Separate and combined effects of 3D building features and urban green space on land surface temperature.

Deduction of urban green space (UGS) and the multidimensional growth of building have exacerbated the urban heat island (UHI). Yet thorough investigations into how 3D building features and UGS combinedly influence urban land surface temperature (LST) are limited, especially at the road-based blocks scale. Therefore, the study uses the boosted regression tree (BRT) model to explore the relative contribution and marginal effects of the influential factors on LST, and quantify the warming/cooling effects of buildings and UGS. Results show that, (1) building coverage ratio (BCR) is the most influential factor among seven building metrics with a relative contribution of 44.6%. Besides, high-rise buildings tend to alleviate LST while low- and mid-rise buildings heat the surroundings. (2) Green coverage ratio (GCR), edge density (ED), and patch density (PD) are the most influential factors among six UGS metrics, with the relative contribution of 21.0%, 20.9%, and 20.4%, respectively. (3) Comprehensively considering 13 metrics, we find that the dominant influential factor is BCR with a relative contribution of 28.3%, while the regulation amplitudes to LST of aggregation index (AI) and GCR dramatically reduced. These findings indicate that the cooling effect of UGS will be obscured when the buildings coverage is large. Hence, only relying on UGS to alleviate the heat island effect seems inadequate, the keys are the reasonable planning and optimization of 3D built environment.

Process optimization to enhance utilization efficiency of precipitants for chloride removal from flue gas desulfurization wastewater via Friedel's salt precipitation.

The treatment cost for Cl- removal by Friedel's salt precipitation depended significantly on utilization rate of the precipitant aluminate. In this study, effects of Ca/Al molar ratio, reaction time, temperature and Al/Cl molar ratio were investigated to maximize Al utilization rate for Cl- removal from flue gas desulfurization wastewater. Batch results showed that the maximum Al utilization rate of 55.8-60.3% was obtained at Ca/Al ratio of 3.00, reaction time of 90 min, temperature of 35 °C and Al/Cl ratio of 0.50 regardless of the initial Cl- concentration. The precipitate obtained at the highest Al utilization rate had the highest interlayer spacing, the best crystal integrity, and the strongest binding energy of the Al-OH bond. The optimized condition made ion exchange between Cl- and OH- easier, and obtained more stable Friedel's salt structure to adsorb Cl-. Pilot-scale results showed that maximizing Al utilization rate with low dosages of precipitants had insignificant effects on the removal of Mg2+, Ca2+ and sulfate compared to the strategy to maximize Cl-, but enhanced Al utilization rate from 38.2% to 56.4%. Economic analysis showed that enhancing Al utilization rate greatly reduced treatment cost of the Friedel's salt precipitation method by 30.5%, and made the two-stage desalination process more feasible and worth popularizing.

Altitude explains insignificant autumn phenological changes across regions with large topography relief in the Tibetan Plateau.

The start of the growing season (SGS) and the end of the growing season (EGS) are widely employed in global change studies to represent the spring and autumn phenology, respectively. Despite the Tibetan Plateau (TP) experiencing significant warming in recent decades, EGS has exhibited only slight changes. Previous studies have concentrated on exploring the environmental regulation of phenology, ignoring the distinctive influences of elevation. Therefore, a more in-depth investigation into the underlying mechanism is warranted. In this study, we investigate the variability of EGS among alpine vegetation regions at different elevations and conduct an analysis based on satellite data. Phenology data of alpine vegetation are extracted from SPOT NDVI dataset spanning from 1999 to 2018, using a piecewise-logistic-maximum-ratio method. We analyze the factors influencing EGS trends at different elevations. The results show that the overall insignificant variation in EGS is mainly attributed to altitude. With the altitude increasing, the annual mean EGS experiences a delay of 0.28 days/100 m below 3500 m, while it advances by 0.2 days/100 m above 3500 m. The opposing shift in elevation below and above 3500 m leads to this counteraction. Elevation emerges as the predominant factor influencing EGS trends, explaining the highest variations (38 %), followed by SGS (22 %) and precipitation (22 %). The elevation effect is most pronounced in areas with substantial topography fluctuations. Moreover, the elevation lapse rate of EGS (ELR_EGS) exhibits an opposite trend with growing season (GS) temperature and a similar trend with GS precipitation between the regions below and above 3500 m, ultimately linking to this counteraction. This study underscores elevation is a critical regulator of vegetation EGS responses to climatic changes over the TP, revealing significant spatial heterogeneities in these responses.

How urban heat island magnifies hot day exposure: Global unevenness derived from differences in built landscape.

Urban heat-islands reportedly expose densely populated areas to higher temperatures. However, the magnitude of the impact of extra hot-day exposure (EHDE) and its association with the effects of urbanization on a global scale remain unclear. As local climate zones (LCZs) refine the impact of differences in urban built-type on heat-island effects, this study aimed to quantify the global EHDE caused by the urban heat-island effect based on LCZs and explored the joint impacts of low gross-domestic product and an increasing vulnerable-age population on EHDE. The results showed that EHDE accounted for 48.01 % of overall hot-day exposure. Additionally, despite a significant geographic differentiation among LCZ types with the highest EHDE intensity, they are almost typically building-intensive LCZs. Furthermore, our study revealed regional differences in the structure of the EHDE share in LCZs, which support the adoption of targeted EHDE mitigation strategies.

Emerging Chemodynamic Nanotherapeutics for Cancer Treatment.

Chemodynamic therapy (CDT) has emerged as a transformative paradigm in the realm of reactive oxygen species -mediated cancer therapies, exhibiting its potential as a sophisticated strategy for precise and effective tumor treatment. CDT primarily relies on metal ions and hydrogen peroxide to initiate Fenton or Fenton-like reactions, generating cytotoxic hydroxyl radicals. Its notable advantages in cancer treatment are demonstrated, including tumor specificity, autonomy from external triggers, and a favorable side-effect profile. Recent advancements in nanomedicine are devoted to enhancing CDT, promising a comprehensive optimization of CDT efficacy. This review systematically elucidates cutting-edge achievements in chemodynamic nanotherapeutics, exploring strategies for enhanced Fenton or Fenton-like reactions, improved tumor microenvironment modulation, and precise regulation in energy metabolism. Moreover, a detailed analysis of diverse CDT-mediated combination therapies is provided. Finally, the review concludes with a comprehensive discussion of the prospects and intrinsic challenges to the application of chemodynamic nanotherapeutics in the domain of cancer treatment.

Shared insights for heat health risk adaptation in metropolitan areas of developing countries.

Global warming has led to a surge in heat health risks (HHRs), the impacts of which are particularly pronounced in metropolitan areas of developing countries. In the current study, six metropolitan areas - Beijing, China; Cairo, Egypt; Jakarta, Indonesia; Mumbai, India; Rio de Janeiro, Brazil; and Tehran, Iran - were selected as the study area to further differentiate the built-up landscapes by utilizing the concept of local climate zones. Moreover, we assessed the similarities and differences in HHR associated with the landscape. Results revealed a 30.67% higher HHR in compact built-up landscapes than in the open built-up type. Urban green spaces played an effective but differentiated role in mitigating HHR. That is, low vegetation in urbanized areas and trees in suburban areas significantly mitigated HHR. Collectively, our findings emphasize the role of effective planning and management in addressing HHR and provide empirical support for implementing HHR mitigation and adaptation strategies.

Do development zones increase carbon emission performance of China's cities?

As a special industrial cluster policy, "development zones" (DZs) represent the growth poles of the regions in which they are located; in China, they fulfill the dual tasks of industrial upgrading and green transformation. While the existing literature has paid close attention to the economic effects of development zones, few efforts have been made to examine their climate effects. Therefore, in the context of China's efforts to achieve "carbon peaking and carbon neutrality", this paper for the first time provides evidence of the effect of development zones on urban carbon emission performance; it does this by constructing a difference-in-difference (DID) model, which is based on panel data for Chinese cities in the period 1997-2017. The findings of the study indicate that the establishment of development zones had a positive influence on urban carbon emission performance without time lag effects. Our heterogeneity analysis of city groups indicated that development zones located in eastern region, or in large or coastal cities, exerted a more significant impact. The mechanism analysis that we conducted demonstrates that development zones promote carbon emissions performance by increasing GDP and reducing carbon emissions. Finally, this paper puts forward a series of policy measures, which are intended to strengthen the environmental benefit of development zones within the context of an urban green transition.

Investigating the Corrosive Influence of Chloride Ions on Slag Recovery Machine Shells in Power Plants.

An effective strategy for achieving cost-effective and environmentally friendly desulfurization wastewater in coal-fired power plants involves the incorporation of desulfurization wastewater into the slag water system. The objective of this study was to analyze the corrosion behavior of Q235-A slag-picker shell material upon the introduction of FGD wastewater into the slag water system. The dynamic weight loss method, electrochemical testing method and microscopic phase characterization were employed to investigate the impact of varying chloride ion concentrations (ranging from 1000 mg/L to 30,000 mg/L) of flue gas desulfurization wastewater (FGD wastewater) on the corrosion of Q235-A slag-picker shell material. The test results indicate that as the concentration of chloride ions increases, the corrosion rate increases from 1.1487 mm/a to 1.5590 mm/a when the concentration is less than 10,000 mg/L. However, when the concentration exceeds 10,000 mg/L, the corrosion rate decreases from 1.559 mm/a to 1.0393 mm/a. The corrosion rate is above 1 mm/a at all concentrations. As the Cl- concentration, the quality of the corrosion product film initially increases and then decreases. The primary components of the corrosion product are α- FeOOH, γ-FeOOH, ß-FeOOH, Fe3O4 and γ-Fe2O3.

Deterioration of air quality associated with the 2020 US wildfires.

The wildfires of August and September 2020 in the western part of the United States were characterized by an unparalleled duration and wide geographical coverage. A particular consequence of massive wildfires includes serious health effects due to short and long-term exposure to poor air quality. Using a variety of data sources including aerosol optical depth (AOD) and ultraviolet aerosol index (UVAI), obtained with the Moderate-Resolution Imaging Spectroradiometer (MODIS), Multi-Angle Implementation of Atmospheric Correction (MAIAC) and Tropospheric Monitoring Instrument (TROPOMI), combined with meteorological information from the European Center for Medium-Range Weather Forecasts (ECMWF) and other supporting data, the impact of wildfires on air quality is examined in the three western US states, California, Oregon, and Washington, and areas to the east. The results show that smoke aerosols not only led to a significant deterioration in air quality in these states but also affected all other states, Canada, and surrounding ocean areas. The wildfires increased the average daily surface concentration of PM2.5 posing significant health risks, especially for vulnerable populations. Large amounts of black carbon (BC) aerosols were emitted into the atmosphere. AOD and UVAI exceeded 1 and 2 over most of the country. In parts of the three western states, those values reached 3.7 and 6.6, respectively. Moreover, a reanalysis based on MERRA-2 (Modern-Era Retrospective Analysis for Research and Applications, version 2) showed that the maximum values of BC surface mass concentration during the wildfires were about 370 µg/m3. These various indicators provide a better understanding of the extent of environmental and atmospheric degradation associated with these forest fires.

Patterns and driving forces of the agricultural water footprint of Chinese cities.

The patterns and determinants of different types of agricultural water footprints in China are poorly understood at the prefecture-city level. In this paper, we evaluate Chinese agricultural water footprints from 2000 to 2017 and analyzed their spatio-temporal characteristics. Our estimation results show that the annual average agricultural water footprint in China was 5.038 × 109 m3, and the proportions of green water, blue water, and gray water were 70%, 9%, and 21%, respectively. In addition, high agricultural water-footprint cities with obvious urban agglomeration effects are mainly located in the Northeast, the Huanghuai River, the Yangtze River Basin, and Northwestern of Xinjiang, while low agricultural water-footprint cities are concentrated in high coastal urbanization-level areas or less developed agricultural areas of the west. We also investigate their determinants using a spatio-temporal fixed-effect model and find that GDP per capita, total investment in fixed assets, the income level of rural residents, the proportion of food grown, spray and drip irrigation technology, low-pressure pipe irrigation technology and seepage control irrigation technology have significant positive impacts on the agricultural water footprint. In contrast, the proportion of secondary and tertiary industries, social retail consumption, urbanization, technology expenditure, and the effective irrigation area proportion have a significant inhibitory effect. The primary determinants of the agricultural water footprint also vary substantially across water footprint categories (green, blue, and gray water footprints) and regions. Our findings imply that the agricultural water footprint should be incorporated into city water resource management and monitoring system.

Research on the Measurement of the Coordinated Relationship between Industrialization and Urbanization in the Inland Areas of Large Countries: A Case Study of Sichuan Province.

Industrialization and urbanization are critical paths to modernization for a country or region. The coordination of industrialization and urbanization fosters the development of a regional economy. In academic circles, this is usually measured by the IU ratio (ratio of labor industrialization rate to urbanization rate) and the NU ratio (ratio of non-agricultural employment rate to urbanization rate). However, these methods are inapplicable to large countries' inland areas. The traditional methods failed to explain the real situation and produced contradictory results. The IU ratio shows that industrialization lags behind urbanization, while the NU ratio shows that industrialization is ahead of urbanization. According to studies conducted in the Sichuan Province of China, through comparison with Jiangsu Province, it is found that the non-agricultural employment growth is not dependent on the development of local industrialization, and rural-urban migration is not entirely dependent on the evolution of the non-agricultural employment rate. Other factors that promote urbanization, such as the country's capital policies and funds for migrant labor force transfer, should also be considered. This research attempts to improve the traditional methods for measuring the degree of urbanization and industrialization synergy in inland areas. The new empirical approach can effectively identify the critical characteristics of urbanization in inland provinces, such as the development of non-agricultural employment with external assistance and urban migrants "unrelated to employment opportunities". Based on these key characteristics, it can provide the basis for local urbanization policy formulation.

Eco-Efficiency and Its Drivers in Tourism Sectors with Respect to Carbon Emissions from the Supply Chain: An Integrated EEIO and DEA Approach.

Eco-efficiency analysis can provide useful information about sustainability in the tourism industry, which has an important role in both global economy recovery and Sustainable Development Goals (SDGs), generating considerable indirect carbon emissions with respect to the supply chain due to its significant connections to other industries. This study, from the perspective of tourism sectors, including tourism hotels, travel agencies, and scenic spots, integrated the environmentally extended input-output analysis (EEIO) and data envelopment analysis (DEA) models to develop a research framework, analyzing the indirect carbon emissions of the tourism supply chain, evaluating eco-efficiency with respect to both direct carbon emissions and total carbon emissions (including direct and indirect parts), and exploring the driving factors of eco-efficiency of tourism sectors using Tobit regression models. This study took Gansu as a case, a province in China characterized by higher carbon intensity, an underdeveloped economy, and rapid tourism growth. The results demonstrate that (1) tourism hotels contribute the most carbon emissions in tourism sectors, especially indirectly due to the supply chain, with carbon emissions mainly resulting from the manufacturing of food and tobacco; (2) the eco-efficiency of tourism sectors in Gansu presents a U-shaped curve, which is consistent with Kuznets' theory; and (3) energy technology is key to improving the eco-efficiency of tourism sectors. The research results provide a clear path for the reduction of carbon emissions and the improvement of eco-efficiency in Gansu tourism sectors. Against the backdrop of global climate change and the post-COVID-19 era, our research framework and findings provide a reference for similar regions and countries who are in urgent need of rapid tourism development to effect economic recovery.

Warming and cooling effects of local climate zones on urban thermal environment.

Understanding the thermal characteristics and contribution ranking of local climate zones (LCZs) is essential since they can help in maintaining environmental harmony. However, previous studies only considered independent effects and could not analyze the combined effects of LCZ on land surface temperature (LST). In this study, we propose a new method to establish an interaction model between LCZs. Five first-level grids with different scales from 270 to 990 m were established to calculate the area proportion of LCZ. The area proportion of LCZ was then applied in the stepwise regression model to quantitatively analyze its magnitude and direction of impact on the LST. The results suggest that the LCZ types of the study area with the highest and lowest average LST were LCZ2 (compact middle-rise building, 39.82°C) and LCZG (water body, 34.24°C), respectively. However, on most scales, the warming effect of LCZ2 was lower than that of LCZE (bare rock or paver), and the cooling effect of LCZG was lower than that of LCZD (low plants). The optimum results were obtained at a scale of 810 m. At this scale, the warming effect was in the order: LCZE (0.314) > LCZ2 (0.236) > LCZ3 (compact low-rise building, 0.135) > LCZ5 (open middle-rise, 0.084) > LCZ6 (open low-rise, 0.056); the cooling effect was in the order: LCZD (-0.272) > LCZA (dense trees, -0.104) > LCZG (-0.103). These findings can help to elucidate the unique warming and cooling effects of LCZ on the interaction condition and the construction of an urban human settlement.

Prediction of the potential geographical distribution of Betula platyphylla Suk. in China under climate change scenarios.

Climate is a dominant factor affecting the potential geographical distribution of species. Understanding the impact of climate change on the potential geographic distribution of species, which is of great significance to the exploitation, utilization, and protection of resources, as well as ecologically sustainable development. Betula platyphylla Suk. is one of the most widely distributed temperate deciduous tree species in East Asia and has important economic and ecological value. Based on 231 species distribution data points of Betula platyphylla Suk. in China and 37 bioclimatic, soil, and topography variables (with correlation coefficients < 0.75), the potential geographical distribution pattern of Betula platyphylla Suk. under Representative Concentration Pathway (RCP) climate change scenarios at present and in the 2050s and 2070s was predicted using the MaxEnt model. We analyzed the main environmental variables affecting the distribution and change of suitable areas and compared the scope and change of suitable areas under different climate scenarios. This study found: (1) At present, the main suitable area for Betula platyphylla Suk. extends from northeastern to southwestern China, with the periphery area showing fragmented distribution. (2) Annual precipitation, precipitation of the warmest quarter, mean temperature of the warmest quarter, annual mean temperature, and precipitation of the driest month are the dominant environmental variables that affect the potential geographical distribution of Betula platyphylla Suk. (3) The suitable area for Betula platyphylla Suk. is expected to expand under global warming scenarios. In recent years, due to the impact of diseases and insect infestation, and environmental damage, the natural Betula platyphylla Suk. forest in China has gradually narrowed. This study accurately predicted the potential geographical distribution of Betula platyphylla Suk. under current and future climate change scenarios, which can provide the scientific basis for the cultivation, management, and sustainable utilization of Betula platyphylla Suk. resources.

Transport accessibility and social demand: A case study of the Tibetan Plateau.

The equity of transport accessibility is a prerequisite for sustainable development targets, especially in the ecologically fragile area of the Tibetan Plateau (also known as the Qinghai-Tibet Plateau). The relationship between transportation supply and social demand has become a key element of socioeconomic development and environmental protection in agricultural and pastoral areas. Based on data from transportation networks, permanent populations and the economy, this study uses a network analysis model, the coefficient of variation and the Gini coefficient to construct an index of social demand in townships and analyse the equity of transport accessibility on the Tibetan Plateau between 1980 and 2017; the principle of geographic distribution and the spatial relationship between transport accessibility and social demand at the township scale are also discussed. This study finds the following: the development of transportation has improved accessibility on the Tibetan Plateau, creating a highly accessible region with important cities as the nodes and major traffic arteries as the axes; both the coefficient of variation of transport accessibility and the Gini coefficient have increased slightly; and the equity of transport accessibility among townships on the Tibetan Plateau has exhibited a downward trend. Further, the social demand index is doubling every ten years, the spatial distribution has regional characteristics, and a decrease in permanent populations is the main reason for declining social demand index scores among townships. Townships with the lowest and highest social demand index scores for transportation development enjoy greater transportation benefits; there is a significant spatial relationship between social demand and location conditions (potential accessibility); the aggregation of social demand and accessibility types follows specific geographical distribution principles; and the Mangya-Gongshan Line delineates the distribution characteristics of township clusters with low social demand and low accessibility.

Identification and analysis of urban functional area in Hangzhou based on OSM and POI data.

The accurate identification of urban functional areas is of great significance for optimizing urban spatial structure, rationally allocating spatial elements, and promoting the sustainable development of the city. This paper proposes a method to precisely identify urban functional areas by coupling Open Street Map (OSM) and Point of Interest (POI) data. It takes the central urban area of Hangzhou as a case study to analyze the spatial distribution characteristics of the functional areas. The results show that: (1) The central urban areas of Hangzhou are divided into 21 functional areas (6 single functional areas, 14 mixed functional areas and 1 comprehensive functional area). (2) The single functional areas and the mixed functional areas show the geographical distribution characteristics of the looping stratification, which means "Core-periphery" differentiation is obvious, and the comprehensive functional area is relatively scattered. (3) The mixed degree of regional function with ecological function and production function is low while comprehensive functional areas are usually associated with higher potential and vitality. (4) The identification results are in great agreement with the actual situation of Hangzhou central urban area, and the method is feasible. Therefore, this paper can provide a reference for urban development planning and management.

Intensifier of urban economic resilience: Specialized or diversified agglomeration?

With increased uncertainty and instability worldwide, how to enhance the urban economy resilience effectively has become one main issue for urban economic development. Based on the measurement of the economic resilience of 241 cities at the prefecture level and above in China using the sensitive index method, we scrutinize the impact of industrial specialization agglomeration and diversification agglomeration on urban economic resilience. Results indicate that, during the impact resistance period, industrial diversification agglomeration, especially related industrial diversification agglomeration, can enhance urban economic resilience, whereas industrial specialization agglomeration has no positive effect. In contrast, during the period of recovery and adjustment, industrial specialization agglomeration can improve urban economic resilience, and industrial diversification agglomeration, especially related industrial diversification agglomeration, has no positive effect. Further analysis indicates that, under the interaction of specialization and diversification agglomerations, the effect of industrial agglomeration on urban economic resilience depends on the type of dual industrial agglomeration, showing remarkable heterogeneity. This study may provide useful references for policy makers concerned with urban resilience.

Evolution Characters and Influencing Factors of Regional Eco-Efficiency in a Developing Country: Evidence from Mongolia.

The sandstorm in 2021 in East Asia demonstrated the ecological issues that culminated for decades in Mongolia. Mongolia is facing challenges to realize green and sustainable development. This article aims to increase the understanding of eco-efficiency and its influencing factors in Mongolia and to provide a reference for similar developing countries and regions to achieve green and sustainable development. This article used the Slacks-Based Measure of Efficiency (SBM) model with advantages of dimension freedom and unit variable to estimate the economic efficiency and eco-efficiency of 22 provinces in Mongolia from 2007 to 2016; energy consumption and undesirable environmental outputs were taken as ecological/environmental indicators in the input and output system of regional eco-efficiency in Mongolia, combining traditional indicators of economic efficiency to build Mongolia's eco-efficiency input-output framework. This article applied hot spot analysis and gravity center analysis to reveal the temporal and spatial evolution characters of eco-efficiency in Mongolia. Finally, the article applied panel Tobit regression to analyze the influencing factors of eco-efficiency. We were found that Mongolia's eco-efficiency slightly improved from 0.7379 in 2007 to 0.7673 in 2016, lower than the economic efficiency. The high eco-efficiency provinces appeared in the capital Ulaanbaatar and its surrounding areas, showing an obvious spatial spillover effect. The low eco-efficiency provinces were mainly in the undeveloped western region. The relationship between per capita GDP and eco-efficiency was U-shaped and consistent with environmental Kuznets theory. Accelerating economic growth, optimizing population distribution, and improving energy structure and green technology can improve Mongolia's eco-efficiency.

Recovering chemical sludge from the zero liquid discharge system of flue gas desulfurization wastewater as flame retardants by a stepwise precipitation process.

In this study, a five-stage stepwise precipitation process, including pre-sedimentation, magnesium removal, gypsum precipitation, ettringite precipitation and calcium removal, was proposed as a softening pretreatment for zero liquid discharge system for flue gas desulfurization wastewater. Batch tests and long-term bench-scale experiment showed that magnesium, sulfate and calcium were efficiently removed with efficiencies all above 98.0%, leaving a clean effluent majorly containing NaCl and NaOH. The precipitated CaSO4, CaCO3, Mg(OH)2 and ettringite were completely separated by stepwise precipitation, and the purity of Mg(OH)2 and ettringite were further enhanced by washing and soaking treatment. CaSO4 and CaCO3 can be directly recycled as gypsum product and desulfurizing agent within the power plant, while Mg(OH)2 and ettringite presented proper particle size and excellent thermal properties as a synergistic flame retardant. The flame retardancy of ethylene vinyl acetate copolymer were greatly improved when blended with recovered Mg(OH)2 and ettringite, and possessed better performance by blending them together because ettringite could act as a dispersing and compatible agent of Mg(OH)2, and relieve the intensity of smoke releasing. Chemical sludge recovery compensates the total cost of the five-stage process by 45.0%, and makes the process technically versatile, economically beneficial and environmentally friendly without solid waste production.

A two-stage desalination process for zero liquid discharge of flue gas desulfurization wastewater by chloride precipitation.

A two-stage desalination process was developed to achieve zero liquid discharge (ZLD) of flue gas desulfurization (FGD) wastewater by precipitating chloride as Friedel's salt. Influential factors for Friedel's salt precipitation, including dosage, reaction time, concentration of sulfate, were investigate by batch tests. Batch results showed that at calcium to aluminum molar ratio of 3.0, the optimal chloride removal and the highest crystallinity of Friedel's salt were obtained. Sulfate impeded Friedel's salt precipitation by competitive inhibition mechanism, and thus calcium sulfate removal was designed in advance of chloride removal. Batch results and long-term results of bench-scale experiments showed that magnesium and part of sulfate were effectively removed by lime addition in Stage I of the proposed process, and then the remaining sulfate and 48.1 % of chloride were precipitated as ettringite and Friedel's salt in Stage II. The effluent of the two-stage process was alkaline with low turbidity, and had considerable desulfurization capacity. Techno-economic evaluation showed that the two-stage process is technically feasible, economically viable and environmentally friendly technology for ZLD of FGD wastewater.