Exploring the potential of electrostatic precipitation as an alternative particulate matter filtration system in aircraft cabins.

On most modern airliners, cabin air pressurization, heating, and renewal are mainly achieved using air supplied from the gas turbine engines during flight. This air intake impairs the motors yield and needs to be conditioned, leading to energy overconsumption. Recent advances in thermal management enable aircraft manufacturers to reduce further the intake airflow needed to maintain cabin temperature at high altitude. Nevertheless, for lower air renewal rates, an appropriate air filtration system will be needed to maintain acceptable air quality in the cabin. In this context, Clean Sky 2 Joint Undertaking (CS2JU) project EC2S (Environment Control Secondary System) aims at developing an integrated filtration system to be implemented in existing cabin air management systems (so-called environmental control system-ECS). The EC2S unit will include three filtration units addressing separately volatile organic compounds (VOCs), CO2 , and particulate matter (PM). Circulated air in the ECS is conventionally filtered on pleated HEPA filters that generate substantial pressure drop. Since the EC2S VOCs and CO2 filtration units would generate additional pressure drop in the ECS system, electrostatic precipitation is foreseen as a low flow resistance alternative for PM removal. This paper reports the development and performance assessment of a two-stage electrostatic precipitator (ESP) designed for aircraft recirculated air filtration. The ESP prototype presents high single-pass particle collection rates (i.e., over 90% for airborne particles with an aerodynamic diameter of 0.5 µm or larger), low-pressure drop (i.e., 4 Pa at nominal flowrate), and a limited ozone generation rate (i.e., below 8 mg h-1 ).

Impact of UV irradiation on multiwall carbon nanotubes in nanocomposites: formation of entangled surface layer and mechanisms of release resistance.

Multiwall carbon nanotubes (MWCNTs) are nanofillers used in consumer and structural polymeric products to enhance a variety of properties. Under weathering, the polymer matrix will degrade and the nanofillers may be released from the products potentially impacting ecological or human health. In this study, we investigated the degradation of a 0.72 % (by mass) MWCNT/amine-cured epoxy nanocomposite irradiated with high intensity ultraviolet (UV) light at various doses, the effects of UV exposure on the surface accumulation and potential release of MWCNTs, and possible mechanisms for the release resistance of the MWCNT surface layer formed on nanocomposites by UV irradiation. Irradiated samples were characterized for chemical degradation, mass loss, surface morphological changes, and MWCNT release using a variety of analytical techniques. Under 295 nm to 400 nm UV radiation up to a dose of 4865 MJ/m2, the nanocomposite matrix underwent photodegradation, resulting in formation of a dense, entangled MWCNT network structure on the surface. However, no MWCNT release was detected, even at very high UV doses, suggesting that the MWCNT surface layer formed from UV irradiation of polymer nanocomposites resist release. Four possible release resistance mechanisms of the UV-induced MWCNT surface layer are presented and discussed.

Effects of sodium hypochlorite exposure mode on PES/PVP ultrafiltration membrane degradation.

Drinking water production plants using membrane filtration processes report membrane failure issues. According to the literature, membrane degradation is often induced by exposure to sodium hypochlorite, an oxidant widely used during in-place cleanings. The present study focused on quantifying the effect of membrane exposure mode to hypochlorite on properties modifications of a PES/PVP ultrafiltration membrane widely used for drinking water production. For this purpose effects of sodium hypochlorite concentration, contact duration and exposure mode (static or dynamic) were investigated. The pH of the hypochlorite solution was set to 8 as it was demonstrated in numerous previous works that the pH range 7-8 leads to the most severe modification in the membrane characteristics. Membrane degradation was monitored at molecular scale by attenuated total reflectance infrared spectroscopy and at macroscopic scale by pure water permeability and elongation at break measurements. The results obtained in static (soaking) and dynamic (filtration and filtration/backwashing cycles) hypochlorite exposure modes indicated that PES/PVP membrane degradation progress was predominantly governed by hypochlorite oxidation rate. In the tested conditions, mechanical stress (pressure differentials) did not significantly contribute to membrane ageing. The correlation between molecular and macroscopic characterizations demonstrated that PVP degradation is responsible for the membrane integrity loss. A linear relationship between the loss of ductility of the membrane and the progress of the PVP degradation was obtained whatever the exposure mode. Thanks to experiments conducted at various hypochlorite concentrations and exposure durations, the hypochlorite dose parameter (hypochlorite concentration times contact time), widely used in the literature, was demonstrated to be inappropriate to describe the degradation rate: the hypochlorite concentration impact was shown to be dominating the exposure time's one on the degradation rate.