RESUMO
Starch and cellulose are among the best known renewable reinforcing components. Scientists are continuously looking for various renewable sources such as flax, hemp, jute, and corn hulls with polymer matrixes to form composite materials and make structural biocomposites a reality. Wheat is a major cereal grain in the US and the world. During wheat milling, a large amount of wheat bran, a by-product, is disposed off as waste. The high percentage of water-insoluble fiber in wheat bran could be advantageous for reinforcing industrial material. However, the utilization of cellulosic fibers derived from wheat byproduct has not been explored in processing of biocomposites. Therefore, the objectives of this study were to characterize wheat bran fiber compositions including dry matter (DM), ash, crude protein (CP), neutral detergent fiber (NDF), acid detergent fiber (ADF), cellulose (Cell), hemicellulose (Hemi), calcium (Ca), fat, starch, and acid detergent lignin (ADL); identify the interrelationship between the fiber composition traits and the influence of the environment and genotype on these traits. The experiment included six diverse and popular hard red spring wheat (HRSW) cultivars commonly grown in spring wheat region of the Northern Plains of USA. The experiment was installed in three different environments in the Dakotas States, USA. Results from this study showed that the DM, ash, Ca, Cell, starch, and ADL contents were influenced mainly by environments. However, CP along with fat, ash and Ca contents were influenced by genotypes in addition to environment. All bran components were influenced by the genotype × environment (G × E) interactions. We observed significant negative correlation of Cell with CP and ADL which make wheat bran a suitable reinforcing industrial material. However surface treatment of bran fiber would make it even more efficient. These preliminary results indicate the potential use of wheat bran components as biocomposite, but further studies to elucidate more these finding are warranted.
RESUMO
Polypropylene (PP) composites reinforced using a novel plant fiber, sunflower hull sanding dust (SHSD), were prepared using a twin-screw extruder. Thermal and mechanical properties of the SHSD/PP composites were characterized and compared to an organically modified clay (organo-clay)/PP composite. Differential scanning calorimetry (DSC) analysis showed that the crystallization temperature and the degree of crystallinity of PP exhibited changes with addition of SHSD and organo-clay. Mechanical properties of the PP were enhanced with the addition of SHSDs. Both the flexural strength and flexural modulus of the PP composites containing 5% (w/w) SHSD were comparable to that of the 5% (w/w) organo-clay reinforced PP. Scanning electron microscope (SEM) observation showed that no obvious agglomeration of SHSD existed in the PP matrix. Compared to the neat PP and organo-clay/PP, the SHSD/PP composites exhibited a relatively decreasing rate of thermal degradation with increase in temperature. Experimental results suggest that SHSD, as a sunflower processing byproduct, may find promising applications in composite materials.