1.
Acta Crystallogr Sect E Struct Rep Online
; 65(Pt 2): m225, 2009 Jan 23.
Artigo
em Inglês
| MEDLINE
| ID: mdl-21581816
RESUMO
In the title compound, [Ni(C(22)H(17)BrN(2)O(4))]·CH(3)OH, the Ni(II) ion is in a slightly distorted square-planar geometry involving an N(2)O(2) atom set of the tetra-dentate Schiff base ligand. The asymmetric unit contains one nickel complex and one methanol solvent mol-ecule. The dihedral angle between the aromatic ring planes of the central aromatic ring and other two aromatic rings are 10.8â (3) and 6.0â (2)°. The crystal structure is stabilized by inter-molecular C-Hâ¯O and C-Hâ¯Br and by intra-molecular O-Hâ¯O hydrogen bonds.