Redox chemistry of low-pH forms of tetrahemic cytochrome c3.

Desulfovibrio vulgaris Hildenborough cytochrome c(3) contains four hemes in a low-spin state with bis-histidinyl coordination. High-spin forms of cytochrome c(3) can be generated by protonation of the axial ligands in order to probe spin equilibrium (low-spin/high-spin). The spin alterations occurring at acid pH, the associated changes in redox potentials, as well as the reactivity towards external ligands were followed by the conjunction of square wave voltammetry and UV-visible, CD, NMR and EPR spectroscopies. These processes may be used for modelling the action of enzymes that use spin equilibrium to promote enzyme activity and reactivity towards small molecules.

Minimal supergravity scalar neutrino dark matter and inverse seesaw neutrino masses.

We show that within the inverse seesaw mechanism for generating neutrino masses, minimal supergravity naturally provides the scalar neutrino as the lightest superparticle. We also demonstrate that such schemes naturally reconcile the small neutrino masses with the correct relic scalar neutrino dark matter abundance and accessible direct detection rates in nuclear recoil experiments. This way, inverse seesaw minimal supergravity offers a common solution to the generation of the neutrino mass and to the origin of dark matter.

Supersymmetric SO10 seesaw mechanism with low B-L scale.

We propose a new seesaw mechanism for neutrino masses within a class of supersymmetric SO(10) models with broken D parity. It is shown that in such scenarios the B-L scale can be as low as TeV without generating inconsistencies with gauge coupling unification nor with the required magnitude of the light neutrino masses. This leads to a possibly light new neutral gauge boson as well as relatively light quasi-Dirac heavy leptons. These particles could be at the TeV scale and mediate lepton flavor and CP violating processes at appreciable levels.