The Potential Valorization of Corn Stalks by Alkaline Sequential Fractionation to Obtain Papermaking Fibers, Hemicelluloses, and Lignin-A Comprehensive Mass Balance Approach.

The current study deals with an examination of strategies for the sequential treatment of corn stalks (CSs) in an integrated manner aiming to obtain papermaking fibers and to recover both lignin and hemicelluloses (HCs). Several pathways of valorization were experimentally trialed, focusing on getting information from mass balance analysis in an attempt to reveal the potential outcomes in terms of pulp yield, chemical composition, and papermaking properties such as tensile and burst strength. The raw lignin amounts and purity as well as separated hemicelluloses were also characterized. In this work, pulp yields in the range of 44-50% were obtained from CSs, while lignin and hemicelluloses yielded maximum values of 10 g/100 g of CS and 6.2 g/100 g of CS, respectively. Other findings of mass balance analysis evidenced that besides the papermaking pulp, the lignin and HCs also have interesting output values. The recovered lignin yield values were shown to be less than 50% in general, meaning that even if 67 to 90% of it is removed from CSs, only about half is recovered. The removal rates of hemicelluloses were found to be in the range of approx. 30 to 60%. About 15 to 25% of the original HCs could be recovered, and polysaccharides-based products with 67 to 75% xylan content could be obtained. Some key opinions were developed regarding how the mass balance could turn as a result of the chosen CS valorization set-up. The determined antioxidant activity showed that both lignin and hemicelluloses had interesting values for IC50.

Integrated Hemicellulose Extraction and Papermaking Fiber Production from Agro-Waste Biomass.

The present study deals with the valorization of corn stalks in an integrated processing strategy targeting two products: extracted hemicelluloses (HC) and papermaking fibers. Preliminary trials were conducted to assess the individual or the combined effects of biomass treatment on the quality of the obtained hemicelluloses and papermaking fibers. Depending on the hot alkaline extraction (HAE) conditions, the extracted HC had a xylan content between 44-63%. The xylan removal yield ranged between 19-35%. The recovery of HC from the extraction liquor and final black liquor was significantly affected by process conditions. The experimental approach continued with the study of HAE conditions on the obtained paper's mechanical properties. The optimization approach considered conserving paper strength properties while achieving an equilibrium with the highest possible HC extraction yield. The optimal values are sodium hydroxide concentration (1%), process time (33 min), and temperature (100 °C). The xylan content in the separated HC sample was ~55%. An extended extraction of HC from the resulting pulp under hot alkaline conditions with 5% NaOH was performed to prove the HC influence on paper strength. The xylan content in HC samples was 65%. The consequence of xylan content reduction in pulp leads to 30-50% mechanical strength loss.

Optimization of Alkaline Extraction of Xylan-Based Hemicelluloses from Wheat Straws: Effects of Microwave, Ultrasound, and Freeze-Thaw Cycles.

The alkaline extraction of hemicelluloses from a mixture of three varieties of wheat straw (containing 40.1% cellulose, 20.23% xylan, and 26.2% hemicellulose) was analyzed considering the following complementary pre-treatments: freeze-thaw cycles, microwaves, and ultrasounds. The two cycles freeze-thaw approach was selected based on simplicity and energy savings for further analysis and optimization. Experiments planned with Design Expert were performed. The regression model determined through the response surface methodology based on the severity factor (defined as a function of time and temperature) and alkali concentration as variables was then used to optimize the process in a multi-objective case considering the possibility of further use for pulping. To show the properties and chemical structure of the separated hemicelluloses, several analytical methods were used: high-performance chromatography (HPLC), Fourier-transformed infrared spectroscopy (FTIR), proton nuclear magnetic resonance spectroscopy (1H-NMR), thermogravimetry and derivative thermogravimetry analysis (TG, DTG), and scanning electron microscopy (SEM). The verified experimental optimization result indicated the possibility of obtaining hemicelluloses material containing 3.40% glucan, 85.51% xylan, and 7.89% arabinan. The association of hot alkaline extraction with two freeze-thaw cycles allows the partial preservation of the hemicellulose polymeric structure.

An Experimental Study on the Hot Alkali Extraction of Xylan-Based Hemicelluloses from Wheat Straw and Corn Stalks and Optimization Methods.

In this paper, we describe an experimental study on the hot alkali extraction of hemicelluloses from wheat straw and corn stalks, two of the most common lignocellulosic biomass constituents in Romania. The chemical compositions of the raw materials were determined analytically, and the relevant chemical components were cellulose, hemicelluloses, lignin, and ash. Using the response surface methodology, the optimum values of the hot alkaline extraction parameters, i.e., time, temperature, and NaOH concentration, were identified and experimentally validated. The physicochemical characterization of the isolated hemicelluloses was performed using HPLC, FTIR, TG, DTG, and 1H-NMR spectroscopy. The main hemicellulose components identified experimentally were xylan, arabinan, and glucan. The study emphasizes that both corn stalks and wheat straw are suitable as raw materials for hemicellulose extraction, highlighting the advantages of alkaline pretreatments and showing that optimization methods can further improve the process efficiency.

Polysaccharides Used in Biosorbents Preparation for Organic Dyes Retaining from Aqueous Media.

Natural polymers can themselves be efficient as materials with biosorptive properties but can also be used to transform microbial biomass into an easy-to-handle form, respectively, into biosorbents, through immobilization. The article aims to study biosorbents based on residual microbial biomass (Saccharomyces pastorianus yeast, separated after the brewing process by centrifugation and dried at 80 °C) immobilized in sodium alginate. The biosorptive properties of this type of biosorbent (spherical particles 2 and 4 mm in diameter) were studied for removal of reactive dye Brilliant Red HE-3B (with concentration in range of 16.88-174.08 mg/L) from aqueous media. The paper aims at three aspects: (i) the physico-chemical characterization of the biosorbent (Scanning Electron Microscopy (SEM), Energy-dispersive X-ray spectroscopy (EDX) and Fourier Transform Infrared (FTIR) spectra); (ii) the modeling of biosorption data in order to calculate the quantitative characteristic parameters using three equilibrium isotherms (Langmuir, Freundlich, and Dubinin-Radushkevich-DR); and (iii) the evaluation of thermal effect and the possible mechanism of action. The results of the study showed that biosorption capacity evaluated by Langmuir (I) model is 222.22 mg/g (ϕ = 2 mm) and 151.51 mg/g (ϕ = 4 mm) at 30 °C, and the free energy of biosorption (E) is in the range of 8.45-13.608 KJ/mol (from the DR equation). The values of thermodynamic parameters suggested an exothermic process due the negative value of free Gibbs energy (ΔG0 = -9.031 kJ/mol till -3.776 kJ/mol) and enthalpy (about ΔH0 = -87.795 KJ/mol). The obtained results underline our finding that the immobilization in sodium alginate of the residual microbial biomass of Saccharomyces pastorianus led to an efficient biosorbent useful in static operating system in the case of effluents with moderate concentrations of organic dyes.

Differential evolution-based optimization of corn stalks black liquor decolorization using active carbon and TiO2/UV.

In this work, the active carbon adsorption and TiO2/UV decolorization of black liquor were studied through experimental analysis (planned using Design of Experiments), modelling and optimization (with Response Surface Method and Differential Evolution). The aim is to highlight the importance of optimization methods for increasing process efficiency. For active carbon adsorption, the considered process parameters were: quantity of active carbon, dilution, and contact time. For TiO2 promoted photochemical decolorization the process parameters were: TiO2 concentration, UV path length and irradiation time. The determined models had an R squared of 93.82% for active carbon adsorption and of 92.82% for TiO2/UV decolorization. The optimization of active carbon resulted in an improvement from 83.08% (corresponding to 50 g/L quantity of active carbon, 30 min contact time and 200 dilution) to 100% (corresponding to multiple combinations). The optimization of TiO2/UV decolorization indicated an increase of efficiency from 36.63% (corresponding to 1 g/L TiO2 concentration, 60 min irradiation time and 5 cm UV path length) to 46.83% (corresponding to 0.4 g/L TiO2 concentration, 59.99 min irradiation time and 2.85 cm UV path length). These results show that the experiments and the subsequent standard RSM optimization can be further improved, leading to better performance.