Effect of calcium oxide on chromium solidification during the melting of hazardous waste incineration fly ash.

Thermal treatment technology considerably affects the harmlessness of fly ash (FA), but highly toxic heavy metals, such as Cr, attract considerable attention. In this study, we investigated the influence of CaO dosage at 600°C-1200 °C on the curing effect of Cr during FA thermal treatment based on the combination effect of CaO. Static, dynamic, and continuous sequential leachings were performed for the sintered products. Results showed that the leaching concentration of Cr decreased by approximately 91% when CaO dosage was 8.57%, and the difference in the residual state was the main reason for the difference in the leaching behavior of Cr. The proportion of the residual state in the sintered products increased from 35.16% to 64.01%. The transition between Cr2O3, Cr5O12, and CaCr2O4 is the fundamental reason for the leaching behavior of Cr and the change in the residual state. This study provides a scientific basis for preventing and controlling heavy metal pollution and optimizing environmental supervision in the FA thermal treatment process.

Effect of Fe-based substance on Cr leaching behavior in hazardous waste incineration fly ash after thermal treatment.

This study investigated the influence of the interaction between Fe-based substances and thermal treatment parameters on the leaching behavior of Cr in hazardous waste incineration fly ash (HWIFA) after thermal treatment. The results revealed that the interaction between the addition of Fe-based substance and the thermal treatment parameters and their effects on static and dynamic leaching behaviors of Cr had significant differences when Fe2O3, Fe3O4, and Fe were added, respectively. Specifically, when Fe2O3 or Fe was added, the thermal treatment temperature was the most significant factor affecting the static leaching of Cr in thermal treated HWIFA, and the interaction effect of other factors was not significant. The most important influence on the dynamic leaching behavior of Cr was the interaction between the thermal treatment temperature and the addition of Fe2O3. Different from the addition of Fe2O3, the effect of the addition of Fe3O4 on the static leaching of Cr in thermal treated HWIFA was more significant than that of thermal treatment temperature; meanwhile, the interaction between the thermal treatment temperature and the addition of Fe3O4 was also significant. However, when Fe3O4 was added, the effect of interaction between factors on the dynamic leaching of Cr in thermal treated HWIFA was consistent with that when Fe2O3 was added.

Transformation and leaching behavior of Pb in hazardous waste incineration fly ash after thermal treatment with addition of Fe2O3.

This study investigated the leaching behavior of Pb in hazardous waste incineration fly ash (HWIFA) after adding Fe2O3 thermal treatment and revealed the leaching mechanism of Pb from the perspective of phase transformation. The static leaching results showed that at 600 °C-1300 °C, with the addition of Fe2O3 increased, the Pb leaching toxicity continued to decrease. The dynamic results indicated that as the thermal treatment temperature was higher than 1100 °C, the addition of Fe2O3 can effectively inhibit the dynamic leaching of Pb in HWIFA. Meanwhile, the inhibition effect was not very closely related to the amount of Fe2O3. The addition of Fe2O3 can react with PbO to form PbFe12O19, which has a better stability. The appearance of PbFe12O19 was the main reason for adding Fe2O3 to enhanced the immobilization of Pb. However, the amount of Fe2O3 should be carefully controlled to avoid an excessive reducible fraction of Pb in the thermal treated HWIFA, which will affect the long-term stability of Pb.