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Inorganic fullerene clusters have attracted widespread attention due to their highly symmetrical geometric structures and intrinsic electronic properties. However, cage-like clusters composed of heavy metal elements with high symmetry are rarely reported, and their synthesis is also highly challenging. In this study, we present the synthesis of a [K2(Bi@Pd12@Bi20)]4- cluster that incorporates a {Bi20} cage with pseudo-Ih symmetry, making it the largest main group metal cluster compound composed of the bismuth element to date. Magnetic characterization and theoretical calculations suggest that the spin state of the overall cluster is a quartet. Quantum chemical calculations reveal that the [Bi20]3- cluster has a similar electronic configuration to C606- and the [Bi@Pd12@Bi20]6- cluster exhibits a unique open-shell aromatic character.
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A unique four-coordinate, classical gold(I)-carbonyl complex with substantial backdonation from gold has been isolated by using a B-methylated and fluorinated tris(pyridyl)borate chelator. Its lighter silver(I) and copper(I) analogs enabled a study of trends in the coinage-metal family. The B-arylated ligand version also afforded a gold-carbon monoxide complex that displays a notably low C-O stretch value, but with trigonal planar geometry at the gold. A computational analysis shows that the AuI -CO bonds of these tris(pyridyl)borate ligand-supported molecules consist of electrostatic attraction, OCâAu σ-donation, and very significant AuâCO π-back-bonding components. The latter is responsible for the observed C-O stretching frequencies, which are lower than in free CO.
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Sterically loaded, anionic pyridine has been synthesized and utilized successfully in the stabilization of a isoleptic series of coinage metal complexes. The treatment of [4-(Ph3B)-2,6-Trip2Py]K (Trip=2,4,6-iPr3C6H2) with CuBr(PPh3), AgCl(PPh3) or AuCl(PPh3) (Py=pyridine) afforded the corresponding [4-(Ph3B)-2,6-Trip2Py]M(PPh3) (M=Au, Ag, Cu) complexes, via salt metathesis, as isolable, crystalline solids. Notably, these reactions avoid the facile single electron transfer chemistry reported with the less bulky ligand systems. The X-ray structures revealed that they are two-coordinate metal adducts. The M-N and M-P bond distances are longest in the silver and shortest in the copper adduct among the three group 11 family members. Computational analysis revealed an interesting stability dependence on steric bulk of the anionic pyridine (i. e., pyridyl borate) ligand. A comparison of structures and bonding of [4-(Ph3B)-2,6-Trip2Py]Au(PPh3) to pyridine and m-terphenyl complexes, {[2,6-Trip2Py]Au(PPh3)}[SbF6] and [2,6-Trip2Ph]Au(PPh3) are also provided. The Au(I) isocyanide complex, [4-(Ph3B)-2,6-Trip2Py]Au(CNBut) has been stabilized using the same anionic pyridylborate illustrating that it can support other gold-ligand moieties as well.
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Supramolecular complexes of carbon nanohoops with fullerenes play a key role for the design of novel nanomaterials with technological applications. Herein we investigate with density functional theory (DFT) methods the capability of neutral and dioxidized cycloparaphenylenes (CPPs) to encapsulate all-boron fullerene B40. Our results show that [9]CPP and [10]CPP are feasible host candidates to encapsulate B40 displaying comparable complexation energies with the all-carbon analog [10]CPPâC60. Upon dioxidation the host-guest interactions are not affected, whereas the positive charge is delocalized on the CPPs leading to global aromatic character of the hosts. Consequently, the dicationic complexes [n]CPP2+âB40 and [10]CPP2+âC60 display augmented global shielding cones that strongly shield the guests, as manifested by large upfield shifts in 11B-NMR and 13C-NMR signals. Hence, CPP complexes with carbon fullerenes can be extended borospherene B40 host-guest complexes, as well as to doubly oxidized species stabilized by global host aromaticity, expanding our understanding of carbon nanohoop complexes to boron-based fullerenes.
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Ligand-protected gold clusters remain potential building blocks for envisaged molecular materials. The archetypal Au38(SR)24 cluster can be viewed as a robust template for the fusion of two Au25(SR)18 - cluster units, retaining a bi-icosahedral Au23 core. Via electrochemical properties, the overall charge state can be selectively tuned, enabling the access of 14 valence electron (ve) species featuring a single intercluster bond and nearby charge from -1 to +3, achieving related species bearing 15- to 11-ve with variable intercluster bond orders. Here, we explore the characteristics of intermediate intercluster bond orders in order to provide insights into the plausible electron communication between the constituent building blocks, with Au38(SR)24, as a representative template. Our results denote a small structural variation along -1 to +3 charge states, provided by the core-protecting ligand interaction, which is enhanced towards more oxidized species. The remaining unpaired electron from intermediate intercluster bond orders of 1.5 for Au38(SR)24 1-, 1.5 for Au38(SR)24 1+, and 2.5 for Au38(SR)24 3+, holds delocalized characteristics between the building block units, favoring electron communication for conductive and cooperative cluster aggregates. Such features are relevant for the formation of molecular electronic device applications, favoring the rationalization prior to engaging in explorative synthesis of larger ligand-protected cluster aggregates.
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Superatomic clusters are relevant species to further understanding of bonding and structural properties of atomically precise molecular nanoparticles. Here, we explore the characteristics of ligand-free [Ba4@Sn56]36- Zintl-ion, as a three-dimensional aggregate of clusters featuring four fused Ba@Sn19 building units as an extension of the understanding in linear and cyclic superatomic cluster arrays. We provide a rational picture of the electronic shell in [Ba4@Sn56]36- as a cluster-of-clusters motif through the recently introduced second-order superatom approach, as a three-dimensional aggregation of superatomic clusters where their shells are able to interact. The electronic structure features both tangential and radial shells from the four building Ba@Sn19 units, leading to a set of 1S'21P'61D'101F'14 and higher angular momentum shells and a second set of 2S'22P'62D'102F'142G'8 second-order shells. Thus, the current approach serves to encourage the rationalization of molecular materials conceived from cluster building blocks toward a rational guide for synthetic efforts.
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Aromaticity is one of the most important and widely used concepts in chemistry. Among the various experimentally discovered and theoretically predicted compounds that possess different types of aromaticity, conflicting aromaticity, where aromatic and antiaromatic electron delocalization is present in one molecule simultaneously, remains one of the most controversial and elusive concepts, although theoretically predicted 15 years ago. In this work, we synthesized a novel conflicting aromatic trirhodium complex that contains a σ-aromatic metal fragment surrounded by the π-antiaromatic organic ligand and characterized it by nuclear magnetic resonance spectroscopy, high-resolution mass spectrometry, and X-ray single crystal structure analysis. Experimental characterization and quantum chemical calculations confirm the unique conflicting aromaticity of the synthesized trirhodium molecule. Thus, this novel conflicting aromatic molecule expands the family of aromatic compounds. This discovery will enable researchers to develop and understand the phenomena of conflicting aromaticity in chemistry.
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Formation of cluster-based materials requires a fundamental understanding of the resulting cluster aggregation processes. The Sn94- Zintl-ion structure can be viewed as a building block featuring a spherical aromatic species, leading to a cluster gathering upon oxidative coupling and/or mediated by transition metals. Here, we evaluate the spherical aromatic properties of [Sn9-Sn9]6-, [Ag(Sn9-Sn9)]5- and [(η4-Sn9)Ag(η1-Sn9)]7-, as aggregates of two Sn9 building units held together via oxidative coupling and mediated by a Ag(I) transition metal center. Our results from magnetic criteria of aromaticity show that the inherent spherical aromatic characteristics of the parent Sn94- cluster are persistent in the overall aggregate where the enabled shielding cones ascribed to each Sn9 unit are able to interplay between them, leading to an overlap of the shielding regions. Hence, the two approaches for bringing cluster units together are able to retain the inherent spherical aromatic features for each Sn9 unit, leading to a cluster-based dimer where the parent properties remain. Thus, further cluster-based materials can be envisaged from aggregation upon oxidative coupling and/or mediated by transition metals, where the constituent building blocks retain their initial features, useful to guide the formation of more complex cluster-based aggregates.
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The aggregation of halide atoms into gold clusters offers an interesting scenario for the development of novel metal-based cavities for anion recognition and sensing applications. Thus, further understanding of the different contributing terms leading to efficient cluster-halide aggregation is relevant to guide their synthetic design. In this report, we evaluate the formation of [(Ph3PAu)4X2]2+ and [(Ph3PAu)4X]3+ species (X = Cl-, Br-, I-) in terms of different energy contributions underlying the stabilization of the cluster-halide interaction, and the expected UV-vis absorption profiles as a result of the variation in frontier orbital arrangements. Our results denote that a non-planar Au4 core shape enables enhanced halide aggregation, which is similar for Cl-, Br-, and I-, in comparison to the hypothetical planar Au4 counterparts. The electrostatic nature of the interaction involves a decreasing ion-dipole term along with the series, and for iodine species, higher-order electrostatic contributions become more relevant. Hence, the obtained results help in gaining further understanding of the different stabilizing and destabilizing contributions to suitable cluster-based cavities for the incorporation of different monoatomic anions.
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Atomically precise gold superatoms have attracted interest owing to their suitable use as building blocks for cluster-assembled materials, favoring ordered structures with advanced properties. In this sense, expanding their versatility is a relevant issue for controlling their properties and retaining a specific nuclearity. Interestingly, the reported structure for isoelectronic [Au4N(PPh3)4]+ and [Au4Sb(PPh3)4]+ clusters denotes two contrasting shapes featuring a tetrahedral and square pyramidal structure, respectively. Herein, we further explore the [Au4E(PPh3)4]+ (E = N, P, As, Sb) series in order to evaluate energetic and structural factors determining the overall shape. Our results show a favorable [Au4(PPh3)4]4+/E3- interaction energy, predicting particular patterns in their UV-vis spectrum. Thus, the use of dopant atoms is enabled to vary the core shape and, in turn, to modify the cluster properties, which serve as a structural control, in addition to ligand-based and size approaches.
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Drug resistance in infectious diseases developed by bacteria and fungi is an important issue since it is necessary to further develop novel compounds with biological activity that counteract this problem. In addition, new pharmaceutical compounds with lower secondary effects to treat cancer are needed. Coordination compounds appear to be accessible and promising alternatives aiming to overcome these problems. In this review, we summarize the recent literature on coordination compounds based on nitrobenzoic acid (NBA) as a ligand, its derivatives, and other nitro-containing ligands, which are widely employed owing to their versatility. Additionally, an analysis of crystallographic data is presented, unraveling the coordination preferences and the most effective crystallization methods to grow crystals of good quality. This underscores the significance of elucidating crystalline structures and utilizing computational calculations to deepen the comprehension of the electronic properties of coordination complexes.
Assuntos
Complexos de Coordenação , Ligantes , Complexos de Coordenação/química , Complexos de Coordenação/farmacologia , Nitrobenzoatos/química , Nitrobenzoatos/farmacologia , Humanos , Cristalografia por Raios X/métodos , Nitrocompostos/química , Nitrocompostos/farmacologiaRESUMO
Ions appear as active components in diverse materials. Here, the bonding energy between mechanically interlocked molecules (MIMs) or their acyclic/cyclic molecular derivatives and i) Cl- and Br- ions and/or ii) Na+ and K+ ions, have been investigated. The chemical environment provided by MIMs is less preferably to recognize ionic species compared to unconstrained interactions that are furnished by acyclic molecules. However, MIMs can be more adequate structures for ionic recognition than cyclic compounds if a chemical arrangement of the bond sites that relevantly support more favorable interactions with ions compared to Pauli repulsive ambient is provided. The hydrogen replacement by electron donor (-NH2 ) or acceptor (-NO2 ) groups in MIMs favors the anion/cation recognition due to decreased Pauli repulsion energy and/or more attractive non-covalent bonds. This study clarifies the chemical environment provided by MIMs to interact with ions and highlights these molecules as relevant structures to realize ionic sensing.
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The silver analogue of the prominent Au25(SR)18 nanocluster reveals the possibility of finding "gold"-like behavior despite their different nature, in addition to the common features among molecular AgNP. Herein, we explore the effect of successive additions of silver atoms reaching an intermediate Ag/Au doping ratio where the parent gold cluster exhibits properties from both elements. Our results show a more favorable situation as the Ag/Au ratio increases along the Au25-xAgx(SH)18- (x = 0-12) clusters, with structural distortions mainly centered at the ligand-protected shell. The calculated optical spectrum shows that from the Au19Ag6 species, a plasmon-like peak appears along species with a doping ratio above 25%, where all the silver atoms are located within the M12 icosahedron. In addition, the chiral properties were explored, showing mild optical activity from the calculated circular dichroism spectra due to the distorted ligand-shell avoiding a centrosymmetric structure. Thus, an intermediate doping ratio ascribed to a specific structural layer can recover inherent properties to both elements in the binary Au25-xAgx(SH)18- series, suggesting the possibility of having clusters with dual properties at a certain degree of element exchange. This can be useful for further exploration theoretically and synthetically toward different and larger-nuclearity clusters.
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Bis- and tris-pyridyl borate ligands containing pyridyl donor arms, a methylated boron cap, and a fluorine-lined coordination pocket have been prepared and utilized in coinage metal chemistry. The tris(pyridyl)borate ligand has been synthesized using a convenient boron source, [NBu4][MeBF3]. These N-based ligands permitted the isolation of group 11 metal-ethylene complexes [MeB(6-(CF3)Py)3]M(C2H4) and [Me2B(6-(CF3)Py)2]M(C2H4) (M = Cu, Ag, Au). The gold complexes display the largest coordination-induced upfield shifts of the ethylene 13C resonance relative to that of the free ethylene in their NMR spectra, while the silver complexes show the smallest shift. Solid-state structures of five of these metal-ethylene complexes as well as the related free ligands were established by X-ray crystallography. Surprisingly, all three [MeB(6-(CF3)Py)3]M(C2H4) adopt the rare κ2 coordination mode rather than the typical κ3 coordination mode of facial capping tridentate ligands. Computational analyses indicate that κ2 coordination mode is favored over the κ3-mode in these coinage metal-ethylene complexes and point to the effects CF3-substituents have on κ2/κ3-energy difference. The M-C and M-N bond distances of [MeB(6-(CF3)Py)3]M(C2H4) follow the trend expected based on covalent radii of M(I) ions. The calculated ethylene-M interaction energy of κ2-[MeB(6-(CF3)Py)3]M(C2H4) indicated that the gold(I) forms the strongest interaction with ethylene. A comparison to the related poly(pyrazolyl)borates is also presented.
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The iconic W@Au12 icosahedral bare cluster reaches the favorable closed-shell superatomic electron configuration 1S2â¯1P6â¯1D10, making it an 18-cluster electron (18-ce) superatom. Here, we pursue the evaluation of a ligand-protected counterpart based on the construction of a fully phosphine-protected [W@Au12(dppm)6] cluster strongly related to the characterized [Au13(dppm)6]5+ homometallic counterpart. The later cluster has the same total number of valence electrons as the former but is considered an 8-ce superatom with 1S2â¯1P6 configuration. The fundamental differences between 8- and 18-ce species are investigated. The character of the frontier orbitals varies from 1P/1D in the 8-ce case to a 1D/ligand for 18-ce species, enabling an efficient charge transfer toward the ligands upon irradiation, being interesting for electron injection in optoelectronic devices and black absorbers applications. Excited-state properties are also revisited, showing different geometrical and electronic structure variations between 8- and 18-ce species. Moreover, the continuum between the 8- and 18-ce limits has been explored by varying the nature of the encapsulated dopant between group 6 and group 11. The transition between the 8- and 18-ce counts can be formally situated between Pt (8-ce) and Ir (18-ce). Thus, 18-ce derivatives obtained as doped counterparts of homometallic gold clusters can introduce useful alternatives to achieve different properties in related structural motifs, which can be further explored owing to their extension of the well-established versatility of current gold nanoclusters.
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Thallium(I) complexes of B-methylated and B-phenylated tris(pyridyl)borates featuring trifluoromethyl groups at the pyridyl ring 6-positions have been synthesized by metathesis using the corresponding potassium salts [MeB(6-(CF3)Py)3]K and [PhB(6-(CF3)Py)3]K with thallium(I) acetate. The closely related tris(pyrazolyl)borate analogue [PhB(3-(CF3)Pz)3]Tl has also been prepared, and comparisons of structural and spectroscopic features between the two scorpionate families are presented. [MeB(6-(CF3)Py)3]Tl displays κ3-coordination of the tris(pyridyl)borate similar to that of tris(pyrazolyl)borate in [MeB(3-(CF3)Pz)3]Tl, while [PhB(6-(CF3)Py)3]Tl and [PhB(3-(CF3)Pz)3]Tl feature κ2-N,N ligand coordination modes with the B-phenyl groups flanking the thallium sites. 19F NMR spectroscopy of [MeB(6-(CF3)Py)3]Tl reveals the presence of a remarkably large 1208 Hz four-bond thallium-fluorine coupling constant in chloroform at room temperature, which is considerably larger than 878 Hz observed for the pyrazolyl borate analogue [MeB(3-(CF3)Pz)3]Tl. Although [PhB(6-(CF3)Py)3]Tl is structurally nonrigid at room temperature in chloroform, at lower temperatures, the ligand arm exchange slows down, revealing 4JTl-F = 1110 Hz. Steric demands of these ligands have been quantified using the buried volume concept. In addition, ligand transfer chemistry from [MeB(6-(CF3)Py)3]Tl and [PhB(6-(CF3)Py)3]Tl to copper(I) under ethylene and computational analyses of the various coordination modes of tris(pyrazolyl)borates and tris(pyridyl)borates are reported.
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Here we show that recent Möbius carbon nanobelts (MCNBs) can be switched from a local to a global aromatic behavior upon dioxidation. Hence, large aromatic structures can be achieved by the choice of the charge states, giving rise to shielding cone characteristics extended within the overall structure at the nanoscale regime, pushing the limit of aromatic circuits to 198 π-electrons.
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The unique formation of an infinity-shaped carbon backbone made exclusively from fused benzene rings has recently been achieved. The structure of [12]infinitene can be viewed as two fused [6]helicene structures with a central crossover section, depicting a global aromatic behavior along with the overall structure, with deshielding regions along both helicoidal axes. In addition, the 13C-NMR characteristics are discussed. The formation of a cumulative region involving the shielding regions from the aromatic rings is depicted along with the overall aesthetically pleasant structural backbone, which is enhanced at the crossover section. For the evaluated dianionic counterpart, the structure shows a deshielding region above the fused-ring trail and a helicoidal shielding region, ascribed to a global antiaromatic counterpart. The aromaticity is recovered and enhanced at the tetranionic state. Thus, the neutral and tetranionic states are able to build up a long-ranged shielding region, given by the global aromatic behavior, with an enhanced shielding region at the center of the crossover section displaying π-π stacked rings.
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Cycloparaphenylenes (CPPs) exhibit selective host capabilities, featuring the ability to incorporate smaller CPPs to form double-walled host-guest complexes. Moreover, CPPs can also be stabilized by global aromaticity under twofold oxidation or reduction, involving electronic conjugation along with the overall structural backbone. Herein we explore the structural modifications, bonding, electron delocalization and magnetic properties of doubly reduced double-walled CPP complexes with DFT methods, in the isolated and aggregate [n + 5]CPPâ[n]CPP2- (n = 5-8) species. Our results show that the hosts undergo structural, bonding and delocalization deformations towards quinoidal configurations and exhibit global long-ranged shielding cones similar to global aromatic free dianionic CPPs, accounting for charge delocalization on the outer nanohoops, whereas the guests preserve local aromatic benzenoid configurations, resulting in global and local aromatic circuits within the host-guest aggregate. This observation suggests that in multi-layered related species electronic delocalization will be retained at the outer structural surface. The aromaticity of the hosts is manifested in the strong upfield shifts of the guests 1H-NMR signals. Hence, CPP complexes can be extended to doubly reduced species stabilized by global host aromaticity expanding our understanding of doubled-walled nanotubes at the nanoscale regime.
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Nanoscaled 2D and 3D carbon structures with closed curved π-surfaces are of relevance in the development of desirable building units for materials science. Such species are able to sustain local and global aromatic circuits involving isolated regions or the overall structural backbone, respectively. Here we account for local and global aromaticity under rotation of representative two- and three-dimensional species involving para-connected and fused edge-sharing phenyl rings ([8]CPP, [10]CPP, CNB), and C60 fullerene at different charge states. Our results denote that nanoscaled 2D global aromatics mimic the behaviour of the most prototypical aromatic 6π-circuit, given by benzene, where the shielding cone properties vary along the rotation motion. In contrast, 3D spherical aromatics remain almost invariant under rotation, given the distinctive characteristics of such species, differing from 2D global aromatics. Dissection of orbital contributions reveals that π-orbitals are determinants for shifting from non-aromatic to spherical aromatic species. Under rotation, the variation of the anisotropic effect inherent to such nanoscaled structures is accounted for, which is relevant to rationalize variation in NMR signal shifts upon the formation of host-guest aggregates.