Carboxymethyl-imidazolium O-vanillin Schiff base grafted into NH2-tagged MIL-101 (Cr) for effective removal of cupric ions from aqueous effluents.

A novel adsorbent (MIL-CMIVSB) was fabricated by modification of H2N-MIL-101(Cr) with carboxymethyl-imidazolium O-vanillin Schiff base. The MIL-CMIVSB's physicochemical characteristics were examined using the pertinent characterization methods. NH2-MIL-101(Cr) has a BET surface area of 1492.4 m2g-1, while MIL-CMIVSB adsorbent had 1278.7 m2g-1. Batch adsorption experiments examined the MIL-CMIVSB's cupric ion adsorption capacity from aqueous solutions at different adsorbent doses (0.1-3 mg), pH (2.0-10.0), contact times (0-240 min), metal ion initial concentrations (10-300 mg/L), and temperatures (298-308 K). The optimum conditions were 1 mg/mL of MIL-CMIVSB adsorbent, 46 min adsorption time, pH 7, 100 ppm initial cupric ion concentration, and 303 K temperature. MIL-CMIVSB effectively and selectively removes cupric ions with an adsorption capability of 359.05 ± 12.06 mg/g. The nonlinear Liu isotherm governed Cu(II) sorption performance on MIL-CMIVSB (KL = 0.257 ± 0.01 mg/g, R2 = 0.99892) and pseudo-2nd-order kinetically (k2 = 0.00116 × 10-4 g/mg min, R2 = 0.99721).

Dielectric Barrier Discharge Plasma Processing and Sr-Doped ZnO/CNT Photocatalyst Decoration of Cotton Fabrics for Self-Cleaning Application.

Nonthermal plasma processing is a chemical-free and environmentally friendly technique to enhance the self-cleaning activity of nanoparticle-coated cotton fabrics. In this research, Sr-doped ZnO/carbon nanotube (CNT) photocatalysts, namely, S10ZC2, S15ZC2, and S20ZC2 with different Sr doping concentrations, were synthesized using the sol-gel method and coated on plasma-functionalized fabric to perform the self-cleaning tests. The fabrics were treated with dielectric barrier discharge plasma in an open environment for 3 min to achieve a stable coating of nanoparticles. The energy band gap of the photocatalyst decreased with an increase in the level of Sr doping. The band gap of S10ZC2, S15ZC2, and S20ZC2 photocatalysts was estimated to be 2.85, 2.78, and 2.5 eV, respectively. The hexagonal wurtzite structure of ZnO was observed on the fabric surface composited with CNTs and Sr. The S20ZC2 photocatalyst showed better homogeneity and photocatalytic response on the fabric when compared with S10ZC2- and S15ZC2-coated fabrics. The S20ZC2 photocatalyst showed 89% dye degradation efficiency after 4 h of light exposure in methylene blue solution, followed by S15ZC2 (84%) and S10ZC2 (80%) photocatalysts.

Biodiesel production from date seed oil using hydroxyapatite-derived catalyst from waste camel bone.

Biodiesel is considered to be more friendly to the environment than petroleum-based fuels, cheaper and capable for producing greener energy which contributed positively in boosting bio-economy. A new non-edible feedstock utilized from date seed oil was analyzed for the synthesis of eco-friendly biodiesel using newly novel hydroxyapatite heterogeneous catalysts, obtaining from waste camel bones prepared from dried camel bone followed calcination under different temperature. This catalyst was characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) and transmission electron microscopy (TEM). Results showed that hydroxyapatite catalyst pore size reduced with increasing the calcination temperature. Optimize biodiesel yield (89 wt%) was achieved through the process of transesterification with optimum reaction conditions of 4 wt% catalyst, oil to ethanol molar ratio of 1:7 and temperature 75 °C for 3 h reaction time. The production of FAME was confirmed by using gas chromatography-mass spectroscopy (GC-MS). Fuel properties of fatty acid ethyl ester complied with ASTM D 6751 which indicated that it would be an appropriate alternative form of fuel. As a result, using biodiesel made from waste and untamed resources to develop and implement a more sustainable and environmentally friendly energy strategy is commendable. The acceptance and implementation of the green energy method may result in favorable environmental effects, which in turn may lead to better societal and economic growth for biodiesel industry at a larger scale.

Methyl esters synthesis from Luffa cylindrica seeds oil using green copper oxide nanoparticle catalyst in membrane reactor.

This study investigates the potential role of Juglans sp. root extract-mediated copper oxide nanoparticles of Luffa cylindrica seed oil (LCSO) into methyl esters. The synthesized green nanoparticle was characterized by Energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), and Scanning electron microscopy (SEM) spectroscopies to find out the crystalline size (40 nm), surface morphology (rod shape), particle size (80-85 nm), and chemical composition (Cu = 80.25% & O = 19.75%), accordingly. The optimized protocol for the transesterification reaction was adjusted as oil to methanol molar ratio (1:7), copper oxide nano-catalyst concentration (0.2 wt %), and temperature (90 °C) corresponding to the maximum methyl esters yield of 95%. The synthesized methyl esters were characterized by GC-MS, 1H NMR, 13C NMR, and FT-IR studies to know and identify the chemical composition of newly synthesized Lufa biodiesel. The fuel properties of Luffa cylindrica seed oil biofuel were checked and compared with the American Biodiesel standards (ASTM) (D6751-10). Finally, it is commendable to use biodiesel made from wild, uncultivated, and non-edible Lufa cylindrica to promote and adopt a cleaner and sustainable energy method. The acceptance and implementation of the green energy method may result in favourable environmental effects, which in turn may lead to better societal and economic development.

Effect of Ionic Liquids on Mechanical, Physical, and Antifungal Properties and Biocompatibility of a Soft Denture Lining Material.

This study aims to evaluate the effect of ionic liquids and their structure on the mechanical (tensile bond strength (TBS) and Shore A hardness), mass change, and antifungal properties of soft denture lining material. Butyl pyridinium chloride (BPCL) and octyl pyridinium chloride (OPCL) were synthesized, characterized, and mixed in concentrations ranging from 0.65-10% w/w with a soft denture liner (Molloplast-B) and were divided into seven groups (C, BPCL1-3, and OPCL1-3). The TBS of bar-shaped specimens was calculated on a Universal Testing Machine. For Shore A hardness, disc-shaped specimens were analyzed using a durometer. The mass change (%) of specimens was calculated by the weight loss method. The antifungal potential of ionic liquids and test specimens was measured using agar well and disc diffusion methods (p ≤ 0.05). The alamarBlue assay was performed to assess the biocompatibility of the samples. The mean TBS values of Molloplast-B samples were significantly lower (p ≤ 0.05) for all groups except for OPCL1. Compared with the control, the mean shore A hardness values were significantly higher (p ≤ 0.05) for samples in groups BPCL 2 and 3. After 6 weeks, the OPCL samples showed a significantly lower (p ≤ 0.05) mass change as compared to the control. Agar well diffusion methods demonstrated a maximum zone of inhibition for 2.5% OPCL (20.5 ± 0.05 mm) after 24 h. Disc diffusion methods showed no zones of inhibition. The biocompatibility of the ionic liquid-modified sample was comparable to that of the control. The addition of ionic liquids in Molloplast-B improved the liner's surface texture, increased its hardness, and decreased its % mass change and tensile strength. Ionic liquids exhibited potent antifungal activity.

Chemotherapeutic Activity of Imidazolium-Supported Pd(II) o-Vanillylidene Diaminocyclohexane Complexes Immobilized in Nanolipid as Inhibitors for HER2/neu and FGFR2/FGF2 Axis Overexpression in Breast Cancer Cells.

Two bis-(imidazolium-vanillylidene)-(R,R)-diaminocyclohexane ligands (H2(VAN)2dach, H2L1,2) and their Pd(II) complexes (PdL1 and PdL2) were successfully synthesized and structurally characterized using microanalytical and spectral methods. Subsequently, to target the development of new effective and safe anti-breast cancer chemotherapeutic agents, these complexes were encapsulated by lipid nanoparticles (LNPs) to formulate (PdL1LNP and PdL2LNP), which are physicochemically and morphologically characterized. PdL1LNP and PdL2LNP significantly cause DNA fragmentation in MCF-7 cells, while trastuzumab has a 10% damaging activity. Additionally, the encapsulated Pd1,2LNPs complexes activated the apoptotic mechanisms through the upregulated P53 with p < 0.001 and p < 0.05, respectively. The apoptotic activity may be triggered through the activity mechanism of the Pd1,2LNPs in the inhibitory actions against the FGFR2/FGF2 axis on the gene level with p < 0.001 and the Her2/neu with p < 0.05 and p < 0.01. All these aspects have triggered the activity of the PdL1LNP and PdL2LNP to downregulate TGFß1 by p < 0.01 for both complexes. In conclusion, LNP-encapsulated Pd(II) complexes can be employed as anti-cancer drugs with additional benefits in regulating the signal mechanisms of the apoptotic mechanisms among breast cancer cells with chemotherapeutic-safe actions.

Treatment of Saussurea heteromalla for biofuel synthesis using catalytic membrane reactor.

Membrane technology has been adopted as a prospective and promising alternative to the standard technology used for biodiesel production since the time when it had some limitations. During this research project, the inedible seed oil generating feedstock known as Saussurea heteromalla was put through a biodiesel production process that utilized membrane technology with an effort to increase the yield of methyl ester. The transesterification process was mediated by zirconium oxide nanoparticles that were generated using an aqueous extract of Portulaca oleracea leaf. With an oil to methanol ratio of 1:9, a catalyst concentration of 0.88 (wt. %), temperature of 87 °C, and reaction time of 180 min, the highest possible biodiesel yield of 93% was achieved. The findings of the catalyst characterization demonstrated the purity of the zirconium oxide nano particles and their nanoscale nature with average particle size of 31 nm. Using gas chromatography and mass spectrometry (GC/MS), an examination of biodiesel revealed the presence of four different peaks of methyl esters. Using Fourier-transform infrared spectroscopy (FTIR) and nuclear magnetic resonance, we were able to verify that the production of methyl esters in the biodiesel sample was successful (NMR). Zerconium oxide nanoparticles were found reusable up to five consecutive cycles of transesterification. The fuel-related properties of methyl ester have been determined and are in line with the requirements of the international standards ASTM D-6571 and EN 14214. In the course of our ongoing research, we made use of membrane technology, which led to the production of biodiesel from the seed oil of Saussurea heteromalla that was better for the environment, more cost effective, and produced in greater quantities.

Ionic chitosan Schiff bases supported Pd(II) and Ru(II) complexes; production, characterization, and catalytic performance in Suzuki cross-coupling reactions.

Taking the advantage of multifunctional characteristics of chitosan (CS), we have developed new scaffolds (imidazolium-vanillyl-chitosan Schiff bases (IVCSSBs)) for supporting Pd(II) and Ru(II) ions in catalyzing Suzuki coupling reactions. The structures of new materials were described based on their elemental, spectral, thermal, and microscopic analysis. The strong interactions between the binding sites of IVCSSB ligand (OH, H-C=N, and OCH3 groups) and Pd(II) ions resulted in the formation of an excellent heterogeneous catalyst (Pd(II)IVCSSB1) with amazing catalytic activity (up to 99%) and highly stable in the reaction medium. The reusability experiments for Pd(II)IVCSSB1 revealed that there is no appreciable decrease in its catalytic activity even after five consecutive operation runs. Furthermore, this heterogeneous catalyst showed an excellent selectivity toward the cross-coupling reaction where no homo-coupling byproducts were observed in the 1H NMR spectra of the obtained products. Consequently, the present ionic catalytic system may open a new window for a novel generation of ionic bio-based catalysts for organic transformations.

Inhibitory activity of biofunctionalized silver-capped N-methylated water-soluble chitosan thiomer for microbial and biofilm infections.

One of the most important self-defense strategies employed by bacteria to resist the action of antibiotics is a biofilm formation upon the infected surface. Thus, there is an urgent need to explore novel candidates that have potent antibacterial and anti-biofilm effects to tackle this challenge. In this endeavor, we have transformed shrimp shell wastes to N-methylated water-soluble chitosan thiomer (MWSCT) which was used as either a chelating agent or bio-reductant and capping agent for Ag(I) ions in the preparation of a Ag(I)MWSCT complex or silver nanocomposite (Ag(0)MWSCT), for targeting antibacterial and anti-biofilm applications. The antibacterial and anti-biofilm performance of the new methylated chitosan thiomer (MWSCT) and its silver architectures (Ag(I)MWSCT, Ag(0)MWSCT) were assessed in vitro against E. coli and S. aureus. These new materials have significant capacities to synergistically inhibit the proliferation of the targeted bacterial cells and biofilm formation, in a structure- and species-dependent manner. Ag(0)MWSCT emerged as the most potent compound in inhibiting the growth of bacterial strains (MICE. coli/ MICS. aureus = 0.05/ 0.34 µg/mL, 1.6-/ 2.5-times lower than that recorded for the clinical drug (ciprofloxacin, Cipro). Also, this nanocomposite showed the highest anti-biofilm effects (only 1.7% E. coli biofilm growth; 11.8% staphylococcal biofilm growth).

Luminescence recognition of different organophosphorus pesticides by the luminescent Eu(III)-pyridine-2,6-dicarboxylic acid probe.

Luminescence quenching of a novel long lived Eu(III)-pyridine-2,6-dicarboxylic acid probe of 1:2 stoichiometric ratio has been studied in 0.10 volume fraction ethanol-water mixture at pH 7.5 (HEPES buffer) in the presence of the organophosphorus pesticides chlorfenvinphos (P1), malathion (P2), azinphos (P3), and paraxon ethyl (P4). The luminescence intensity of Eu(III)-(PDCA)(2) probe decreases as the concentration of the pesticide increases. It was observed that the quenching due to P3 and P4 proceeds via both diffusional and static quenching processes. Direct methods for the determination of the pesticides under investigation have been developed using the luminescence quenching of Eu(III)-pyridine-2,6-dicarboxylic acid probe in solution. The linear range for determination of the selected pesticides is 1.0-35.0 µM. The detection limits were 0.24-0.55 µM for P3, P4, and P1 and 2.5 µM for P2, respectively. The binding constants (K), and thermodynamic parameters of the OPs with Eu(III)-(PDCA)(2) were evaluated. Positive and negative values of entropy (ΔS) and enthalpy (ΔH) changes for Eu(III)-(PDCA)(2)-P1 ternary complex were calculated. As the waters in this study do not contain the above mentioned OPs over the limit detectable by the method, a recovery study was carried out after the addition of the adequate amounts of the organophosphorus pesticides under investigation.