulsões , Água , ViscosidadeRESUMO
Demulsification of water-in-crude oil emulsions is an essential and sometimes challenging procedure for crude oil processing facilities. Pulse field gradient (PFG) NMR techniques are known to monitor the dynamics of emulsion separation. This method has limitations that restrict its application to some crude oils. A comprehensive methodology applicable to all types of crude oil regardless of its viscosity, without assumptions, and providing a large number of data with fast measurements, is proposed in this paper. The coalescence and sedimentation of unstable emulsions was observed through simultaneous measurements of the evolution of the brine profile and droplet size distribution (DSD). Measurements of emulsions after stabilization, with and without the contribution of the free water layer, revealed the residual emulsified water quantity and location in the sample. A new, faster approach to separate the oil and water overlapping T2 relaxation signals was demonstrated on real water-in-crude oil emulsions, using the root mean square displacement (RMSD) measured with the spoiler recovery and a loop of 13-interval pulsed field gradient stimulated echo (PFGSTE) oneshot sequences. The residual water within the crude oils after separation was determined and used to quantify the efficiency of the demulsifier used.
RESUMO
Small-angle X-ray scattering (SAXS) analysis of the diblock copolymer poly(styrene-b-(4-vinyl)pyridine) in a ternary solvent system of 1,4-dioxane, tetrahydrofuran, and N,N-dimethylformamide, and the triblock terpolymer poly(isoprene-b-styrene-b-(4-vinyl)pyridine) in a binary solvent system of 1,4-dioxane and tetrahydrofuran, reveals a concentration-dependent onset of ordered structure formation. Asymmetric membranes fabricated from casting solutions with polymer concentrations at or slightly below this ordering concentration possess selective layers with the desired nanostructure. In addition to rapidly screening possible polymer solution concentrations, solution SAXS analysis also predicts hexagonal and square pore lattices of the final membrane surface structure. These results suggest solution SAXS as a powerful tool for screening casting solution concentrations and predicting surface structure in the fabrication of asymmetric ultrafiltration membranes from self-assembled block copolymers.