Enhanced Stability of Rhombic Dodecahedron Nb15- with Well-Organized Superatomic States.

Well-resolved Nbn- clusters are produced and reacted with ethene and propene via a downstream flow tube reactor. Interestingly, the Nbn- clusters readily react with ethene and propene to form dehydrogenation products; however, Nb15- shows up in the mass spectra with prominent mass abundance indicating its inertness to react with olefins. For this cluster, we conduct photoelectron velocity map imaging (VMI) experiments and verify the stability of Nb15- within a highly symmetrical rhombic dodecahedron structure. Theoretical studies show that the stability of the Nb15- cluster is correlated with its superatomic nature pertaining to both geometric and electronic shell closures. Notably, the superatomic 1s orbital is dominated by the 5s electron of the central Nb atom, while the other superatomic orbitals are contributed by s-d hybridization, especially a remarkable contribution of s-dz2 hybridization. Apart from the closed shells, the highly symmetric geometry of Nb15- is associated with a regular polyhedral structure directed by all rhombus facets, embodying a magic number for body-centered dodecahedra, indicative of enhanced stability as a double magic cluster free of olefin adsorption.

Gas-Phase Synthesis of Metal Olefins: Plasma-Assisted Methane Dehydrogenation and C═C Bond Formation.

Methane dehydrogenation and C-C coupling under mild conditions are very important but challenging in chemistry. Utilizing a customized time of flight mass spectrometer combined with a magnetron sputtering (MagS) cluster source, here, we have conducted a study on the reactions of methane with small silver and copper clusters simply by introducing methane in argon as the working gas for sputtering. Interestingly, a series of [M(CnH2n)]+ (M = Cu and Ag; n = 2-12) clusters were observed, indicating high-efficiency methane dehydrogenation in such a plasma-assisted chamber system. Density functional theory calculations find the lowest energy structures of the [M(CnH2n)]+ series pertaining to olefins indicative of both C-H bond activation of methane and C-C bond coupling. We analyzed the interactions involved in the [Cu(CnH2n)]+ and [Ag(CnH2n)]+ (n = 1-6) clusters and demonstrated the reaction coordinates for the "Cu+ + CH4" and "Ag+ + CH4." It is illustrated that the presence of a second methane molecule enables us to reduce the necessary energy of dehydrogenation, which concurs with the experimental observation of an absence of the metal carbine products Cu+CH2 and Ag+CH2, which are short-lived. Also, it is elucidated that the higher-lying excitation states of Cu+ and Ag+ ions enable more favorable dehydrogenation process and C═C bond formation, shedding light on the plasma assistance of the essence.

Gas-phase synthesis and deposition of metal-bipyridine complex [M-bpy1-2]+ (M = Ag, Cu).

Controllable synthesis of organometallic clusters in the gas phase is a topic of reasonable interest with precisely tunable properties depending on sizes, compositions, and intra-cluster charge-transfer interactions. Here, we have prepared small Agn+ and Cun+ clusters by using a customized magnetron sputtering (MagS) source and observed the gas-phase reactions with 2,2'-bipyridine. It is found that the small silver and copper clusters readily react with bipyridine and form products of [M-bpy1-2]+ (M = Ag, Cu). Quantum chemistry calculations reveal that the bipyridine in both [Ag-bpy1-2]+ and [Cu-bpy1-2]+ takes on cis-conformation with altered N-C-C-N dihedral angles, which is in contrast to the trans-conformation of a free 2,2'-bipyridine molecule itself. In order to unveil the principle of conformational transition, we have fully studied the interactions between the nitrogen atoms of bipyridine and the cationic Ag+ and Cu+, calculated the donor-acceptor orbital overlaps, and analyzed the correlation of their frontier molecular orbital energy levels. Furthermore, by using a soft-landing strategy, we have managed to deposit the [Cu-bpy2]+ complex onto the glass substrates coated with Ag nanoparticles, and recorded the surface-enhanced Raman scattering spectra.

Hydrogen Evolution Reactions of Hydrocarbons and Hydroborons Promoted by Superatomic Nbn- Clusters.

Hydrogen evolution reactions (HER) are crucial for producing renewable and ecological hydrogen energy. Here we report the finding that ethyl acetylene (C2H2), borane (B2H6), and benzene (C6H6) undergo drastic dehydrogenation reactions upon interaction with niobium cluster anions (Nbn-). This finding was enabled by our very sensitive and specialized mass spectrometer, which monitored the cluster ions and the resulting metal carbide and boride products in real time. Through mass spectrometry experiments and density functional theory computations, we delved into the varying reactivities of these common gas molecules with small Nbn- clusters and elucidated the underlying reaction mechanisms. These findings shed light on the HER mechanisms of hydrocarbon and hydroboron molecules on superatomic Nbn- clusters, furnishing valuable insights pertinent to the advancement of hydrogen energy resources.