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As an important computer vision technique, image segmentation has been widely used in various tasks. However, in some extreme cases, the insufficient illumination would result in a great impact on the performance of the model. So more and more fully supervised methods use multi-modal images as their input. The dense annotated large datasets are difficult to obtain, but the few-shot methods still can have satisfactory results with few pixel-annotated samples. Therefore, we propose the Visible-Depth-Thermal (three-modal) images few-shot semantic segmentation method. It utilizes the homogeneous information of three-modal images and the complementary information of different modal images, which can improve the performance of few-shot segmentation tasks. We constructed a novel indoor dataset VDT-2048-5i for the three-modal images few-shot semantic segmentation task. We also proposed a Self-Enhanced Mixed Attention Network (SEMANet), which consists of a Self-Enhanced module (SE) and a Mixed Attention module (MA). The SE module amplifies the difference between the different kinds of features and strengthens the weak connection for the foreground features. The MA module fuses the three-modal feature to obtain a better feature. Compared with the most advanced methods before, our model improves mIoU by 3.8% and 3.3% in 1-shot and 5-shot settings, respectively, which achieves state-of-the-art performance. In the future, we will solve failure cases by obtaining more discriminative and robust feature representations, and explore achieving high performance with fewer parameters and computational costs.
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A practical strategy for the synthesis of spiro[5.5]trienones-fused selenocyanates and spiro[4.5]trienones-fused selenocyanates through electrophilic selenocyanogen cyclization and dearomative spirocyclization is reported. This approach was conducted under mild conditions with broad substrate scope and good functional group tolerance. The utility of this procedure is exhibited in the late-stage functionalization of nature product and drug molecules.
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Compostos de Espiro , Cianatos , Ciclização , Estrutura Molecular , Compostos de Selênio , Compostos de Espiro/químicaRESUMO
Here, a novel Z-scheme MoS2/Ag2CO3 heterojunction photocatalyst was assembled from two-dimensional MoS2 nanosheets and Ag2CO3 nanoparticles through facile hydrothermal and in-situ precipitation method. The MoS2/Ag2CO3 heterojunction exhibited much enhanced visible-light photocatalytic performance in probe experiment for organic pollutants degradation and Escherichia coli (E. coli) inactivation compared to pristine Ag2CO3 and MoS2. The degradation rates of Lanasol Red 5B, rhodamine B, ciprofloxacin, and metronidazole reached 95%, 90%, 80%, and 72%, respectively. On the other hand, E. coli was completely inactivated in 80â¯min in the presence of 5%-MoS2/Ag2CO3. The improved photocatalytic performance was ascribed to the enhanced photogenerated charge separation efficiency and increased lifetime of the charge carriers, proved by photoluminescence spectra, time-resolved fluorescence emission decay spectra, and electrochemical measures. In addition, the active species trapping and ESR experiments all indicated that holes (h+) exhibited a significant contribution and superoxide radicals (O2-) acted as assistants. Based on experiment results, the photocatalytic enhancement mechanism for organic pollutants degradation and E. coli inactivation was discussed. The effect of representative environmental factors on the degradation of Lanasol Red 5B was investigated. The experiment results indicated that the degradation efficiency was partially influenced in the presence of inorganic salt. Furthermore, the appearance of a small amount of Ag nanoparticles not only enhanced the charge transfer, but also improved the stability of photocatalyst. Overall, MoS2/Ag2CO3 heterojunction has a great application potential for future water purification.
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Poluentes Ambientais , Nanopartículas Metálicas , Bismuto , Catálise , Escherichia coli , Molibdênio , PrataRESUMO
BACKGROUND: Numerous reports have shown that rigid spinal fixation contributes to a series of unwanted complications in lumbar fusion procedure. This innovative micro-dynamic pedicle screw study was designed to investigate the biomechanical performance of lumbar implants using numerical simulation technique and biomechanical experiment. METHODS: Instrumented finite element models of three configurations (dynamic fixation, rigid fixation and hybrid fixation) using a functional L3-L4 lumbar unit were developed, to compare the range of motion of the lumbar spine and stress values on the endplate and implants. An in vitro experiment was simultaneously conducted using 18 intact porcine lumbar spines and segmental motion analyses were performed as well. RESULTS: Simulation results indicated that the dynamic fixation and the hybrid fixation models respectively increased the range of motion of the lumbar spine by 95 and 60% in flexion and by 83 and 55% in extension, compared with the rigid fixation model. The use of micro-dynamic pedicle screw led to higher stress on endplates and lower stress on pedicle screws. The outcome of the in vitro experiment demonstrated that the micro-dynamic pedicle screw could provide better range of motion at the instrumented segments than a rigid fixation. CONCLUSION: The micro-dynamic pedicle screw has the advantage of providing better range of motion than conventional pedicle screw in flexion-extension, without compromising stabilization, and has the potential of bringing the load transfer behavior of fusional segment closer to normal and also lowers the stress values of pedicle screws.
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Vértebras Lombares/fisiologia , Vértebras Lombares/cirurgia , Parafusos Pediculares , Amplitude de Movimento Articular/fisiologia , Fusão Vertebral/instrumentação , Animais , Fenômenos Biomecânicos/fisiologia , Parafusos Pediculares/normas , Distribuição Aleatória , Fusão Vertebral/métodos , Fusão Vertebral/normas , SuínosRESUMO
Extracting horizontal planes in heavily cluttered three-dimensional (3D) scenes is an essential procedure for many robotic applications. Aiming at the limitations of general plane segmentation methods on this subject, we present HoPE, a Horizontal Plane Extractor that is able to extract multiple horizontal planes in cluttered scenes with both organized and unorganized 3D point clouds. It transforms the source point cloud in the first stage to the reference coordinate frame using the sensor orientation acquired either by pre-calibration or an inertial measurement unit, thereby leveraging the inner structure of the transformed point cloud to ease the subsequent processes that use two concise thresholds for producing the results. A revised region growing algorithm named Z clustering and a principal component analysis (PCA)-based approach are presented for point clustering and refinement, respectively. Furthermore, we provide a nearest neighbor plane matching (NNPM) strategy to preserve the identities of extracted planes across successive sequences. Qualitative and quantitative evaluations of both real and synthetic scenes demonstrate that our approach outperforms several state-of-the-art methods under challenging circumstances, in terms of robustness to clutter, accuracy, and efficiency. We make our algorithm an off-the-shelf toolbox which is publicly available.
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L-Ascorbic acid, α-tocopherol, procyanidin B3, ß-carotene and astaxanthin are five classic dietary antioxidants. In this study, the interaction between the five antioxidants and ovalbumin was investigated by fluorescence spectroscopy, in combination with UV-vis absorption spectroscopy and circular dichroism (CD) spectroscopy. The quenching mechanism of ovalbumin by α-tocopherol is static quenching and the interaction between α-tocopherol and ovalbumin is synergistically driven by enthalpy and entropy. Electrostatic interactions and hydrophobic interactions play a major role in stabilizing the complex. For the other four antioxidants, the quenching mechanisms are all static quenching mechanisms at lower concentrations of antioxidants, but at higher concentrations of antioxidants, predominantly by the "sphere of action" quenching mechanisms. The binding processes of the other four antioxidants to ovalbumin are all entropy process and the major part of the action force is hydrophobic interactions. The binding constants of ovalbumin with the five antioxidants are in the following order as: astaxanthin > ß-carotene > L-ascorbic acid > procyanidin B3 > α-tocopherol at 298 K. Synchronous fluorescence spectroscopy shows the interaction between L-ascorbic acid/ß-carotene/astaxanthin and ovalbumin decreases the hydrophobicity of the microenvironment of tryptophan (Trp) and tyrosine (Tyr) residues. The hydrophobicity of Trp is increased while the hydrophility of Tyr is increased in the presence of α-tocopherol. However, the microenvironment of Trp and Tyr is not affected by procyanidin B3. The UV-vis absorption and CD spectra suggest that the interaction between the five antioxidants and ovalbumin leads to the loosening and unfolding of ovalbumin skeleton and exerts some influence on the natural secondary structure of ovalbumin. The study provides an accurate and full basic data for clarifying the binding mechanisms of L-ascorbic acid, α-tocopherol, procyanidin B3, ß-carotene and astaxanthin interacting with ovalbumin and is helpful for understanding rational use of antioxidants as dietary supplements.
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Ácido Ascórbico/metabolismo , Biflavonoides/metabolismo , Catequina/metabolismo , Ovalbumina/metabolismo , Proantocianidinas/metabolismo , Espectrometria de Fluorescência/métodos , alfa-Tocoferol/metabolismo , beta Caroteno/metabolismo , Animais , Antioxidantes/química , Antioxidantes/metabolismo , Ácido Ascórbico/química , Biflavonoides/química , Sítios de Ligação , Catequina/química , Dicroísmo Circular , Humanos , Ovalbumina/química , Proantocianidinas/química , Ligação Proteica , Termodinâmica , Xantofilas/química , Xantofilas/metabolismo , alfa-Tocoferol/química , beta Caroteno/químicaRESUMO
The structure and surface physicochemical properties of anode play a crucial role in microbial fuel cells (MFCs). To enhance the enrichment of exoelectrogen and facilitate extracellular electron transfer (EET), a three-dimensional macroporous graphene aerogel with polydopamine coating was successfully introduced to modify carbon brush (PGA/CB). The three-dimensional graphene aerogel (GA) with micrometer pores improved the space utilization efficiency of microorganisms. Polydopamine (PDA) coating enhanced the physicochemical properties of the electrode surface by introducing abundant functional groups and nitrogen-containing active sites. MFCs equipped with PGA/CB anodes (PGA/CB-MFCs) demonstrated superior power generation compared to GA/CB-MFCs and CB-MFCs (MFCs with GA/CB and CB anodes respectively), including a 23.0 % and 30.1 % reduction in start-up time, and an increase in maximum power density by 2.43 and 1.24 times respectively. The higher bioelectrochemical activity exhibited by the biofilm of PGA/CB anode and the promoted riboflavin secretion by PGA modification imply the enhanced EET efficiency. 16S rRNA high-throughput sequence analysis of the biofilms revealed successful enrichment of Geobacter on PGA/CB anodes. These findings not only validate the positive impact of the synergistic effects between GA and PDA in promoting EET and improving MFC performance but also provide valuable insights for electrode design in other bioelectrochemical systems.
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Polydopamine has gained considerable attention in the biomaterial domain owing to its excellent biocompatibility, antioxidant activity, photothermal effect and adhesion property. Herein, copper sulfide (Cu2-xS) wrapped in mesoporous polydopamine (MPDA) was synthesized through in-situ polymerization, followed by the surface modification with cationic polyethyleneimine (PEI). The mussel-inspired MPDA matrix successfully prevented the oxidation and agglomeration of Cu2-xS nanoparticles, and regulated the release of copper ions and reactive oxygen species (ROS) levels. Surface-modified PEI endow MPDA@Cu2-xS with positive charges, facilitating their rapid contact with negatively charged bacteria through electrostatic interactions. The pH-dependent Cu+/Cu2+ release and NIR-responsive ROS generation were confirmed using molecular probes and electron spin resonance (ESR). The MPDA@Cu2-xS/PEI showed significantly enhanced antibacterial activity and reduced cytotoxicity for NIH3T3 cells. Under NIR irradiation (1.0 W/cm2, 10 min), germicidal efficiency against Escherichia coli (E. coli) and Staphyloccocus aureus (S. aureus) could reach 100 % and 99.94 %, respectively. The exceptional antibacterial activities of MPDA@Cu2-xS/PEI was mainly attributed to the synergistic photothermal effect, controlled release of copper ions and ROS generation, as well as electrostatic interaction. More importantly, the MPDA@Cu2-xS/PEI composite exhibited excellent biocompatibility and biosafety. Overall, this organic/inorganic hybrid holds great potential as a promising candidate for wound treatment.
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Anode material and surface properties have a crucial impact on the performance of MFCs. Designing and fabricating various modified carbon-based anodes with functional materials is an effective strategy to improve anode performance in MFCs. Anode materials with excellent bioaffinity can promote bacterial attachment, growth, and extracellular electron transfer. In this study, positively charged nano hydroxyapatite (nHA) with remarkable biocompatibility combined with carbon nanotubes (CNTs) with unique structure and high conductivity were used as anode modifying material. The nHA/CNTs modified carbon brush (CB) exhibited improved bacteria adsorption capacity, electrochemical activity and reticular porous structure, thus providing abundant sites and biocompatible microenvironment for the attachment and growth of functional microbial and accelerating extracellular electron transfer. Consequently, the nHA/CNTs/CB-MFCs achieved the maximum power density of 4.50 ± 0.23 mW m-2, which was 1.93 times higher than that of the CB-MFCs. Furthermore, diclofenac sodium (DS), which is a widely used anti-inflammatory drug and is also a persistent toxic organic pollutant constituting a serious threat to public health, was used as the model organic pollutant. After 322 days of long-term operation, enhanced diclofenac sodium removal efficiency and simultaneous bioelectricity generation were realized in nHA/CNTs/CB-MFCs, benefiting from the mature biofilm and the diverse functional microorganisms revealed by microbial community analysis. The nHA/CNTs/CB anode with outstanding bioaffinity, electrochemical activity and porous structure presents great potential for the fabrication of high-performance anodes in MFCs.
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Fontes de Energia Bioelétrica , Nanotubos de Carbono , Fontes de Energia Bioelétrica/microbiologia , Diclofenaco , Durapatita , Eletrodos , BactériasRESUMO
Ferrous and sulfur ions are essential elements for the human body, which play an active role in maintaining the body's normal physiology. Meanwhile, mussel-inspired polydopamine (PDA) possesses good hydrophilicity and biocompatibility. In the present work, ferrous sulfide embedded into polydopamine nanoparticles (PDA@FeS NPs) was designed and synthesized via a simple predoping polymerization-coprecipitation strategy and the intelligent PDA matrix successfully prevented the oxidation and agglomeration of FeS nanoparticles. Importantly, there was an obvious synergistic enhancement of the photothermal effect between polydopamine and ferrous sulfide. The PDA@FeS NPs exhibited excellent photothermal antibacterial effects against both E. coli and S. aureus. The near-infrared (NIR) light-mediated release of ferrous ions could reach about 26.5% under weakly acidic conditions, further triggering the Fenton reaction to produce toxic hydroxyl radicals (·OH) in the presence of hydrogen peroxide. The antibacterial mechanism could be attributed to cell membrane damage and cellular content leakage with the synergistic effect of PTT and CDT. This study highlighted the germicidal efficacy of PDA@FeS NPs and provided a new strategy for designing and developing next-generation antibacterial platforms.
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Nanocompostos , Nanopartículas , Humanos , Escherichia coli , Staphylococcus aureus , Antibacterianos/farmacologia , Íons , Nanocompostos/toxicidadeRESUMO
BACKGROUND: The biomechanics of C1 posterior arch screw and C2 vertebral lamina screw techniques has not been well studied, and the biomechanical performance of the constructs cannot be explained only by cadaver testing. METHODS: From computed tomography images, a nonlinear intact three-dimensional C1-2 finite element model was developed and validated. And on this basis, models for the odontoid fractures and the three posterior internal fixation techniques were developed. The range of motion (ROM) and stress distribution of the implants were analyzed and compared under flexion, extension, lateral bending, and axial rotation. RESULTS: All three kinds of fixation techniques completely restricted the range of motion (ROM) at the C1-2 operative level. The C1-2 pedicle screw fixation technique showed lower and stable stress peak on implants. The C1 posterior arch screw + C2 pedicle screw and C1 pedicle screw + C2 lamina screw fixation techniques showed higher stress peaks on implants in extension, lateral bending, and axial rotation. CONCLUSIONS: As asymmetrical fixations, C1 posterior arch screw + C2 pedicle screw and C1 pedicle screw + C2 lamina screw fixations may offer better stability in lateral bending and axial rotation, but symmetrical fixation C1-2 pedicle screw can put the implants in a position of mechanical advantage.
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Articulação Atlantoaxial/fisiopatologia , Instabilidade Articular/cirurgia , Parafusos Pediculares , Adulto , Articulação Atlantoaxial/diagnóstico por imagem , Articulação Atlantoaxial/cirurgia , Fenômenos Biomecânicos , Humanos , Instabilidade Articular/diagnóstico por imagem , Instabilidade Articular/fisiopatologia , Masculino , Procedimentos Ortopédicos/instrumentação , Procedimentos Ortopédicos/métodos , Amplitude de Movimento Articular , Tomografia Computadorizada por Raios XRESUMO
BACKGROUND: Management of distal humerus metaphyseal-diaphyseal junction (MDJ) region fractures can be very challenging mainly because of the higher location and characteristics of the fracture lines. Loss of reduction is relatively higher in MDJ fractures treated with classical supracondylar humerus fractures (SHFs) fixation techniques. METHODS: Three different fracture patterns including transverse, medial oblique and lateral oblique fractures were computationally simulated in the coronal plane in the distal MDJ region of a pediatric humerus and fixated with Kirschner Wires (K-wires), elastic stable intramedullary nails (ESIN), and lateral external fixation system (EF). Stiffness values in flexion, extension, valgus, varus, internal, and external rotations for each fixation technique were calculated. RESULTS: In the transverse fracture model, 3C (1-medial, 2-lateral K-wires) had the best stiffness in flexion, varus, internal, and external rotations, while 3L (3-divergent lateral K-wires) was the most stable in extension and valgus. In the medial oblique fracture model, EF had the best stiffness in flexion, extension, valgus, and varus loadings, while the best stiffness in internal and external rotations was generated by 3MC (2-medial, 1-lateral K-wires). In the lateral oblique fracture model, 3C (1-medial, 2-lateral K-wires) had the best stiffness in flexion and internal and external rotations, while ESIN had the best stiffness in extension and valgus and varus loadings. CONCLUSION: The best stability against translational forces in lateral oblique, medial oblique, and transverse MDJ fractures would be provided by ESIN, EF, and K-wires, respectively. K-wires are however superior to both ESIN and EF in stabilizing all three fracture types against torsional forces, with both 2-crossed and 3-crossed K-wires having comparable stability. Depending on the fracture pattern, a 3-crossed configuration with either 2-divergent lateral and 1-medial K-wires or 2-medial and 1-lateral K-wires may offer the best stability.
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Fios Ortopédicos , Análise de Elementos Finitos , Fixação Interna de Fraturas/métodos , Fraturas do Úmero/diagnóstico por imagem , Fraturas do Úmero/cirurgia , Imageamento Tridimensional/métodos , Fenômenos Biomecânicos/fisiologia , Criança , Fixação Interna de Fraturas/instrumentação , Humanos , Fixadores Internos , Instabilidade Articular/diagnóstico por imagem , Instabilidade Articular/cirurgia , MasculinoRESUMO
Although photochromic and photocatalytic performance are the most significant features of WO3, the effects of photochromism on photocatalytic activities have not been investigated further. Herein, a novel gear-shaped WO3, with high coloration efficiency, fast reversibility, and remarkable photocatalytic performance was successfully prepared via a facile hydrothermal method. The influence of photochromic effects on its photocatalytic properties was evaluated under visible light irradiation. The results showed that the yellow WO3 sample exhibited higher photocatalytic efficiencies toward tetracycline hydrochloride (TCH), oxytetracycline (OTC), rhodamine B (RhB), and ciprofloxacin (CIP) (94.3%, 87.9%, 76%, and 68.6%, respectively, in 60 min). Further research found that the redox conversion between W6+ and W5+ played a key role in separating e-/h+ pairs. Importantly, the rapid and reversible conversion between W6+ and W5+ could be realized through light radiation or H2O2 treatment. Therefore, the gear-shaped WO3 possessed tunable and sustainable photocatalytic properties and maintained a high level of activity after recycling ten times under visible light irradiation. This work provides new insights into practical WO3 applications for environmental remediation based on photochromic regulation.
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In this study, a novel 0D/2D WS2/BiOBr heterostructured photocatalyst with rich oxygen vacancies was fabricated by a hydrothermal method. The WS2 QDs/BiOBr-10 heterostructures exhibited a maximum removal rate of 92% towards ciprofloxacin (CIP) within 100 min under visible-light irradiation, which was 2.63- and 2.02- folds higher activity than that of pristine BiOBr and WS2 QDs/BiOBr-10 with poor oxygen vacancies, respectively. In addition, the removal efficiencies of this photocatalyst towards various pollutants were 99% (Lanasol Red 5B), 95% (Rhodamine B), 85% (metronidazole), 96% (tetracycline) and 41% (Bisphenol A), respectively. Besides, the simultaneous photocatalytic degradation showed the competitive interactions between these organic contaminants for the active species, decreasing the removal efficiency for CIP. However, the simultaneous photocatalytic oxidation of CIP and reduction of Cr(VI) improved the utilization efficiency of photo-induced electrons and holes, resulting in high removal efficiencies for both CIP and Cr(VI). Three-dimensional excitation-emission matrix fluorescence spectra (3D EEMs) were used to investigate the degradation of CIP molecules. The synergistic effect of heterostructure and oxygen vacancies greatly assisted in the removal of organic pollutants, attributing to the enhanced visible-light harvesting and effective separation of photo-induced electron-hole pairs. Furthermore, trapping experiments and ESR results demonstrated that the CIP removal was dominated by the direct oxidation of holes (h+), whereas the hydroxyl radicals (OH) and superoxide radicals (O2-) acted as auxiliary active species. This study provides a new way to rationally design and construct active 0D/2D pattern heterojunction photocatalysts for environmental remediation.
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Herein, an efficient broad-spectrum WS2/BiOBr heterostructure with ultrathin nanosheet was successfully prepared by one-pot hydrothermal route. The self-assembled flower-like WS2/BiOBr nanostructure was formed by few-layer WS2 and BiOBr nanosheets. The optimized heterojunction presented broad-spectrum high-efficiency photocatalytic activity towards the removal of various pollutants under visible-light irradiation, including organic dyes, antibiotics and phenols. This efficiency was linked to high light harvesting combined with effective charge separation/transfer. Meanwhile, the degradation efficiencies varied with nature of the pollutant decreased in the following order: LR5B (99%)â¯>â¯MNZ (97%)â¯>â¯TC (92%)â¯>â¯OTC (92%)â¯>â¯RhB (90%)â¯>â¯CIP (83%)â¯>â¯MB (78%)â¯>â¯MO (62%)â¯>â¯bisphenol (42%)â¯>â¯phenol (40%). The photocatalytic process of ciprofloxacin was explored, and the results indicated that high ciprofloxacin concentrations, low pH values and elevated concentrations of ions (PO43-, HPO42-, H2PO4-, and Cu2+) restrained the photocatalytic performances. Trapping experiments and ESR revealed the significant contribution of holes (h+) in the mechanism, where both superoxide radicals (O2-) and hydroxyl radicals (OH) acted as assistants. Overall, this work could offer a new protocol for the design of highly efficient heterostructure photocatalysts for environmental remediation.
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The interaction of nanoparticles (NPs) with proteins is a topic of high relevance for the medical application of nanomaterials. In this study, a comprehensive investigation was performed to clarify the binding mechanism, adsorption isotherms and kinetics of the interaction between silver nanoparticles (AgNPs) and trypsin. The experimental results indicate that the binding of AgNPs to trypsin seems to be a static quenching mechanism. Thermodynamic analysis reveals that AgNPs binding to trypsin is synergistically driven by enthalpy and entropy, and the major driving forces are hydrophobic and electrostatic interactions. The adsorption of trypsin on AgNPs was analyzed by Langmuir and Freundlich models, suggesting that the equilibrium adsorption data fit well with Freundlich model. The kinetics of adsorption data were modeled using the pseudo-first-order and pseudo-second-order kinetic equations. The results indicate that a pseudo-second-order kinetic equation describes better. The conformational change at the secondary structural level of trypsin induced by AgNPs was investigated with the circular dichroism (CD) measurements and no obvious changes in trypsin secondary structural elements are observed. These fundamental works will provide some new insights into the safe and effective application of AgNPs in biological and medical areas.
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Nanopartículas Metálicas/química , Prata/química , Tripsina/metabolismo , Adsorção , Calorimetria , Entropia , Interações Hidrofóbicas e Hidrofílicas , Cinética , Modelos Químicos , Ligação Proteica , Espectrometria de Fluorescência , Eletricidade Estática , TermodinâmicaRESUMO
A novel BiVO4/BiPO4 composite with a balsam pear-shaped morphology was fabricated by a green hydrothermal synthesis approach, which didn't employ a strong acid and base, and neither a template or surfactant. The co-precipitation hydrothermal process had significant influence not only on particle size and shape, but also on the BiVO4 oriented growth along the (040) facet. The morphology, microstructure, light absorption and emission properties were analyzed by several characterization techniques. A formation mechanism for the hollow BiVO4/BiPO4 composite was proposed on the basis of time-dependent SEM observations. Charge transfer absorption and an efficient charge separation were observed by UV-vis DRS, PL spectra and photocurrent measurements, which suggest that there are chemical interactions between BiVO4 and BiPO4. The above synergistic effects of the as-prepared composite result in a higher photocatalytic performance for the degradation of RhB and MNZ compared with the single component and their physical mixture. Besides that, the special hollow structure and preferred exposure of the BiVO4 (040) facet could contribute to the dramatically improved performance. Subsequently, a possible photocatalytic mechanism over the BiVO4/BiPO4 composite was proposed based on experiment and theoretical analysis. These results indicate that the hollow BiVO4/BiPO4 composite has a great potential application value for the treatment of organic dyes and medicine wastewater.
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The amphiphilic star-like copolymer polyethylenimine-block-poly(ε-caprolactone) (PEI-b-PCL) was utilized to transfer the pre-synthesized citrate-capped noble metal nanoparticles (NMNPs) from an aqueous layer to an organic layer without any additional reagents. Dynamic light scattering (DLS) and transmission electron microscopy (TEM) were utilized to study the assembly of the polymers coated on the surface of the citrate-capped NMNPs. After removing the organic solvent, the polymer-coated NMNPs in powder form (PCP-NMNPs) were obtained. The excellent solubility of the PEI-b-PCL allows the PCP-NMNPs to be easily dispersed in most of the organic solvents without any significant aggregation. Moreover, the good thermal stability and long-term stability make PCP-NMNPs an excellent NMNP-containing hybrid system for different specific applications, such as surface coating, catalysis and thermoplastic processing of nanocomposite materials.
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Heterojunction construction is an exciting direction to pursue for highly active photocatalysts. In this study, novel core/shell ß-Bi2O3/Bi2S3 hollow heterostructures were successfully synthesized through a simple and economical ion exchange method between ß-Bi2O3 hollow microspheres and thioacetamide (CH3CSNH2, TAA), and characterized by multiform techniques, such as XRD, XPS, SEM, TEM, BET, DRS and PL. The results indicated that the core/shell ß-Bi2O3/Bi2S3 hollow heterostructures exhibited strong absorption in visible light region and excellent photocatalytic performance for decomposing rhodamine B (RhB) compared with pure ß-Bi2O3 under visible light irradiation. Among the ß-Bi2O3/Bi2S3 photocatalysts with different molar percentage of Bi2S3 to initial ß-Bi2O3, the ß-Bi2O3/Bi2S3 (10%) heterostructures exhibited the highest photocatalytic activity, which was about 3.3 times higher than that of pure ß-Bi2O3 sample. Moreover, the study on the mechanism suggested that the enhanced photocatalytic activity mainly resulted from the role of ß-Bi2O3-Bi2S3 heterojunction formed in the ß-Bi2O3/Bi2S3, which could lead to efficient separation of photoinduced carriers. Additionally, the photosensitization of Bi2S3 and the hollow nature of ß-Bi2O3 were also responsible for the high photocatalytic activity.