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1.
J Occup Environ Hyg ; 20(2): 120-128, 2023 02.
Artigo em Inglês | MEDLINE | ID: mdl-36445186

RESUMO

Agricultural workers are more prone to noise-induced hearing loss than are many other workers. Hearing protection device use among agricultural workers is low, but training can increase hearing protection device use. This work proposes a system designed to automatically inform agricultural workers when they were exposed to noises that exceed the National Institute for Occupational Safety and Health (NIOSH) recommended exposure level. The smartphone-based system worn on the arm uses a noise dosimeter to measure noise exposures throughout the day to within ±2 A-weighted decibels of a Class 2 sound level meter. The device collects location and audio data, which are transferred to a server and presented to the worker on a locally hosted website. The website details noise exposure and helps the worker identify where exposure occurred and what specific tasks exceed NIOSH's recommended exposure limit, putting them at higher risk of noise-induced hearing loss. With this understanding, the worker is expected to adopt behavior changes and better hearing protection use at critical places and times. This pilot study evaluates the accuracy of the noise dosimeter and GPS relative to gold-standard instruments. The system was tested on a farm with outputs compared with gold-standard instruments. A-weighted, 1-sec averaged sound pressure levels and position data were collected while users were performing a variety of tasks indoors and outdoors. The smartphone's external noise dosimeter read within ±2 A-weighted decibels of the Class 2 reference dosimeter 59% of the time. The positioning devices had an average error of sub-4 m. While not perfectly matching gold-standard instruments, the device is capable of identifying and collecting information relative to loud noise events that promote noise-induced hearing loss.


Assuntos
Perda Auditiva Provocada por Ruído , Ruído Ocupacional , Exposição Ocupacional , Saúde Ocupacional , Humanos , Perda Auditiva Provocada por Ruído/etiologia , Perda Auditiva Provocada por Ruído/prevenção & controle , Ruído Ocupacional/efeitos adversos , Ruído Ocupacional/prevenção & controle , Projetos Piloto
2.
J Occup Environ Hyg ; 19(5): 295-301, 2022 05.
Artigo em Inglês | MEDLINE | ID: mdl-35286244

RESUMO

Ventilation plays an important role in mitigating the risk of airborne virus transmission in university classrooms. During the early phase of the COVID-19 pandemic, methods to assess classrooms for ventilation adequacy were needed. The aim of this paper was to compare the adequacy of classroom ventilation determined through an easily accessible, simple, quantitative measure of air changes per hour (ACH) to that determined through qualitative "expert judgment" and recommendations from the American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE), and the American Conference of Governmental Industrial Hygienists (ACGIH)®. Two experts, ventilation engineers from facilities maintenance, qualitatively ranked buildings with classrooms on campus with regard to having "acceptable classroom ventilation." Twelve lecture classrooms were selected for further testing, including a mix of perceived adequate/inadequate ventilation. Total air change per hour (ACH) was measured to quantitatively assess ventilation through the decay of carbon dioxide in the front and rear of these classrooms. The outdoor ACH was calculated by multiplying the total ACH by the outdoor air fraction. The classrooms in a building designed to the highest ASHRAE standards (62.1 2004) did not meet ACGIH COVID-19 recommendations. Four of the classrooms met the ASHRAE criteria. However, a classroom that was anticipated to fail based on expert knowledge met the ASHRAE and ACGIH criteria. Only two classrooms passed stringent ACGIH recommendations (outdoor ACH > 6). None of the classrooms that passed ACGIH criteria were originally expected to pass. There was no significant difference in ACH measured in the front and back of classrooms, suggesting that all classrooms were well mixed with no dead zones. From these results, schools should assess classroom ventilation considering a combination of classroom design criteria, expert knowledge, and ACH measurements.


Assuntos
Poluição do Ar em Ambientes Fechados , COVID-19 , Poluição do Ar em Ambientes Fechados/prevenção & controle , COVID-19/epidemiologia , Humanos , Pandemias , Instituições Acadêmicas , Universidades , Ventilação/métodos
3.
J Occup Environ Hyg ; 19(6): 343-352, 2022 06.
Artigo em Inglês | MEDLINE | ID: mdl-35286249

RESUMO

Worker exposure to occupational hazards is traditionally measured by equipping workers with wearable exposure monitors. An emerging alternative measurement first generates time-varying hazard maps from permanent monitors within the facility, then estimating worker exposure by integrating hazard levels traversed in map, following the tracked movement of workers. Complex environments may require many monitors to produce a hazard map with the necessary accuracy, but effective interpolation functions can reduce the required number of monitors needed. This work assesses the effectiveness of three models for accurately interpolating hazard levels among monitors: a traditional Kriging model, a physics-based model, and a hybrid model that combines the Kriging and physics-based models. The effectiveness of each interpolation function was tested with sound levels collected in four environmental settings. These detailed experimental data were used to generate over 10,000 simulation trials, where each trial configured the experimental data into a unique arrangement of simulated monitoring and sampling positions. For each simulation trial, the effectiveness of the three models was assessed with the root mean square error of the sound levels at the simulated sampling positions, using the simulated monitoring positions as input. The interpolated values between the monitored positions were analyzed separately from the extrapolated values beyond the monitored positions. The hybrid model consistently reported among the lowest errors in each trial. The Kriging model performed best for the densest networks (those with the most monitors). Even in these cases, the hybrid model performed within 10% of the Kriging model with less than a third of the monitors. The experiment demonstrates that the hybrid model is highly effective at estimating hazardous sound levels; future work may demonstrate similar advantages for gas and aerosol hazards.


Assuntos
Monitoramento Ambiental , Física , Humanos , Análise Espacial
4.
J Occup Environ Hyg ; 18(2): 65-71, 2021 02.
Artigo em Inglês | MEDLINE | ID: mdl-33406010

RESUMO

A quantitative fit test is performed using a benchtop instrument (e.g., TSI PortaCount) to assess the fit factor provided by a respirator when assigned to a worker. There are no wearable instruments on the market to measure protection factors while the respirator is in use. The aim of this study is to evaluate two new, wearable, quantitative instruments-a dual-channel optical particle counter (DC OPC) and a dual-channel condensation particle counter (DC CPC)-that would enable in-situ, real-time measurement of respirator workplace protection factor. Respirator laboratory protection factors measured by the new instruments were compared to those measured with the TSI PortaCount on one test subject for three test aerosols (sodium chloride, incense, ambient) at target laboratory protection factors of 100, 300, and 1,000 for sodium chloride and ambient, and 75 and 500 for incense. Three replicates were performed for each test condition. Data were analyzed with a two-sided paired t-test at a significance level of 0.05. Laboratory protection factors measured with the DC CPC agree with those measured with the PortaCount whereas those from the DC OPC generally do not. Mean laboratory protection factors derived from the DC CPC are only statistically significantly different for mean values of a laboratory protection factor at ambient conditions for a target laboratory protection factor of 300 (p = 0.02) and for incense at a target laboratory protection factor of 75 (p = 0.03). Although statistically significant, the difference in laboratory protection factors derived from the DC CPC are not substantial in practice and may be explained by systematic uncertainty. In contrast, the DC OPC reports substantially larger mean laboratory protection factors, differing by about half an order of magnitude in extreme cases, and statistically significantly different mean laboratory protection factors for the sodium chloride aerosol for target laboratory protection factors of 100 and 300 (p = 0.01 and p = 0.01).


Assuntos
Exposição Ocupacional , Dispositivos de Proteção Respiratória , Aerossóis , Laboratórios , Exposição Ocupacional/prevenção & controle , Ventiladores Mecânicos
5.
J Occup Environ Hyg ; 18(3): 139-148, 2021 03.
Artigo em Inglês | MEDLINE | ID: mdl-33507840

RESUMO

Daily activities performed by music instructors generate high sound levels that could potentially lead to overexposure. Adverse outcomes associated with high-exposure to sound, such as hearing loss and tinnitus, can be especially devastating to music instructors as hearing is essential to both job performance and career reward. The primary objective of this study was to compare sound exposures of music instructors to recommended exposure limits. Secondary objectives were to identify high-exposure activities and to evaluate potential similar exposure groups by examining between- and within-worker exposure variability. Personal sound exposure measurements from music instructors were collected using dosimeters during full workdays for up to 4 weeks over multiple semesters at a university's school of music. Study participants completed an activity log to record work-related activities throughout each day of sampling. Dosimeters logged 1-sec sound equivalent levels in A-weighted decibels. These data were used to calculate 8-hr time-weighted averages, daily dose, and activity-specific contributions to that dose to determine if daily exposures exceeded the recommended limit of 85 dBA and to identify high-exposure activities that could be targeted for future intervention. Seventeen participants were sampled for a total of 200 days. Approximately one-third of daily exposures exceeded recommended limits. The groups with the highest exposures were brass and conducting instructors. Conductors experienced the highest between-day variability in daily exposures. Activities that contributed the most to daily dose included group rehearsals, personal practice sessions, and performances, while classes and administrative work did not substantially contribute to daily dose. Daily exposures were highly variable, ranging from 60-95 dBA (mean = 81 dBA, sd = 8 dBA), and were influenced by instructional area and musical activity. Future exposure assessments for music instructors should include sampling for multiple days, and those above-recommended limits should be placed into hearing conservation programs.


Assuntos
Música , Ruído Ocupacional , Exposição Ocupacional , Zumbido , Humanos , Som
6.
Environ Res ; 189: 109888, 2020 10.
Artigo em Inglês | MEDLINE | ID: mdl-32979995

RESUMO

BACKGROUND: Cooks exposed to biomass fuel experience increased risk of respiratory disease and mortality. We sought to characterize lung function and environmental exposures of primary cooking women using two fuel-types in southeastern India, as well as to investigate the effect of particulate matter (PM) from kitchens on human airway epithelial (HAE) cells in vitro. METHODS: We assessed pre- and post-bronchodilator lung function on 25 primary female cooks using wood biomass or liquified petroleum gas (LPG), and quantified exposures from 34 kitchens (PM2.5, PM < 40 µm, black carbon, endotoxin, and PM metal and bacterial content). We then challenged HAE cells with PM, assessing its cytotoxicity to small-airway cells (A549) and its effect on: transepithelial conductance and macromolecule permeability (NuLi cells), and antimicrobial activity (using airway surface liquid, ASL, from primary HAE cells). RESULTS: Lung function was impaired in cooks using both fuel-types. 60% of participants in both fuel-types had respiratory restriction (post bronchodilator FEV1/FVC>90). The remaining 40% in the LPG group had normal spirometry (post FEV1/FVC = 80-90), while only 10% of participants in the biomass group had normal spirometry, and the remaining biomass cooks (30%) had respiratory obstruction (post FEV1/FVC<80). Significant differences were found in environmental parameters, with biomass kitchens containing greater PM2.5, black carbon, zirconium, arsenic, iron, vanadium, and endotoxin concentrations. LPG kitchens tended to have more bacteria (p = 0.14), and LPG kitchen PM had greater sulphur concentrations (p = 0.02). In vitro, PM induced cytotoxicity in HAE A549 cells in a dose-dependent manner, however the effect was minimal and there were no differences between fuel-types. PM from homes of participants with a restrictive physiology increased electrical conductance of NuLi HAE cells (p = 0.06) and decreased macromolar permeability (p ≤ 0.05), while PM from homes of those with respiratory obstruction tended to increase electrical conductance (p = 0.20) and permeability (p = 0.07). PM from homes of participants with normal spirometry did not affect conductance or permeability. PM from all homes tended to inhibit antimicrobial activity of primary HAE cell airway surface liquid (p = 0.06). CONCLUSIONS: Biomass cooks had airway obstruction, and significantly greater concentrations of kitchen environmental contaminants than LPG kitchens. PM from homes of participants with respiratory restriction and obstruction altered airway cell barrier function, elucidating mechanisms potentially responsible for respiratory phenotypes observed in biomass cooks.


Assuntos
Poluição do Ar em Ambientes Fechados , Petróleo , Poluição do Ar em Ambientes Fechados/efeitos adversos , Poluição do Ar em Ambientes Fechados/análise , Biomassa , Culinária , Feminino , Humanos , Índia , Pulmão/química , Material Particulado/análise , Material Particulado/toxicidade
7.
J Aerosol Sci ; 134: 72-79, 2019 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-37752991

RESUMO

A high-flow (10 L/min) nanoparticle respiratory deposition (NRD) sampler was designed and evaluated to achieve reduced limits of quantification (LOQs) for metal nanoparticles. The high-flow NRD consists of an inlet, impactor stage, diffusion stage, and a final filter. An impactor stage with 12 nozzles was designed from theory to achieve a cut-off diameter of 300 nm at 50% particle collection efficiency (d50). Various depths of 37-mm-diameter polyurethane foam cylinders were tested for the diffusion stage to obtain a collection efficiency curve similar to the deposition of nanoparticles in the human respiratory tract, known as the nanoparticulate matter (NPM) criterion. The objective for the final filter was a collection efficiency of near 100% with minimal pressure drop. The collection efficiencies by size and pressure drops were measured for all NRD sampler components. The final design of the impactor stage nozzle achieved a d50 of 305 nm. The collection efficiency for the diffusion stage with a depth of 7 cm when adjusted for presence of the impactor was the closest to the NPM curve with a R2 value of 0.96 and d50 of 43 nm. Chemical analysis of the metal content for foam affirmed that the high-flow NRD sampler required less sampling time to meet metal LOQs than the 2.5 L/min NRD sampler. The final filter with a modified support pad had a collection efficiency near 100%. The overall pressure drop of the sampler of 8.5 kPa (34 in. H2O) could not be handled by commercial personal sampling pumps. Hence the high-flow NRD sampler can be used as an area sampler or without the final filter for collection of nanoparticles.

8.
J Occup Environ Hyg ; 16(8): 564-574, 2019 08.
Artigo em Inglês | MEDLINE | ID: mdl-31251121

RESUMO

The quality of mass concentration estimates from increasingly popular networks of low-cost particulate matter sensors depends on accurate conversion of sensor output (e.g., voltage) into gravimetric-equivalent mass concentration, typically using a calibration procedure. This study evaluates two important sources of variability that lead to error in estimating gravimetric-equivalent mass concentration: the temporal changes in sensor calibration and the spatial and temporal variability in gravimetric correction factors. A 40-node sensor network was deployed in a heavy vehicle manufacturing facility for 8 months. At a central location in the facility, particulate matter was continuously measured with three sensors of the network and a traditional, higher-cost photometer, determining the calibration slope and intercept needed to translate sensor output to photometric-equivalent mass concentration. Throughout the facility, during three intensive sampling campaigns, respirable mass concentrations were measured with gravimetric samplers and photometers to determine correction factors needed to adjust photometric-equivalent to gravimetric-equivalent mass concentration. Both field-determined sensor calibration slopes and intercepts were statistically different than those estimated in the laboratory (α = 0.05), emphasizing the importance of aerosol properties when converting voltage to photometric-equivalent mass concentration and the need for field calibration to determine slope. Evidence suggested the sensors' weekly field calibration slope decreased and intercept increased, indicating the sensors were deteriorating over time. The mean correction factor in the cutting and shot blasting area (2.9) was substantially and statistically lower than that in the machining and welding area (4.6; p = 0.01). Therefore, different correction factors should be determined near different occupational processes to accurately estimate particle mass concentrations.


Assuntos
Poluentes Atmosféricos/análise , Monitoramento Ambiental/instrumentação , Exposição Ocupacional/análise , Material Particulado/análise , Calibragem , Monitoramento Ambiental/métodos , Instalações Industriais e de Manufatura , Veículos Automotores
9.
J Occup Environ Hyg ; 16(6): 387-399, 2019 06.
Artigo em Inglês | MEDLINE | ID: mdl-30570411

RESUMO

There is great concern regarding the adverse health implications of engineered nanoparticles. However, there are many circumstances where the production of incidental nanoparticles, i.e., nanoparticles unintentionally generated as a side product of some anthropogenic process, is of even greater concern. In this study, metal-based incidental nanoparticles were measured in two occupational settings: a machining center and a foundry. On-site characterization of substrate-deposited incidental nanoparticles using a field-portable X-ray fluorescence provided some insights into the chemical characteristics of these metal-containing particles. The same substrates were then used to carry out further off-site analysis including single-particle analysis using scanning electron microscopy and energy-dispersive X-ray spectroscopy. Between the two sites, there were similarities in the size and composition of the incidental nanoparticles as well as in the agglomeration and coagulation behavior of nanoparticles. In particular, incidental nanoparticles were identified in two forms: submicrometer fractal-like agglomerates from activities such as welding and supermicrometer particles with incidental nanoparticles coagulated to their surface, herein referenced as nanoparticle collectors. These agglomerates will affect deposition and transport inside the respiratory system of the respirable incidental nanoparticles and the corresponding health implications. The studies of incidental nanoparticles generated in occupational settings lay the groundwork on which occupational health and safety protocols should be built.


Assuntos
Poluentes Ocupacionais do Ar/análise , Nanopartículas Metálicas/análise , Metalurgia , Monitoramento Ambiental/métodos , Nanopartículas Metálicas/química , Nanopartículas Metálicas/ultraestrutura , Metais/análise , Microscopia Eletrônica de Varredura , Exposição Ocupacional/análise , Tamanho da Partícula , Material Particulado/análise , Espectrometria por Raios X , Soldagem
10.
Sensors (Basel) ; 18(5)2018 May 03.
Artigo em Inglês | MEDLINE | ID: mdl-29751534

RESUMO

An integrated network of environmental monitors was developed to continuously measure several airborne hazards in a manufacturing facility. The monitors integrated low-cost sensors to measure particulate matter, carbon monoxide, ozone and nitrogen dioxide, noise, temperature and humidity. The monitors were developed and tested in situ for three months in several overlapping deployments, before a full cohort of 40 was deployed in a heavy vehicle manufacturing facility for a year of data collection. The monitors collect data from each sensor and report them to a central database every 5 min. The work includes an experimental validation of the particle, gas and noise monitors. The R² for the particle sensor ranges between 0.98 and 0.99 for particle mass densities up to 300 μg/m³. The R² for the carbon monoxide sensor is 0.99 for concentrations up to 15 ppm. The R² for the oxidizing gas sensor is 0.98 over the sensitive range from 20 to 180 ppb. The noise monitor is precise within 1% between 65 and 95 dBA. This work demonstrates the capability of distributed monitoring as a means to examine exposure variability in both space and time, building an important preliminary step towards a new approach for workplace hazard monitoring.


Assuntos
Poluentes Atmosféricos/análise , Monitoramento Ambiental/métodos , Local de Trabalho , Monóxido de Carbono/análise , Monitoramento Ambiental/economia , Monitoramento Ambiental/instrumentação , Humanos , Umidade , Instalações Industriais e de Manufatura , Dióxido de Nitrogênio/análise , Ruído Ocupacional , Ozônio/análise , Material Particulado/análise , Temperatura
11.
J Occup Environ Hyg ; 15(12): 810-817, 2018 12.
Artigo em Inglês | MEDLINE | ID: mdl-30193088

RESUMO

Continuous and intermittent exposure to noise elevates stress, increases blood pressure, and disrupts sleep among patients in hospital intensive care units. The purpose of this study was to determine the effectiveness of a behavior-based intervention to reduce noise and to identify determinants of noise in a medical intensive care unit. Staff were trained for 6 weeks to reduce noise during their activities in an effort to keep noise levels below 55 dBA during the day and below 50 dBA at night. One-min noise levels were logged continuously in patient rooms 8 weeks before and after the intervention. Noise levels were compared by room position, occupancy status, and time of day. Noise levels from flagged days (>60 dBA for >10 hr) were correlated with activity logs. The intervention was ineffective, with noise frequently exceeding project goals during the day and night. Noise levels were higher in rooms with the oldest heating, ventilation, and air-conditioning system, even when patient rooms were unoccupied. Of the flagged days, the odds of noise over 60 dBA occurring was 5.3 dBA higher when high-flow respiratory support devices were in use compared to times with low-flow devices in use (OR = 5.3, 95% CI = 5.0-5.5). General sources, like the heating, ventilation, and air-conditioning system, contribute to high baseline noise and high-volume (>10 L/min) respiratory-support devices generate additional high noise (>60 dBA) in Intensive Care Unit patient rooms. This work suggests that engineering controls (e.g., ventilation changes or equipment shielding) may be more effective in reducing noise in hospital intensive care units than behavior modification alone.


Assuntos
Unidades de Terapia Intensiva/normas , Ruído/prevenção & controle , Ventiladores Mecânicos/normas , Ar Condicionado/instrumentação , Monitoramento Ambiental , Calefação/instrumentação , Humanos , Iowa , Quartos de Pacientes/normas , Recursos Humanos em Hospital/educação , Ventilação/instrumentação
12.
J Occup Environ Hyg ; 15(2): 87-98, 2018 02.
Artigo em Inglês | MEDLINE | ID: mdl-29083958

RESUMO

Development of an air quality monitoring network with high spatio-temporal resolution requires installation of a large number of air pollutant monitors. However, state-of-the-art monitors are costly and may not be compatible with wireless data logging systems. In this study, low-cost electro-chemical sensors manufactured by Alphasense Ltd. for detection of CO and oxidative gases (predominantly O3 and NO2) were evaluated. The voltages from three oxidative gas sensors and three CO sensors were recorded every 2.5 sec when exposed to controlled gas concentrations in a 0.125-m3 acrylic glass chamber. Electro-chemical sensors for detection of oxidative gases demonstrated sensitivity to both NO2 and O3 with similar voltages recorded when exposed to equivalent environmental concentrations of NO2 or O3 gases, when evaluated separately. There was a strong linear relationship between the recorded voltages and target concentrations of oxidative gases (R2 > 0.98) over a wide range of concentrations. Although a strong linear relationship was also observed for CO concentrations below 12 ppm, a saturation effect was observed wherein the voltage only changes minimally for higher CO concentrations (12-50 ppm). The nonlinear behavior of the CO sensors implied their unsuitability for environments where high CO concentrations are expected. Using a manufacturer-supplied shroud, sensors were tested at 2 different flow rates (0.25 and 0.5 Lpm) to mimic field calibration of the sensors with zero air and a span gas concentration (2 ppm NO2 or 15 ppm CO). As with all electrochemical sensors, the tested devices were subject to drift with a bias up to 20% after 9 months of continuous operation. Alphasense CO sensors were found to be a proper choice for occupational and environmental CO monitoring with maximum concentration of 12 ppm, especially due to the field-ready calibration capability. Alphasense oxidative gas sensors are usable only if it is valuable to know the sum of the NO2 and O3 concentrations.


Assuntos
Monóxido de Carbono/análise , Técnicas Eletroquímicas/instrumentação , Dióxido de Nitrogênio/análise , Ozônio/análise , Poluentes Atmosféricos/análise , Técnicas Eletroquímicas/economia , Monitoramento Ambiental/economia , Monitoramento Ambiental/instrumentação
13.
J Aerosol Sci ; 107: 123-133, 2017 05.
Artigo em Inglês | MEDLINE | ID: mdl-28871212

RESUMO

Recently, inexpensive (<$300) consumer aerosol monitors (CAMs) targeted for use in homes have become available. We evaluated the accuracy, bias, and precision of three CAMs (Foobot from Airoxlab, Speck from Carnegie Mellon University, and AirBeam from HabitatMap) for measuring mass concentrations in occupational settings. In a laboratory study, PM2.5 measured with the CAMs and a medium-cost aerosol photometer (personal DataRAM 1500, Thermo Scientific) were compared to that from reference instruments for three aerosols (salt, welding fume, and Arizona road dust, ARD) at concentrations up to 8500 µg/m3. Three of each type of CAM were included to estimate precision. Compared to reference instruments, mass concentrations measured with the Foobot (r-value = 0.99) and medium-cost photometer (r-value = 0.99) show strong correlation, whereas those from the Speck (r-value range 0.88 - 0.99) and AirBeam (0.7 - 0.96) were less correlated. The Foobot bias was (-12%) for ARD and measurements were similar to the medium-cost instrument. Foobot bias was (< -46%) for salt and welding fume aerosols. Speck bias was at 18% salt for ARD and -86% for welding fume. AirBeam bias was (-36%) for salt and (-83%) for welding fume. All three photometers had a bias (< -82%) for welding fume. Precision was excellent for the Foobot (coefficient of variation range: 5% to 8%) and AirBeam (2% to 9%), but poorer for the Speck (8% to 25%). These findings suggest that the Foobot, with a linear response to different aerosol types and good precision, can provide reasonable estimates of PM2.5 in the workplace after site-specific calibration to account for particle size and composition.

14.
J Occup Environ Hyg ; 14(5): 368-376, 2017 05.
Artigo em Inglês | MEDLINE | ID: mdl-27875101

RESUMO

The nanoparticle respiratory deposition (NRD) sampler is a personal sampler that combines a cyclone, impactor, and a nylon mesh diffusion stage to measure a worker's exposure to nanoparticles. The concentration of titanium in the nylon mesh of the diffusion stage complicates the application of the NRD sampler for assessing exposures to titanium dioxide nanoparticles. This study evaluated commercially available nonwoven textiles for use as an alternative media in the diffusion stage of the NRD sampler. Three textiles were selected as containing little titanium from an initial screening of 11 textiles by field portable x-ray fluorescence (FPXRF). Further evaluation on these three textiles was conducted to determine the concentration of titanium and other metals by inductively coupled plasma-optical emission spectroscopy (ICP-OES), the number of layers required to achieve desired collection characteristics for use as the diffusion stage in the NRD sampler (i.e., the nanoparticulate matter, NPM, criterion), and the pressure drop associated with that number of layers. Only three (two composed of cotton fibers, C1 and C2; and one of viscose bamboo and cotton fibers, BC) of 11 textiles screened had titanium concentrations below the limit of detection the XRF device (0.15 µg/cm2). Multiple metals, including small amounts of titanium, were found in each of the three nonwoven textiles using ICP-OES. The number of 25-mm-diameter layers required to achieve the collection efficiency by size required for the NRD sampler was three for C1 (R2 = 0.95 with reference to the NPM criterion), two for C2 (R2 = 0.79), and three for BC (R2 = 0.87). All measured pressure drops were less than theoretical and even the greatest pressure drop of 65.4 Pa indicated that a typical personal sampling pump could accommodate any of the three nonwoven textiles in the NRD sampler. The titanium concentration, collection efficiency, and measured pressure drops show there is a potential for nonwoven textiles to be used as the diffusion stage of the NRD sampler.


Assuntos
Monitoramento Ambiental/instrumentação , Exposição por Inalação/análise , Nanopartículas/análise , Têxteis , Poluentes Ocupacionais do Ar/análise , Celulose , Fibra de Algodão , Monitoramento Ambiental/métodos , Teste de Materiais , Exposição Ocupacional/análise , Sasa , Titânio/análise , Titânio/química
15.
Environ Sci Technol ; 50(14): 7581-9, 2016 07 19.
Artigo em Inglês | MEDLINE | ID: mdl-27300163

RESUMO

We report on the precision and accuracy of measuring PM10-2.5 and its components with particles collected by passive aerosol samplers and analyzed by computer-controlled scanning electron microscopy with energy dispersive X-ray spectroscopy. Passive samplers were deployed for week-long intervals in triplicate and colocated with a federal reference method sampler at three sites and for 5 weeks in summer 2009 and 5 weeks in winter 2010 in Cleveland, OH. The limit of detection of the passive method for PM10-2.5 determined from blank analysis was 2.8 µg m(-3). Overall precision expressed as root-mean-square coefficient of variation (CVRMS) improved with increasing concentrations (37% for all samples, n = 30; 19% for PM10-2.5 > 10 µg m(-3), n = 9; and 10% for PM10-2.5 > 15 µg m(-3), n = 4). The linear regression of PM10-2.5 measured passively on that measured with the reference sampler exhibited an intercept not statistically different than zero (p = 0.46) and a slope not statistically different from unity (p = 0.92). Triplicates with high CVs (CV > 40%, n = 5) were attributed to low particle counts (and mass concentrations), spurious counts attributed to salt particles, and Al-rich particles. This work provides important quantitative observations that can help guide future development and use of passive samplers for measuring atmospheric particulate matter.


Assuntos
Microscopia Eletrônica de Varredura , Tamanho da Partícula , Aerossóis , Poluentes Atmosféricos , Monitoramento Ambiental , Material Particulado
16.
Environ Sci Technol ; 50(10): 4961-70, 2016 05 17.
Artigo em Inglês | MEDLINE | ID: mdl-27077697

RESUMO

High mass concentrations of atmospheric lead particles are frequently observed in the Delhi, India metropolitan area, although the sources of lead particles are poorly understood. In this study, particles sampled across Delhi (August - December 2008) were analyzed by computer-controlled scanning electron microscopy with energy dispersive X-ray spectroscopy (CCSEM-EDX) to improve our understanding of the spatial and physicochemical variability of lead-rich particles (>90% lead). The mean mass concentration of lead-rich particles smaller than 10 µm (PM10) was 0.7 µg/m(3) (1.5 µg/m(3) std. dev.) with high variability (range: 0-6.2 µg/m(3)). Four samples (16% of 25 samples) with PM10 lead-rich particle concentrations >1.4 µg/m(3) were defined as lead events and studied further. The temporal characteristics, heterogeneous spatial distribution, and wind patterns of events, excluded regional monsoon conditions or common anthropogenic sources from being the major causes of the lead events. Individual particle composition, size, and morphology analysis indicate informal recycling operations of used lead-acid batteries as the likely source of the lead events. This source is not typically included in emission inventories, and the observed isolated hotspots with high lead concentrations could represent an elevated exposure risk in certain neighborhoods of Delhi.


Assuntos
Chumbo , Material Particulado , Poluentes Atmosféricos , Monitoramento Ambiental , Índia , Tamanho da Partícula
17.
Ann Occup Hyg ; 60(3): 387-401, 2016 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-26602453

RESUMO

The welding of shear stud connectors to structural steel in construction requires a prolonged stooped posture that exposes ironworkers to biomechanical and welding fume hazards. In this study, biomechanical and welding fume exposures during stud welding using conventional methods were compared to exposures associated with use of a prototype system that allowed participants to weld from an upright position. The effect of base material (i.e. bare structural beam versus galvanized decking) on welding fume concentration (particle number and mass), particle size distribution, and particle composition was also explored. Thirty participants completed a series of stud welding simulations in a local apprenticeship training facility. Use of the upright system was associated with substantial reductions in trunk inclination and the activity levels of several muscle groups. Inhalable mass concentrations of welding fume (averaged over ~18 min) when using conventional methods were high (18.2 mg m(-3) for bare beam; 65.7 mg m(-3) for through deck), with estimated mass concentrations of iron (7.8 mg m(-3) for bare beam; 15.8 mg m(-3) for through deck), zinc (0.2 mg m(-3) for bare beam; 15.8 mg m(-3) for through deck), and manganese (0.9 mg m(-3) for bare beam; 1.5 mg m(-3) for through deck) often exceeding the American Conference of Governmental Industrial Hygienists Threshold Limit Values (TLVs). Number and mass concentrations were substantially reduced when using the upright system, although the total inhalable mass concentration remained above the TLV when welding through decking. The average diameters of the welding fume particles for both bare beam (31±17 nm) through deck conditions (34±34 nm) and the chemical composition of the particles indicated the presence of metallic nanoparticles. Stud welding exposes ironworkers to potentially high levels of biomechanical loading (primarily to the low back) and welding fume. The upright system used in this study improved exposure levels during stud welding simulations, but further development is needed before field deployment is possible.


Assuntos
Poluentes Ocupacionais do Ar , Ergonomia , Exposição por Inalação/análise , Exposição Ocupacional/prevenção & controle , Soldagem/métodos , Adulto , Fenômenos Biomecânicos , Gases/análise , Humanos , Pessoa de Meia-Idade , Tamanho da Partícula
18.
Ann Occup Hyg ; 60(5): 597-607, 2016 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-26944922

RESUMO

Exposure to dust is a known occupational hazard in the swine industry, although efforts to measure exposures are labor intensive and costly. In this study, we evaluated a Dylos DC1100 as a low-cost (~$200) alternative to assess respirable dust concentrations in a swine building in winter. Dust concentrations were measured with collocated monitors (Dylos DC1100; an aerosol photometer, the pDR-1200; and a respirable sampler analyzed gravimetrically) placed in two locations within a swine farrowing building in winter for 18-24-h periods. The particle number concentrations measured with the DC1100 were converted to mass concentration using two methods: Physical Property Method and Regression Method. Raw number concentrations from the DC1100 were highly correlated to mass concentrations measured with the pDR-1200 with a coefficient of determination (R (2)) of 0.85, indicating that the two monitors respond similarly to respirable dust in this environment. Both methods of converting DC1100 number concentrations to mass concentrations yielded strong linear relationships relative to that measured with the pDR-1200 (Physical Property Method: slope = 1.03, R (2) = 0.72; Regression Method: slope = 0.72, R (2) = 0.73) and relative to that measured gravimetrically (Physical Property Method: slope = 1.08, R (2) = 0.64; Regression Method: slope = 0.75, R (2) = 0.62). The DC1100 can be used as a reasonable indicator of respirable mass concentrations within a CAFO and may have broader applicability to other agricultural and industrial settings.


Assuntos
Agricultura , Poluentes Ocupacionais do Ar/análise , Poluição do Ar em Ambientes Fechados/análise , Poeira/análise , Monitoramento Ambiental/instrumentação , Aerossóis/análise , Animais , Monitoramento Ambiental/métodos , Exposição Ocupacional/análise , Fotometria/instrumentação , Estações do Ano , Suínos
19.
J Occup Environ Hyg ; 13(1): 30-9, 2016.
Artigo em Inglês | MEDLINE | ID: mdl-26181824

RESUMO

Titanium dioxide (TiO(2)) particles, including nanoparticles with diameters smaller than 100 nm, are used extensively in consumer products. In a 2011 current intelligence bulletin, the National Institute of Occupational Safety and Health (NIOSH) recommended methods to assess worker exposures to fine and ultrafine TiO(2) particles and associated occupational exposure limits for these particles. However, there are several challenges and problems encountered with these recommended exposure assessment methods involving the accurate quantitation of titanium dioxide collected on air filters using acid digestion followed by inductively coupled plasma optical emission spectroscopy (ICP-OES). Specifically, recommended digestion methods include the use of chemicals, such as perchloric acid, which are typically unavailable in most accredited industrial hygiene laboratories due to highly corrosive and oxidizing properties. Other alternative methods that are used typically involve the use of nitric acid or combination of nitric acid and sulfuric acid, which yield very poor recoveries for titanium dioxide. Therefore, given the current state of the science, it is clear that a new method is needed for exposure assessment. In this current study, a microwave-assisted acid digestion method has been specifically designed to improve the recovery of titanium in TiO(2) nanoparticles for quantitative analysis using ICP-OES. The optimum digestion conditions were determined by changing several variables including the acids used, digestion time, and temperature. Consequently, the optimized digestion temperature of 210°C with concentrated sulfuric and nitric acid (2:1 v/v) resulted in a recovery of >90% for TiO(2). The method is expected to provide for a more accurate quantification of airborne TiO(2) particles in the workplace environment.


Assuntos
Filtros de Ar , Poluentes Ocupacionais do Ar/análise , Nanopartículas Metálicas/análise , Micro-Ondas , Titânio/análise , Monitoramento Ambiental/métodos , Ácido Nítrico/química , Exposição Ocupacional/análise , Saúde Ocupacional , Espectrofotometria Atômica/métodos , Ácidos Sulfúricos/química
20.
J Occup Environ Hyg ; 12(9): D201-10, 2015.
Artigo em Inglês | MEDLINE | ID: mdl-25955507

RESUMO

General ventilation with recirculated air may be cost-effective to control the concentration of low-toxicity, contaminants in workplaces with diffuse, dusty operations, such as in agriculture. Such systems are, however, rarely adopted with little evidence showing improved air quality and ability to operate under harsh conditions. The goal of this work was to examine the initial and long-term performance of a fabric-filter shaker dust collector (SDC) in laboratory tests and as deployed within a recirculating ventilation system in an agricultural building. In laboratory tests, collection efficiency and pressure drop were tracked over several filter loading cycles, and the recovery of filter capacity (pressure drop) from filter shaking was examined. Collection efficiencies of particles larger than 5 µm was high (>95%) even when the filter was pristine, showing effective collection of large particles that dominate inhalable concentrations typical of agricultural dusts. For respirable-sized particles, collection efficiencies were low when the filter was pristine (e.g., 27% for 1 µm) but much higher when a dust cake developed on the filter (>99% for all size particles), even after shaking (e.g., 90% for 1 µm). The first shake of a filter was observed to recovery a substantial fraction of filter capacity, with subsequent shakes providing little benefit. In field tests, the SDC performed effectively over a period of three months in winter when incorporated in a recirculating ventilation system of a swine farrowing room. Trends in collection efficiency and pressure drop with loading were similar to those observed in the laboratory with overall collection efficiencies high (>80%) when pressure drop exceeded 230 Pa, or 23% of the maximum loading recommended by the manufacturer. This work shows that the SDC can function effectively over the harsh winter in swine rearing operations. Together with findings of improved air quality in the farrowing room reported in a companion manuscript, this article provides evidence that an SDC represents a cost-effective solution to improve air quality in agricultural settings.


Assuntos
Poluentes Ocupacionais do Ar/análise , Poluição do Ar em Ambientes Fechados/prevenção & controle , Exposição Ocupacional/prevenção & controle , Ventilação/instrumentação , Agricultura , Poluição do Ar em Ambientes Fechados/análise , Criação de Animais Domésticos , Animais , Poeira/análise , Poeira/prevenção & controle , Filtração , Iowa , Tamanho da Partícula , Estações do Ano , Suínos
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