RESUMO
The use of non-fullerene acceptors (NFAs) in organic solar cells has led to power conversion efficiencies as high as 18%1. However, organic solar cells are still less efficient than inorganic solar cells, which typically have power conversion efficiencies of more than 20%2. A key reason for this difference is that organic solar cells have low open-circuit voltages relative to their optical bandgaps3, owing to non-radiative recombination4. For organic solar cells to compete with inorganic solar cells in terms of efficiency, non-radiative loss pathways must be identified and suppressed. Here we show that in most organic solar cells that use NFAs, the majority of charge recombination under open-circuit conditions proceeds via the formation of non-emissive NFA triplet excitons; in the benchmark PM6:Y6 blend5, this fraction reaches 90%, reducing the open-circuit voltage by 60 mV. We prevent recombination via this non-radiative channel by engineering substantial hybridization between the NFA triplet excitons and the spin-triplet charge-transfer excitons. Modelling suggests that the rate of back charge transfer from spin-triplet charge-transfer excitons to molecular triplet excitons may be reduced by an order of magnitude, enabling re-dissociation of the spin-triplet charge-transfer exciton. We demonstrate NFA systems in which the formation of triplet excitons is suppressed. This work thus provides a design pathway for organic solar cells with power conversion efficiencies of 20% or more.
RESUMO
Although significant improvements have been achieved for organic photovoltaic cells (OPVs), the top-performing devices still show power conversion efficiencies far behind those of commercialized solar cells. One of the main reasons is the large driving force required for separating electron-hole pairs. Here, we demonstrate an efficiency of 14.7% in the single-junction OPV by using a new polymer donor PTO2 and a nonfullerene acceptor IT-4F. The device possesses an efficient charge generation at a low driving force. Ultrafast transient absorption measurements probe the formation of loosely bound charge pairs with extended lifetime that impedes the recombination of charge carriers in the blend. The theoretical studies reveal that the molecular electrostatic potential (ESP) between PTO2 and IT-4F is large, and the induced intermolecular electric field may assist the charge generation. The results suggest OPVs have the potential for further improvement by judicious modulation of ESP.
Assuntos
Fontes de Energia Elétrica , Compostos Orgânicos/química , Energia Solar , Eletricidade Estática , Transporte de Elétrons , Fulerenos/química , Modelos Moleculares , Conformação Molecular , Polímeros/químicaRESUMO
The open-circuit voltage of organic solar cells is usually lower than the values achieved in inorganic or perovskite photovoltaic devices with comparable bandgaps. Energy losses during charge separation at the donor-acceptor interface and non-radiative recombination are among the main causes of such voltage losses. Here we combine spectroscopic and quantum-chemistry approaches to identify key rules for minimizing voltage losses: (1) a low energy offset between donor and acceptor molecular states and (2) high photoluminescence yield of the low-gap material in the blend. Following these rules, we present a range of existing and new donor-acceptor systems that combine efficient photocurrent generation with electroluminescence yield up to 0.03%, leading to non-radiative voltage losses as small as 0.21 V. This study provides a rationale to explain and further improve the performance of recently demonstrated high-open-circuit-voltage organic solar cells.
RESUMO
We report a systematic study of the efficiency limitations of non-fullerene organic solar cells that exhibit a small energy loss (Eloss) between the polymer donor and the non-fullerene acceptor. To clarify the impact of Eloss on the performance of the solar cells, three thieno[3,4-c]pyrrole-4,6-dione-based conjugated polymers (PTPD3T, PTPD2T, and PTPDBDT) are employed as the electron donor, which all have complementary absorption spectra compared with the ITIC acceptor. The corresponding photovoltaic devices show that low Eloss (0.54 eV) in PTPDBDT:ITIC leads to a high open-circuit voltage (Voc) of 1.05 V, but also to a small quantum efficiency, and in turn photocurrent. The high Voc or small energy loss in the PTPDBDT-based solar cells is a consequence of less non-radiative recombination, whereas the low quantum efficiency is attributed to the unfavorable micro-phase separation, as confirmed by the steady-state and time-resolved photoluminescence experiments, grazing-incidence wide-angle X-ray scattering, and resonant soft X-ray scattering (R-SoXS) measurements. We conclude that to achieve high performance non-fullerene solar cells, it is essential to realize a large Voc with small Eloss while simultaneously maintaining a high quantum efficiency by manipulating the molecular interaction in the bulk-heterojunction.
RESUMO
A novel polythiophene derivative, PBT1, was designed, synthesized, and applied in polymer solar cells (PSCs). This work provides a successful example of using molecular structure as a tool to realize optimal photovoltaic performance with high polymer content, thus enabling the realization of efficient photoabsorption in very thin films. As a result, an efficiency of 6.88% was recorded in a PSC with a 75 nm active layer.
Assuntos
Polímeros/síntese química , Energia Solar , Tiofenos/síntese química , Absorção , Fontes de Energia Elétrica , Estrutura Molecular , Tamanho da Partícula , Processos Fotoquímicos , Polímeros/química , Propriedades de Superfície , Tiofenos/químicaRESUMO
Herein, a new ternary strategy to fabricate efficient and photostable inverted organic photovoltaics (OPVs) is introduced by combining a bulk heterojunction (BHJ) blend and a fullerene self-assembled monolayer (C60 -SAM). Time-of-flight secondary-ion mass spectrometry - analysis reveals that the ternary blend is vertically phase separated with the C60 -SAM at the bottom and the BHJ on top. The average power conversion efficiency - of OPVs based on the ternary system is improved from 14.9% to 15.6% by C60 -SAM addition, mostly due to increased current density (Jsc ) and fill factor -. It is found that the C60 -SAM encourages the BHJ to make more face-on molecular orientation because grazing incidence wide-angle X-ray scattering - data show an increased face-on/edge-on orientation ratio in the ternary blend. Light-intensity dependent Jsc data and charge carrier lifetime analysis indicate suppressed bimolecular recombination and a longer charge carrier lifetime in the ternary system, resulting in the enhancement of OPV performance. Moreover, it is demonstrated that device photostability in the ternary blend is enhanced due to the vertically self-assembled C60 -SAM that successfully passivates the ZnO surface and protects BHJ layer from the UV-induced photocatalytic reactions of the ZnO. These results suggest a new perspective to improve both performance and photostability of OPVs using a facial ternary method.
RESUMO
We report efficient polymer solar cells (PSCs) based on poly(3-hexylthiophene) (P3HT) and indene-C(60) bisadduct (ICBA) with water soluble nickel acetate (NiAc) instead of acidic poly(ethylenedioxythiophene) : poly(styrene sulfonate) (PEDOT : PSS) as hole collection layer (HCL). The NiAc layer after thermal annealing at 150 °C for 30 min (α-NiAc) shows high transparency with light transmittance better than PEDOT : PSS in the wavelength range of 500-900 nm, high hole mobility of 1.3 × 10(-3) cm(2) V(-1) s(-1) and suitable energy levels for application as HCL. The power conversion efficiency of the PSC based on P3HT/ICBA with the α-NiAc anode buffer layer reached 6.08% under the illumination of AM1.5G 100 mW cm(-2), which is among the best efficiencies of the P3HT-based PSCs. This work gives a new option for HCL selection in designing higher efficiency and more stable PSCs.
RESUMO
A solution-processed vanadium oxide (s-VO(x)) anode buffer layer on an indium-tin-oxide (ITO) electrode was used instead of PEDOT:PSS for improving the stability and photovoltaic performance of the polymer solar cells (PSCs). The s-VO(x) layer was prepared by spin-coating a vanadyl acetylacetonate (VO(acac)(2)) isopropyl alcohol solution on the ITO electrode and then thermal annealing at 150 °C for 10 min. The s-VO(x) oxide layer is highly transparent in the visible range and shows effective hole collection property. The photovoltaic performance of the s-VO(x) buffer layer was studied by fabricating the PSCs based on poly(3-hexylthiophene) (P3HT) as an electron donor and four soluble fullerene derivatives, [6,6]-phenyl-C(61)-butyric acid methyl ester (PC(60)BM), [6,6]-phenyl-C(71)-butyric acid methyl ester (PC(70)BM), indene-C(60) bisadduct (IC(60)BA), and indene-C(70) bisadduct (IC(70)BA), as electron acceptors. The PSCs with the s-VO(x) buffer layer show improved performance in comparison with the traditional devices with the PEDOT:PSS buffer layer on ITO, no matter which fullerene derivative was used as an acceptor. The power conversion efficiency of the PSC based on P3HT:IC(70)BA (1 : 1, w/w) with the s-VO(x) anode buffer layer reached 6.35% under the illumination of AM1.5G 100 mW cm(-2).
Assuntos
Fontes de Energia Elétrica , Óxidos/química , Polímeros/química , Compostos de Estanho/química , Compostos de Vanádio/química , Eletrodos , Hidroxibutiratos/química , Óxidos/síntese química , Pentanonas/química , Soluções , Compostos de Vanádio/síntese químicaRESUMO
Manipulating charge generation in a broad spectral region has proved to be crucial for nonfullerene-electron-acceptor-based organic solar cells (OSCs). 16.64% high efficiency binary OSCs are achieved through the use of a novel electron acceptor AQx-2 with quinoxaline-containing fused core and PBDB-TF as donor. The significant increase in photovoltaic performance of AQx-2 based devices is obtained merely by a subtle tailoring in molecular structure of its analogue AQx-1. Combining the detailed morphology and transient absorption spectroscopy analyses, a good structure-morphology-property relationship is established. The stronger π-π interaction results in efficient electron hopping and balanced electron and hole mobilities attributed to good charge transport. Moreover, the reduced phase separation morphology of AQx-2-based bulk heterojunction blend boosts hole transfer and suppresses geminate recombination. Such success in molecule design and precise morphology optimization may lead to next-generation high-performance OSCs.
RESUMO
Organic solar cells are thought to suffer from poor thermal stability of the active layer nanostructure, a common belief that is based on the extensive work that has been carried out on fullerene-based systems. We show that a widely studied non-fullerene acceptor, the indacenodithienothiophene-based acceptor ITIC, crystallizes in a profoundly different way as compared to fullerenes. Although fullerenes are frozen below the glass-transition temperature Tg of the photovoltaic blend, ITIC can undergo a glass-crystal transition considerably below its high Tg of â¼180 °C. Nanoscopic crystallites of a low-temperature polymorph are able to form through a diffusion-limited crystallization process. The resulting fine-grained nanostructure does not evolve further with time and hence is characterized by a high degree of thermal stability. Instead, above Tg, the low temperature polymorph melts, and micrometer-sized crystals of a high-temperature polymorph develop, enabled by more rapid diffusion and hence long-range mass transport. This leads to the same detrimental decrease in photovoltaic performance that is known to occur also in the case of fullerene-based blends. Besides explaining the superior thermal stability of non-fullerene blends at relatively high temperatures, our work introduces a new rationale for the design of bulk heterojunctions that is not based on the selection of high- Tg materials per se but diffusion-limited crystallization. The planar structure of ITIC and potentially other non-fullerene acceptors readily facilitates the desired glass-crystal transition, which constitutes a significant advantage over fullerenes, and may pave the way for truly stable organic solar cells.
RESUMO
A nonfullerene-based polymer solar cell (PSC) that significantly outperforms fullerene-based PSCs with respect to the power-conversion efficiency is demonstrated for the first time. An efficiency of >11%, which is among the top values in the PSC field, and excellent thermal stability is obtained using PBDB-T and ITIC as donor and acceptor, respectively.
RESUMO
Low-work-function active metals are commonly used as cathode in polymer solar cells (PSCs), but sensitivity of the active metals towards moisture and oxygen results in poor stability of the devices. Therefore, solution-proceessable and stable cathode buffer layer is of great importance for the application of PSCs. Here we demonstrate high performance PSCs by employing as-prepared zirconium acetylacetonate (a-ZrAcac) film spin-cast from its ethanol solution as cathode buffer layer. The PSCs based on a low bandgap polymer PBDTBDD as donor and PC60BM as acceptor with a-ZrAcac/Al cathode demonstrated an average power conversion efficiency (PCE) of 8.75% which is significantly improved than that of the devices with traditional Ca/Al cathode. The improved photovoltaic performance is benefitted from the decreased series resistance and enhanced light harvest of the PSCs with the a-ZrAcac/Al cathode. The results indicate that a-ZrAcac is a promising high performance cathode buffer layer for fabricating large area flexible PSCs.
RESUMO
An integrated device architecture was constructed via vertical combination of planar and bulk heterojunctions by solution processing, where a cross-linked D-A copolymer (PBDTTT-Br25) was inserted between a PEDOT:PSS layer and the blended photoactive layer. PBDTTT-Br25 can readily undergo photo crosslinking to form an insoluble robust film via ultraviolet irradiation after solution-deposition, which enables the subsequent solution processing of a photoactive layer on the robust surface. The insertion of a pure PBDTTT-Br25 layer to build an integrated heterojunction could provide an additional donor/acceptor interface, which enables hole transport to the anode without interruption, thereby reducing the charge carrier recombination probability. The power conversion efficiency (PCE) of the polymer solar cell (PSC) with the integrated architecture reaches 5.24% under an AM1.5G illumination of 100 mW/cm(2), which is increased by 65%, in comparison with that of the reference single heterojunction device (3.17%), under the same experimental conditions.
RESUMO
High-performance inverted polymer solar cells (PSCs) with solution-processed titanium chelate TIPD as electron collecting layer are reported. The power conversion efficiency (PCE) of the inverted PSC with a-TIPD buffer layer with thermal annealing at 150 °C for 10 min reached 7.4% under the illumination of AM1.5, 100 mW/cm(2), which is increased by 16% in comparison with that (6.4%) of the device in the conventional structure. The PCE of 7.4% is the highest among the inverted PSCs reported so far in the literature.