Capillary interactions between soft capsules protruding through thin fluid films.

When a suspension dries, the suspending fluid evaporates, leaving behind a dry film composed of the suspended particles. During the final stages of drying, the height of the fluid film on the substrate drops below the particle size, inducing local interface deformations that lead to strong capillary interactions among the particles. Although capillary interactions between rigid particles are well studied, much is still to be understood about the behaviour of soft particles and the role of their softness during the final stages of film drying. Here, we use our recently-introduced numerical method that couples a fluid described using the lattice Boltzmann approach to a finite element description of deformable objects to investigate the drying process of a film with suspended soft particles. Our measured menisci deformations and lateral capillary forces, which agree well with previous theoretical and experimental works in case of rigid particles, show that the deformations become smaller with increasing particle softness, resulting in weaker lateral interaction forces. At large interparticle distances, the force approaches that of rigid particles. Finally, we investigate the time dependent formation of particle clusters at the late stages of the film drying.

Mesoscale simulation of soft particles with tunable contact angle in multicomponent fluids.

Soft particles at fluid interfaces play an important role in many aspects of our daily life, such as the food industry, paints and coatings, and medical applications. Analytical methods are not capable of describing the emergent effects of the complex dynamics of suspensions of many soft particles, whereas experiments typically either only capture bulk properties or require invasive methods. Computational methods are therefore a great tool to complement experimental work. However, an efficient and versatile numerical method is needed to model dense suspensions of many soft particles. In this article we propose a method to simulate soft particles in a multicomponent fluid, both at and near fluid-fluid interfaces, based on the lattice Boltzmann method, and characterize the error stemming from the fluid-structure coupling for the particle equilibrium shape when adsorbed onto a fluid-fluid interface. Furthermore, we characterize the influence of the preferential contact angle of the particle surface and the particle softness on the vertical displacement of the center of mass relative to the fluid interface. Finally, we demonstrate the capability of our model by simulating a soft capsule adsorbing onto a fluid-fluid interface with a shear flow parallel to the interface, and the covering of a droplet suspended in another fluid by soft particles with different wettability.