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1.
Langmuir ; 38(12): 3860-3867, 2022 Mar 29.
Artigo em Inglês | MEDLINE | ID: mdl-35293214

RESUMO

When a water droplet strikes a superhydrophobic surface, there may be several to a few tens of rebounds before it comes to rest. Although this intriguing multiphase flow phenomenon has received a great deal of attention from interfacial scientists and engineers, the underlying dynamics have not yet been completely resolved. In this paper, we report on an experimental investigation into the bouncing behavior of water droplets impinging on macroscopically flat superhydrophobic surfaces. We show that the restitution coefficient, which quantifies the energy consumed during impact and rebound, exhibits a nonmonotonic dependence on the Weber number. It is the droplet-surface friction that restricts the rebound height of the impinging droplet, so its restitution coefficient increases with the Weber number when the impact velocity is below a critical value. Above this value, the viscous friction within a thin liquid layer close to the superhydrophobic surface becomes dominant, and thus, the restitution coefficient decreases sharply. On the basis of energy analyses, semiempirical formulas are proposed to describe the restitution coefficient, and these can be employed to predict the number of successive rebounds of impinging droplets on superhydrophobic surfaces.

2.
Sci Rep ; 12(1): 11920, 2022 Jul 13.
Artigo em Inglês | MEDLINE | ID: mdl-35831383

RESUMO

Spraying occurs by the impact of water droplets on the superhydrophobic wire meshes by liquid penetration during the spreading and recoiling. We have shown that adding a small amount of high molecular weight polymer (PEO) alters the ligaments formation and stabilizes them due to its high elasticity. Consequently, it suppresses droplet spray during droplet spreading and recoiling (recoil penetration). In the wide range of the impact velocities, the penetrated ligaments retracted back to the mesh after reaching the maximum length and eventually merged with the droplet on the mesh. The empirical fitting shows that the ligament evolution follows the parallel spring-dashpot model of Kelvin-Voigt. The additive polymer also changes the recoil penetration mechanisms from cavity collapse to cavity detachment due to the higher retraction velocity of the cavity near the mesh that is induced by the upward flow formed by the retraction of the ligaments to the mother droplet. A model based on mass conservation is proposed to calculate the variation of the maximum ligament size.

3.
Chemosphere ; 287(Pt 3): 132245, 2022 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-34543908

RESUMO

Aluminum phosphide is a well-known hazardous agent used as an agricultural pesticide to protect stored grains from insect damage. However, accidental consumption of a trivial amount of it caused irreversible damage to the human body or even death in acute cases. The present study used taurine and grape seed extract as a natural cardioprotective medicine against aluminum phosphide poisoning by decreasing oxidative stress. The activity of oxidative stress biomarkers (Malondialdehyde, Catalase, Protein carbonyl, and Superoxide dismutase) were evaluated in the cell line model on Human Cardiac Myocyte cells. In the beginning, to clarify the pure impact of aluminum phosphide poison, taurine, and grape seed extract on the human heart cells, their effects on the biomarkers quantity in cell line were measured. Subsequently, the effect of taurine and grape seed extract with various concentrations as a treatment on the oxidative stress biomarkers of the poisoned heart cells were studied. Data analysis reveals that taurine and grape seed extract treatment can successfully diminish the poisoning effect by their antioxidant properties. The oxidative markers values of the poisoned cells were recovered by taurine and grape seed extracts treatment. Taurine (2 g/l) can recover Malondialdehyde, Catalase, Protein carbonyl, and Superoxide dismutase by 56%, 78%, 88%, 78%, when the recovering power of grape seed extract (100 g/l) for the aforementioned enzymes are 56%, 0.71%,74%, 51%, respectively. Therefore, it is clear that the performance of taurine in the recovery of the biomarkers' value is better than grape seed extract.


Assuntos
Extrato de Sementes de Uva , Praguicidas , Vitis , Compostos de Alumínio , Antioxidantes , Biomarcadores , Extrato de Sementes de Uva/farmacologia , Humanos , Estresse Oxidativo , Fosfinas , Taurina/farmacologia
4.
Chemosphere ; 294: 133800, 2022 May.
Artigo em Inglês | MEDLINE | ID: mdl-35101429

RESUMO

Numerous people suffer from accidental or deliberate exposure to different pesticides when poisoning with aluminum phosphate (AlP) is increasing in the eastern countries. Aluminum phosphate is a conventional insecticide that quickly reacts with water or the moistures in the atmosphere and produces fatal phosphine gas, which absorbs quickly by the body. Oral consumption or inhalation of AlP leads to excessive reaction of the body such as fatigue, vomiting, fever, palpitation, vasodilatory shock, increasing blood pressure, cardiac dysfunction, pulmonary congestion, shortness of breath, and death. The garlic smell from the patient's mouth or exhale is one of the methods to recognize the positioning. Due to the lack of individual antidotes, several supportive treatments are required. The present study focused on the available and new therapies that help reduce the effect of AlP poisoning and the mortality rate. The therapies are divided into the antioxidant-related agent and the other agents. The impacts of each agent on the experimental cases are reported.


Assuntos
Inseticidas , Intoxicação por Organofosfatos , Praguicidas , Fosfinas , Intoxicação , Compostos de Alumínio , Antídotos/uso terapêutico , Humanos , Praguicidas/toxicidade , Intoxicação/terapia
5.
Comput Methods Programs Biomed ; 184: 105300, 2020 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-31901632

RESUMO

BACKGROUND AND OBJECTIVE: In this study, the effect of the second excitation frequency mode under different conditions on the fluid streaming and its microparticles displacement is investigated. METHODS: For this purpose, some variable parameters such as the particle diameter, microchannel aspect ratio, and applied frequency modes have been selected to study. The resulted acoustic streaming was scrutinized to understand the physics of the problem under different geometrical and input conditions. Finally, the effect of the increasing the microparticle size and aspect ratio of the microchannel, simultaneously, has been evaluated. RESULTS: The results demonstrated that increasing the microparticle size accelerates the displacement of the microparticles. On the other hand, changing the aspect ratio affects the formation of the microparticle distribution and it also changes the velocity of the microparticles due to the gradient of the second-order pressure. CONCLUSIONS: The obtained results have wide applications in the military, medical, petrochemical, and other related studies.


Assuntos
Acústica , Separação Celular/métodos , Microfluídica/métodos , Ondas Ultrassônicas
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