3-Hydroxyphenylboronic Acid-Based Carbon Dot Sensors for Fructose Sensing.

The selective fluorescence sensing of fructose was achieved by fluorescence quenching of the emission of hydrothermal-synthesized carbon quantum dots prepared by 3-hydroxyphenylboronic acid. Quantification of fructose was possible in aqueous solutions with pH of 9 (Limit of Detection LOD and Limit of Quantification LOQ of 2.04 and 6.12 mM), by quenching of the emission at 376 nm and excitation ~380 nm with a linearity range of 0-150 mM. A Stern-Volmer constant (KSV) of 2.11 × 10-2 mM-1 was obtained, while a fluorescent quantum yield of 31% was calculated. The sensitivity of this assay towards fructose was confirmed by comparison with other sugars (such as glucose, sucrose and lactose). Finally, the validity of the proposed assays was further demonstrated by performing recovery assays in different matrixes. Graphical Abstract.

Insight into the hybrid luminescence showed by carbon dots and molecular fluorophores in solution.

Carbon dots have attracted great attention from the research community given their very attractive luminescent properties. However, the recent discovery that some of these properties may result from fluorescent impurities originating from the synthesis process, and not from the carbon dots themselves, constitute a significant setback to our knowledge of these materials. Herein, we proceeded to the study of carbon dots generated from citric acid and urea via a microwave-assisted synthesis, focusing on their analysis by AFM, HR-TEM, XPS, FT-IR, ESI-MS, UV-Vis and fluorescence spectroscopy. We have found that this synthesis process does generate molecular fluorophores that can mask the luminescence of the carbon dots. More importantly, our data demonstrates that when present in the same solution, the carbon dots and these fluorophores do not behave as separated species with individual emission. Instead, they interact to produce a hybrid luminescence, which excited state properties and reactivity are different from the properties of the individual species. These results indicate the possibility for the development of hybrid materials composed by carbon dots and related molecular fluorophores with new and improved properties.

Photocatalytic removal of pharmaceutical water pollutants by TiO2 - Carbon dots nanocomposites: A review.

Pharmaceuticals are becoming increasingly more relevant water contaminants, with photocatalysts (such as TiO2) being a promising approach to remove these compounds from water. However, TiO2 has poor sunlight-harvesting capacity, low photonic efficiency, and poor adsorption towards organic pollutants. One of the emerging strategies to enhance the photocatalytic performance of TiO2 is by conjugating it with fluorescent carbon dots. Herein, we performed a critical review of the development of TiO2 - carbon dots nanocomposites for the photocatalytic removal of pharmaceuticals. We found that carbon dots can improve the photocatalytic efficiency of the resulting nanocomposites, mostly due to increasing the adsorption of organic pollutants and enhancing the absorption in the visible range. However, while this approach shows significant promise, we also identified and discussed several aspects that need to be addressed before this strategy could be more widely used. We hope that this review can guide future studies aiming to the development of enhanced photocatalytic TiO2 - carbon dots nanocomposites.