An Anthocyanin-Based Eco-Friendly Triboelectric Nanogenerator for pH Monitoring and Energy Harvesting.

In recent years, renewable and sustainable triboelectric nanogenerators have attracted attention due to their high energy conversion rate, and enhancing their functionality further contributes to their applicability across various fields. A pH-sensitive triboelectric nanogenerator (pH-TENG) has been prepared by electrostatic spinning technology, with anthocyanin as the pH indicator and environmentally friendly polyvinyl alcohol (PVA) as the substrate. Among many friction-negative materials, the pH-TENG exhibits the best combination with fluorinated ethylene propylene (FEP) and yields an open-circuit voltage of 62 V, a short-circuit current of 370 nA, and a transferred charge of 21.8 nC. At a frequency of 3 Hz, it can charge a 4.7 µF capacitor to 2 V within 45 s, effectively powering a thermometer. Furthermore, the presence of anthocyanin does not affect the pH-TENG's power generation performance and enables the monitoring of a wide range of environmental pH changes, with an ΔE change of 28.8 ± 7.6. Therefore, pH-TENG prepared with environmentally friendly materials can bring new available materials to the biological and medical fields.

A noval transparent triboelectric nanogenerator as electronic skin for real-time breath monitoring.

Against the backdrop of advancements in modern multifunctional wearable electronics, there is a growing demand for simple, sustainable, and portable electronic skin (e-skin), posing significant challenges. This study aims to delineate the development of a straightforward, transparent, highly sensitive, and high power-density electronic skin based on a triboelectric nanogenerator(S-TENG), designed for harvesting human body energy and real-time monitoring of the physiological motion status. Our e-skin incorporates thermally treated polyvinylidene fluoride (PVDF) fiber membranes as the contact layer and a film of silver nanowires as the conductive electrodes. The resulting contact-separation type e-skin exhibits an impressive transparency of 80 %, along with a nice sensitivity value, capable of detecting a light touch from a 0.13 g sponge and demonstrating good working stability and breathability. Leveraging the triboelectric effect, our e-skin generates an open-circuit voltage of 301 V and a short-circuit current of 2.7 µA under an extrinsic force of 8 N over an interaction area of 4 × 4 cm2, achieving a power density up to 306 mW/m2. With its signal processing circuitry, the integrated S-TENG showcases nice energy harvesting and signal transmission capabilities. Accordingly, we contend that S-TENG has potential applications in energy capture and real-time human motion state monitoring. This research is anticipated to blaze a novel and practical trail for self-powered wearable devices and personalized health rehabilitation training regimens.

A Study on the Mechanisms and Performance of a Polyvinyl Alcohol-Based Nanogenerator Based on the Triboelectric Effect.

Polyvinyl alcohol (PVA), a versatile polymer, is extensively used across many industries, such as chemicals, food, healthcare, textiles, and packaging. However, research on applying PVA to triboelectric nanogenerators (TENGs) remains limited. Consequently, we chose PVA as the primary material to explore its contact electrification mechanisms at the molecular level, alongside materials like Polyethylene (PE), Polyvinylidene fluoride (PVDF), and Polytetrafluoroethylene (PTFE). Our findings show that PVA has the highest band gap, with the smallest band gap occurring between the HOMO of PVA and the LUMO of PTFE. During molecular contact, electron transfer primarily occurs in the outermost layers of the molecules, influenced by the functional groups of the polymers. The presence of fluorine atoms enhances the electron transfer between PVA and PTFE to maximum levels. Experimental validation confirmed that PVA and PTFE contact yields the highest triboelectric performance: VOC of 128 V, ISC of 2.83 µA, QSC of 82 nC, and an output power of 384 µW. Moreover, P-TENG, made of PVA and PTFE, was successfully applied in self-powered smart devices and monitored human respiration and bodily movements effectively. These findings offer valuable insights into using PVA in triboelectric nanogenerator technologies.

Bio-inspired e-skin with integrated antifouling and comfortable wearing for self-powered motion monitoring and ultra-long-range human-machine interaction.

Electronic skin (e-skin) inspired by the sensory function of the skin demonstrates broad application prospects in health, medicine, and human-machine interaction. Herein, we developed a self-powered all-fiber bio-inspired e-skin (AFBI E-skin) that integrated functions of antifouling, antibacterial, biocompatibility and breathability. AFBI E-skin was composed of three layers of electrospun nanofibrous films. The superhydrophobic outer layer Poly(vinylidene fluoride)-silica nanofibrous films (PVDF-SiO2 NFs) possessed antifouling properties against common liquids in daily life and resisted bacterial adhesion. The polyaniline nanofibrous films (PANI NFs) were used as the electrode layer, and it had strong "static" antibacterial capability. Meanwhile, the inner layer Polylactic acid nanofibrous films (PLA NFs) served as a biocompatible substrate. Based on the triboelectric nanogenerator principle, AFBI E-skin not only enabled self-powered sensing but also utilized the generated electrical stimulation for "dynamic" antibacterial. The "dynamic-static" synergistic antibacterial strategy greatly enhanced the antibacterial effect. AFBI E-skin could be used for self-powered motion monitoring to obtain a stable signal output even when water was splashed on its surface. Finally, based on AFBI E-skin, we constructed an ultra-long-range human-machine interaction control system, enabling synchronized hand gestures between human hand and robotic hand in any internet-covered area worldwide theoretically. AFBI E-skin exhibited vast application potential in fields like smart wearable electronics and intelligent robotics.

In-situ amino-functionalized and reduced graphene oxide/polyimide composite films for high-performance triboelectric nanogenerator.

As a promising sustainable power source in intelligent electronics, Triboelectric Nanogenerators (TENGs) have garnered widespread interest, with various strategies explored to enhance their output performance. However, most optimization methods for triboelectric materials have focused solely on tuning chemical compositions or fabricating surface microstructures. Here, we have prepared amino-functionalized reduced graphene oxide (FRGO)/polyimide (PI) composite films (PI-FRGO) via in-situ polymerization, aimed at enhancing PI materials' nanotribological power generation performance. By varying the doping levels of amino groups and controlling the FRGO proportion during synthesis, we can explore the optimal FRGO/PI composite film ratio. At a p-Phenylenediamine: reduced Graphene Oxide (PPDA: RGO) ratio of 1:1 and an FRGO addition of 0.1 %, the output electrical performance peaks with a voltage of 58 V, a charge of 33 nC and a current of 12 µA, nearly 2 times that of a pure PI film. We have fabricated a TENG with an optimally formulated PI-FRGO composite to explore its application potential. Under a 10 MΩ external load resistance, the TENG can deliver a power density of 3.5 mW/m2 and can be powering small devices. This work presents new effective strategies to significantly enhance TENG output performance and promote their widespread application.

Multiangle, self-powered sensor array for monitoring head impacts.

Mild concussions occur frequently and may come with long-term cognitive, affective, and physical sequelae. However, the diagnosis of mild concussions lacks objective assessment and portable monitoring techniques. Here, we propose a multiangle self-powered sensor array for real-time monitoring of head impact to further assist in clinical analysis and prevention of mild concussions. The array uses triboelectric nanogenerator technology, which converts impact force from multiple directions into electrical signals. With an average sensitivity of 0.214 volts per kilopascal, a response time of 30 milliseconds, and a minimum resolution of 1.415 kilopascals, the sensors exhibit excellent sensing capability over a range of 0 to 200 kilopascals. Furthermore, the array enables reconstructed head impact mapping and injury grade assessment via a prewarning system. By gathering standardized data, we expect to build a big data platform that will permit in-depth research of the direct and indirect effects between head impacts and mild concussions in the future.

Poly-l-lactic acid (PLLA)/anthocyanin nanofiber color indicator film for headspace detection of low-level bacterial concentration.

Since bacterial contamination is a significant threat to humans, early detection is essential to safeguard dietary safety and physical health. Here, a nanofiber color indicator film based on poly-l-lactic acid (PLLA) as the support and anthocyanin as the indicator material was prepared by electrostatic spinning. It was found that the PLLA/0.8CY nanofiber color indicator film was hydrophobic (the water contact angle of 102.4°) and contained uniform nanofibers with an average diameter of 750 nm. In addition, the film's humidity insensitivity, reusability, color stability, and ammonia sensitivity (the limits of detection 35.39 ppm) made the film environmentally friendly and more accurate and faster for bacterial detection. The film was able to sense 102 CFU/mL of gram-positive and negative bacteria after the model strain E. coli and L. monocytogene. Thus, the PLLA/0.8CY nanofiber color indicator film was able to perform headspace nondestructive detection of low-level bacterial contamination.

Multi-responsive poly N-isopropylacrylamide/poly N-tert-butylacrylamide nanocomposite hydrogel with the ability to be adsorbed on the chitosan film as an active antibacterial material.

Nanocomposite hydrogel composed of Poly N-isopropylacrylamide (PNIPAM), poly N-tert-Butylacrylamide (PBAM) and poly acrylic acid (PAA) was synthesized by free radical polymerization, and then thymol was embedded in it, to design an active antibacterial material that could control release. The characterization of products used SEM, AFM, FTIR, Zeta sizer to analyze the sensitivity of nanoparticles to pH, temperature and salt ions, and the agar diffusion method was used to determine the antibacterial effect of the polymers. The results showed that nanoparticles had pH, temperature and salt ion responsiveness, PNIPAM/PBAM (65:35) nanoparticles loaded thymol had longer release time (more than 24 h) at lower temperature than that (around 6 h) at high temperature. In addition, the nanoparticles could also be adsorbed on the chitosan film, which makes it have a wider range of applications. All thymol-loaded nanoparticles showed antibacterial activity against both B. subtilis and E. coli, while the chitosan film adsorbed nanoparticles showed weak effect, which was related to the controlled and slow release of bacteriostatic agents. Thus, these copolymers have potential value in the development and application of bacteriostatic packaging films for food.