1.
Inorg Chem
; 57(23): 14467-14470, 2018 Dec 03.
Artigo
em Inglês
| MEDLINE
| ID: mdl-30411887
RESUMO
A new bifunctional acid-base catalyst, core-shell UiO-66@SNW-1, with robust chemical and thermal stability, recyclability, and durable catalytic activity is synthesized by a convenient, universal strategy. Interestingly, this hybrid material can effectively catalyze deacetalization-Knoevenagel condensation reaction in the presence of excellent compartmentalization to spatially isolate opposing acid-base sites.
2.
Chem Commun (Camb)
; 55(45): 6377-6380, 2019 May 30.
Artigo
em Inglês
| MEDLINE
| ID: mdl-31089619
RESUMO
A novel strategy has been developed to construct a highly stable core-shell MOF@COF (PCN-222-Co@TpPa-1) bifunctional catalyst through strong π-π stacking interaction. This hybrid material with spatially isolated antagonistic acid-base sites can effectively catalyze the deacetalization-Knoevenagel condensation cascade reaction.