Phase Change Material Evolution in Thermal Energy Storage Systems for the Building Sector, with a Focus on Ground-Coupled Heat Pumps.

The building sector is responsible for a third of the global energy consumption and a quarter of greenhouse gas emissions. Phase change materials (PCMs) have shown high potential for latent thermal energy storage (LTES) through their integration in building materials, with the aim of enhancing the efficient use of energy. Although research on PCMs began decades ago, this technology is still far from being widespread. This work analyses the main contributions to the employment of PCMs in the building sector, to better understand the motivations behind the restricted employment of PCM-based LTES technologies. The main research and review studies are critically discussed, focusing on: strategies used to regulate indoor thermal conditions, the variation of mechanical properties in PCMs-based mortars and cements, and applications with ground-coupled heat pumps. The employment of materials obtained from wastes and natural sources was also taken in account as a possible key to developing composite materials with good performance and sustainability at the same time. As a result, the integration of PCMs in LTES is still in its early stages, but reveals high potential for employment in the building sector, thanks to the continuous design improvement and optimization driven by high-performance materials and a new way of coupling with tailored envelopes.

A second life for cigarette butts? A review of recycling solutions.

Trillions of cigarettes are smoked annually making cigarette butts one of the most common types of litter in the world. Due to the materials and toxic substances that they contain, this waste carries a very harmful risk for the environment and for living organisms (including humans). Only a few - barely sustainable - solutions have tried to tackle this waste and alternative solutions to landfilling and incineration are needed. Identifying the best methodological solutions and technologies for recycling this kind of waste in terms of results and applicability to real contexts would reduce the presence of dangerous materials in the environment and ecosystems and would promote the recovery of materials in line with the circular economy and sustainable development. The objective of this review was to collect and analyze the alternative solutions available in the literature for the recovery and recycling of the materials in cigarette butts, considering them as possible sources of secondary raw materials applicable to contexts of common interest. Several papers were selected and the results obtained by the authors are presented in terms of type of treatment process (physical, chemical or both), product derived (in solid, liquid or gaseous form) and its possible use in different sectors (e.g. construction, electronics, energy, chemistry and environmental protection). The main results, together with the advantages and disadvantages are highlighted and proposals for further research are outlined.

Ecotoxicity of Plastics from Informal Waste Electric and Electronic Treatment and Recycling.

Plastic materials account for about 20% of waste electrical and electronic equipment (WEEE). The recycling of this plastic fraction is a complex issue, heavily conditioned by the content of harmful additives, such as brominated flame retardants. Thus, the management and reprocessing of WEEE plastics pose environmental and human health concerns, mainly in developing countries, where informal recycling and disposal are practiced. The objective of this study was twofold. Firstly, it aimed to investigate some of the available options described in the literature for the re-use of WEEE plastic scraps in construction materials, a promising recycling route in the developing countries. Moreover, it presents an evaluation of the impact of these available end-of-life scenarios on the environment by means of the life cycle assessment (LCA) approach. In order to consider worker health and human and ecological risks, the LCA analysis focuses on ecotoxicity more than on climate change. The LCA evaluation confirmed that the plastic re-use in the construction sector has a lower toxicity impact on the environment and human health than common landfilling and incineration practices. It also shows that the unregulated handling and dismantling activities, as well as the re-use practices, contribute significantly to the impact of WEEE plastic treatments.

Data on the environmental performance analysis of a dual-source heat pump system.

This data article reports supplementary input and output data related to the research article "Environmental performance analysis of a dual-source heat pump system" on the life cycle assessment evaluation of an heat pump prototype, able to use alternatively the air and the ground as external heat sources. Primarily, the present article shows the life cycle inventory input data of the system under study and of the conventional air and ground heat pump systems, which were used for comparison. Secondly, complete numerical results are exposed, which are showed only graphically and in an aggregated form in the main article. Data include normalised and unaggregated environmental impacts of each investigated life cycle phase. The article also reports the complete results of the sensitivity analysis conducted using different assumptions on the energy mix and on the energy use.

An innovative container for WEEE collection and transport: details and effects following the adoption.

The content of hazardous components in Waste arising from Electrical and Electronic Equipment (WEEE) is a major concern that urges governments and industry to take measures to ensure proper treatment and disposal. Thus, the European Union issued directives to encourage reuse, recycling and other proper forms of recovery of such waste while companies and academics are still studying methods and technologies for optimizing recovery processes. This paper presents an analysis of the logistics process assuring the correct collection, handling, transportation and storing of WEEE. The experience comes from an Italian WEEE treatment plant (TRED Carpi S.r.l.) where a new kind of container has been introduced in order to improve the logistics system. An evaluation framework is described and used in order to compare different system configurations and assess the advantages emerging from adopting proper equipments for WEEE transport and handling.